Illustrated Physics
physics, drawn
Concept

Cavitation — where it appears

The formation of vapour cavities in a liquid held below its own vapour pressure, and the collapse that follows when the pressure returns. The collapse is violent enough to erode metal, and avoiding it sets the ceiling on how high a siphon or a suction pump can lift.

Named by 4 essays across one field — each of them below, with the objects they name alongside it.

The small bubble empties into the large one. Two soap bubbles of radius 4 mm and 12 mm joined by an open tube. The excess pressure inside each is 4γ/R — 72.8 Pa and 24.3 Pa — so the 4 mm bubble is at the higher pressure and blows itself into the other. The smaller a bubble gets the harder it pushes, so the process runs away rather than settling: there is no equilibrium anywhere except both bubbles equal.

The small bubble blows up the big one

Connect two soap bubbles of different size and the small one empties into the large one. Everybody expects the opposite, and the reason it happens is one equation with a radius in the denominator — which also means the process runs away rather than settling.

fluids · Surface tension A siphon's pressure, and the 10.09 m it cannot pass. The absolute pressure of the liquid along a siphon, from the upper surface, over the crown, and down to an outlet 1.2 m below the surface, for 4 crown heights. The profile is hydrostatic and depends on nothing but height: the tube's shape, its length and its bore do not appear. At the crown the liquid is below atmospheric pressure by ρg times the lift, and the whole question of how high a siphon can reach is whether that number stays above the liquid's vapour pressure — 2.34 kPa for water at 20 °C, which puts the ceiling at 10.09 m. a 2 m crown sits at 81.7 kPa and holds, a 6 m crown sits at 42.5 kPa and holds, a 9.5 m crown sits at 8.1 kPa and holds, a 11.5 m crown sits at -11.5 kPa and is below the vapour pressure, so it boils. The ceiling is a property of the liquid, not of the mechanism: a degassed liquid that can