Illustrated Physics
physics, drawn
Concept

Laplace pressure — where it appears

The excess pressure inside a curved interface, equal to the surface tension times the curvature, so the smaller the radius the larger it is. That inverse dependence is why a small bubble connected to a large one empties into it, and why nucleating a new bubble is hard.

Named by 16 essays across 3 fields — each of them below, with the objects they name alongside it.

The small bubble empties into the large one. Two soap bubbles of radius 4 mm and 12 mm joined by an open tube. The excess pressure inside each is 4γ/R — 72.8 Pa and 24.3 Pa — so the 4 mm bubble is at the higher pressure and blows itself into the other. The smaller a bubble gets the harder it pushes, so the process runs away rather than settling: there is no equilibrium anywhere except both bubbles equal.

The small bubble blows up the big one

Connect two soap bubbles of different size and the small one empties into the large one. Everybody expects the opposite, and the reason it happens is one equation with a radius in the denominator — which also means the process runs away rather than settling.

fluids · Surface tension Which wavelength wins. The growth rate of a disturbance on a liquid thread against kR, the circumference divided by the wavelength. Everything to the right of one decays; the maximum sits at kR = 0.697, which is a wavelength of 9.01 radii or 4.51 diameters. That number, and not a property of any particular liquid, is what sets the spacing of the drops a tap breaks into.

The thread that cannot stay a thread

A stream of water from a tap breaks into drops, and it does so at a spacing that is always about four and a half diameters. Nothing chooses that number — it is the wavelength that grows fastest out of a competition between all of them, and it can be computed before any water is poured.

fluids · Surface tension Four tubes, four heights. Water in tubes of radius 0.2, 0.4, 0.8, 1.6 mm, with each meniscus drawn as the spherical cap a 20° contact angle forces and each height computed from it. The narrowest rises 70 mm and the widest 9 mm — in inverse proportion to the radius, with nothing about the glass or the volume of water entering it.

How high water will climb

Water rises up a narrow tube against gravity, and the narrower the tube the higher it goes. The height is set by a curved surface pulling on a circumference while gravity pulls on an area, and the two scale differently — which is the whole of it.

fluids · Capillarity One volume of liquid, several solids. 4 drops of the same 5 µL of liquid, on 4 solids it meets at 20°, 60°, 90°, 140°. Each is the spherical cap that volume and that angle force, so the footprint radius is computed rather than chosen: 20° gives 2.61 mm, 60° gives 1.71 mm, 90° gives 1.34 mm, 140° gives 0.69 mm. At every contact line the three interfacial tensions are drawn to scale, and only their horizontal components balance — γsv = γsl + γlv cos θ. The vertical pull of the liquid surface is taken up by the solid, which is why the angle belongs to three interfaces at once and to no single liquid: change the solid and nothing about the water has changed.

The angle a liquid makes with what it sits on

Everything capillarity does — climbing, beading, wicking, waterproofing — is the sign and size of one cosine, and that cosine belongs to three interfaces at once rather than to the water. Change the solid and nothing about the water has changed, yet the same five microlitres goes from a footprint 2.61 mm across to one of 0.69 mm.

fluids · Capillarity Where a drying drop loses its liquid. The rate at which liquid leaves the surface of a drying drop, against distance from the centre in units of the drop's radius, for 5 contact angles. The flux is not uniform, and it is not a property of the liquid: it is set by how vapour diffuses away from a lens-shaped object, which is the same boundary-value problem as the field around a charged lens and has the same answer — a power law in the distance from the rim, with an exponent that depends only on the contact angle. at 10° the exponent is 0.471, and the loss has doubled by 87.8 per cent of the way out, at 40° the exponent is 0.357, and the loss has doubled by 92.5 per cent of the way out, at 70° the exponent is 0.182, and the loss has doubled by 98.9 per cent of the way out, at 90° the exponent is 0.000 and the drop dries evenly everywhere, at 120° the exponent is -0.500 and the flux falls toward the rim. Below a right angle the flux diverges at the contact line; at exactly a right angle it is uniform; above it the edge is the slowest-drying part of the drop. Since a pinned edge must be resupplied from the interior, that sign decides which way the liquid inside the drop flows — and therefore whether everything suspended in it ends up in a ring at the rim or in a spot at the centre.

The ring the drop leaves behind

A drop of coffee dries into a ring rather than a disc, and nothing about coffee is responsible. The pattern is produced by a boundary condition — an edge that cannot move — and it survives replacing the coffee with anything else that will stay suspended.

fluids · Surface tension A pore that lifts 100 m has to be 0.1 µm or finer. Capillary rise against pore radius, both logarithmic, for a liquid of surface tension 72.8 mN/m at a contact angle of 20°. The relation is a straight line of slope −1 — halve the pore and double the rise — and the two horizontal marks are the height in question, 100 m, and the 10.3 m that one atmosphere supports. 0.01 µm lifts 1394.7 m; 0.1 µm lifts 139.5 m; 1 µm lifts 13.9 m; 5 µm lifts 2.8 m; 20 µm lifts 69.7 cm; 50 µm lifts 27.9 cm. The conducting vessels of a tree are tens of microns across and lift under a metre; the pores in the membranes between them are tens of nanometres and would lift kilometres. Those are the same expression at two scales, and only one of them is a pipe.

The column that is pulled, not pushed

A capillary fine enough to lift a hundred metres is far too fine to carry any flow, and one wide enough to carry the flow lifts under a metre. Neither is how the water gets up a tree. The column is under tension — an absolute pressure of −0.88 MPa at the top, which a gas cannot have — held together by cohesion and prevented from tearing by pores a few tens of nanometres across.

fluids · Capillarity The outward pull on a charged surface. Electrostatic pressure against the field at a conductor's surface. The quantity is ½ε₀E², the energy density of the field itself, and it is outward whatever the sign of the charge — like charges repel, and a charged surface is trying to fly apart. The factor of a half is the interesting part and is where a first attempt goes wrong: the field is σ/ε₀ outside and zero inside, and the layer of charge feels neither of those but their mean, because no charge exerts a force on itself. 0.5 MV/m gives 1.1 Pa, 1 MV/m gives 4.4 Pa, 2 MV/m gives 17.7 Pa, 3 MV/m gives 39.8 Pa, 5 MV/m gives 110.7 Pa. Those are small pressures — three megavolts per metre is the breakdown field of air and pulls with about a hundredth of an atmosphere — which is why electrostatic forces shape soap films and dust and not much that is stiffer, and why the same pressure set against surface tension has a definite size of drop at which it wins.

The pressure a charge puts on its own metal

Charge on a conductor sits on the surface and tries to leave. The outward pull is half epsilon-nought E squared, the half is because a charge exerts no force on itself, and setting that pull against surface tension gives the largest a charged drop is allowed to be — a number Rayleigh wrote down in 1882 and an industry now depends on.

electromagnetism · Conductors One line decides whether it climbs for ever. The wetting condition for a corner, drawn as a map. The horizontal axis is the corner's half-angle and the vertical axis the liquid's contact angle with the walls; the diagonal is θ + α = 90°. Below it the meniscus in the corner curves into the liquid, the capillary pressure grows without bound as the corner narrows, and the liquid wicks along it indefinitely. Above it the curvature has the other sign and the liquid stays put. The boundary is tested by evaluating the meniscus a millionth of a degree either side of it at seventeen half-angles, and it wicks on one side and not the other every time. water on clean glass, right-angled corner: α = 45°, θ = 5° — wicks; water on glass, a 20° groove: α = 10°, θ = 40° — wicks; water on plastic, right-angled corner: α = 45°, θ = 75° — does not. A right-angled corner needs a contact angle under 45°, which water on clean glass has and water on most plastics does not.

The corner a liquid never stops climbing

A narrow tube lifts a liquid to a definite height because it has a smallest width. A corner has none, so the capillary suction it can develop is unbounded — and whether the liquid takes advantage is decided by a single inequality between the contact angle and the corner's own angle.

fluids · Surface tension The pore size the air decides. The largest pore radius that holds condensed water in equilibrium with air at a given relative humidity, for water at 25 °C, on a logarithmic radius axis. A concave meniscus lowers the vapour pressure over it by exp(−2γVₘ/rRT), so a pore whose meniscus would be tighter than a radius set by the humidity is in equilibrium only when full. The upper curve is the emptying condition, through a hemispherical meniscus with two curvatures; the lower is the filling condition, through the cylindrical film that lines a pore before it closes, with one — so the same pore fills at a higher humidity than it empties at. At 50% humidity a pore empties below 1.51 nm and fills below 0.76 nm; at 90% humidity a pore empties below 9.96 nm and fills below 4.98 nm; at 99% humidity a pore empties below 104 nm and fills below 52 nm. The radii run from molecular at low humidity to a tenth of a micrometre at 99 per cent, and every one was checked by putting it back into the vapour-pressure relation.

The pore that fills from dry air

Water condenses when the air is saturated — on a flat surface. Over a curved one the vapour pressure is different, higher over a drop and lower over a meniscus, and in a pore a few nanometres across it is low enough that the pore fills with liquid from air at half humidity. The water it holds is under a tension of a hundred megapascals, and the pore empties at a lower humidity than it filled at, for a reason that needs no roughness at all.

fluids · Capillarity The pull of a meniscus against the stiffness of a wall. For two neighbouring lines of a wet pattern leaning towards each other, the net Laplace pressure pulling them together (heavy curve) and the bending stiffness pushing them back (straight lines), against the lean as a fraction of the half-gap. The pull grows faster than linearly, because narrowing a gap raises its suction, and it diverges as the gap closes. The stiffness is a straight line whose slope falls as the fourth power of the line's height; the lines drawn are for 0.8 times, 1 times, 1.25 times the critical height. At 0.8 of the critical height the straight state is stable and an unstable balance lies at a lean of 0.77 of the half-gap, a barrier the lines must be pushed over; at the critical height the two start with the same slope and the straight state is marginal; at 1.25 times the straight state is unstable and the pair collapses.

The walls a rinse pulls together

Every result about capillary rise assumes the walls hold still. Make them thin enough and they do not. The water between two walls is below atmospheric pressure, so it pulls them together, and as the gap narrows the suction grows. Beyond a critical height or length the walls cannot push back and they snap shut. It is why wet hair clumps, why a paintbrush comes out of water as a point, and why a chip factory cannot rinse lines of resist taller than about three times their width without laying them flat.

fluids · Capillarity A cell swells until its membrane runs out. The volume of a red cell of 90 fL against the salt concentration of the solution round it, in per cent sodium chloride by weight, with 0.9 per cent isotonic. By the Boyle–van 't Hoff law the water inside follows the outside's tonicity: the cell's volume is an inactive part, 40 per cent of the normal volume in haemoglobin and other solids, plus a part inversely proportional to the concentration. Its membrane's 135 μm² can enclose at most 147.5 fL, as a sphere (dashed). The swelling curve reaches that at 0.44 per cent salt: below it the cell has no more shape to give up and bursts. In a 1.5 per cent solution the same cell shrinks to 68 fL and crenates, with membrane to spare.

The cell that bursts by geometry

Put a red blood cell in salt water weaker than blood and water flows in. The cell does not stretch to take it, because its membrane will not stretch: it can change shape almost for nothing and change its area by about two per cent before it tears. So the cell swells by changing shape, from a dimpled disc towards a sphere, and when it reaches the sphere its membrane can enclose, it has no more shape to spend. That happens at about 0.44 per cent salt, half the strength of blood, and the clinical test that measures it — called a test of fragility — turns out to measure a ratio of area to volume, not the strength of anything.

fluids · Osmosis Why silt heaves and sand and clay do not. The relative rate at which water is drawn to a growing ice lens, against grain diameter on a logarithmic scale, for three loads on the soil above it, in a capillary model: the rate is the soil's permeability, which grows as the grain diameter squared, times the suction the lens can sustain less the load. The suction is capped both by the supercooling at the lens, here 2 K, and by the Gibbs–Thomson pressure at which ice would break into the pores. Coarse soil has open pores that ice simply invades, so the suction never exceeds the load: under 10 kPa, half a metre of soil, nothing heaves above 58 μm. Fine clay can sustain the full suction but passes water too slowly to feed it. Between lies a fastest grain size, 29 μm under 10 kPa, 10 μm under 30 kPa and 2.9 μm under 100 kPa: silt, the soil engineers have long called frost-susceptible. Real heave pressures exceed this model's, and the fit is to the shape, not the scale.

The frost that lifts by drinking

Frozen ground rises in winter, sometimes by tens of centimetres, and the usual explanation — water expands by nine per cent when it freezes — is wrong: soil soaked in benzene, which shrinks as it freezes, heaves too. The lift comes from layers of clear ice that grow by pulling liquid water up through the soil from below. Ice and water touching each other need not be at the same pressure, and when the water is free to flow, ice a degree below its melting point can push with 1.12 megapascals while it drinks — twelve times less than freezing water in a sealed pipe, and enough to lift a house at a tenth of a degree.

thermodynamics · Chemical potential Six cells of a two-dimensional foam, by number of sides. Cells of a two-dimensional soap froth with three to eight sides, each drawn with its films meeting three at a time at 120°, as surface tension requires. A hexagon can do that with straight sides. A cell with fewer than six sides cannot: to make its corners 120° its sides must bulge outward, so its gas is at higher pressure than its neighbours' and leaks out. A cell with more than six must have sides curving inward, lower pressure, and gains gas. The rate of change of area, in units of πκγ/3 where κ is the films' permeability, is n − 6: −3 for a triangle, +2 for an octagon.

The bubble that grows by counting its sides

A froth of soap bubbles squeezed between two sheets of glass coarsens over a few days: small cells vanish and large ones swell. The obvious guess is that size decides which cells win, as it does for two bubbles joined by a tube, where the small one always empties into the large one. In a froth it is wrong. John von Neumann showed in 1952 that a cell's area changes at a rate fixed entirely by how many sides it has — shrinking if fewer than six, growing if more — and not at all by how big it is. The proof is a single sum of angles.

fluids · Surface tension A drop in a tapered tube. A section through a glass tube tapering from 1.2 mm to 0.2 mm in radius over 60 mm, holding a 2 μL plug of water (contact angle 20°), not to scale across. Both menisci curve into the empty tube, so the water just inside each is below atmospheric pressure — by 269 Pa at the narrow end, radius 0.50 mm, and by 252 Pa at the wide end, radius 0.54 mm. The pressure is lower at the narrow end, so the water flows towards it: a net push of 17 Pa, with no gravity, no pump and no motion of the tube.

The drop that runs to the narrow end

Put a drop of water into a glass tube that narrows towards one end and it moves, on its own, towards the narrow end — horizontally, with nothing pushing it. Francis Hauksbee reported it to the Royal Society in 1712, and the explanation is two curved surfaces pulling with different strengths: each meniscus lowers the pressure of the water behind it by an amount that grows as the tube narrows, so the end in the narrower part sucks harder. A drop of mercury, which does not wet glass, goes the other way. Which way a drop goes depends on the cosine of one angle, and, for a short drop, on its length.

fluids · Capillarity One height inside the bottle where the pressure is the air's. Gauge pressure against height inside a sealed bottle with an open tube reaching down to 10 cm above its outlet, while it is bubbling, at three water levels: 30.0, 22.0, 13.0 cm. Each line rises at the same hydrostatic slope, ρg, from the air pocket at the top, which is below atmospheric, to the outlet at the foot. All three cross atmospheric pressure at the tube's tip — 7.4 mm below it, the extra a bubble needs to leave a 2 mm tube — and so all three reach the outlet at the same 906 Pa above atmospheric, whatever the level. Dashed: an open bottle at the same levels, whose pressure at the outlet is 2937, 2154, 1273 Pa.

The bottle that pours at one rate however full it is

Water running from a hole in the foot of an open bottle slows as the bottle empties, because the pressure at the hole is the depth of water above it. Seal the bottle and push an open tube through the stopper, down into the water, and it stops slowing: the flow holds steady from full until the level reaches the bottom of the tube. Nothing regulates it. The tube's tip is the one point inside where the pressure is the atmosphere's, the water above it hangs from an air pocket below atmospheric, and the outlet sees only the height of the tip.

fluids · Hydrostatics The force that does not count the water. The force of a water bridge between two touching spheres of radius R, in units of 2πRγ, against the bridge's volume on a logarithmic scale running over six decades, for three contact angles. Each curve is nearly flat: from a millionth of R³ to a thousandth, the force on a wetting grain falls only from 0.99 to 0.92 of 2πRγ, and it stays close to cos θ for the others. A droplet between two grains of sand pulls almost as hard as one a thousand times larger. This is the reason sand wet with one per cent of water and sand wet with ten per cent hold together with about the same strength. The curves fall where a bridge is large enough for its neck to stop being small compared with the grain, and bridges of that size merge with their neighbours.

The sandcastle a spoonful of water holds

A dry heap of sand stands at thirty degrees and no steeper. Add a spoonful of water to a bucketful, and the same grains will stand in a vertical wall and carry a person's weight. Add ten times as much water and the wall is no stronger, because a bridge of water between two grains pulls with almost the same force whatever its size. Its strength belongs to the grain and the surface tension, and the amount of water hardly enters.

fluids · Granular matter

Named alongside it

The objects these essays reach for when they reach for this one.

Surface tensionCapillarityContact angleWettingCapillary lengthCurvatureCavitationInstabilityMeniscusSurface energyChemical potentialDiffusion

All concepts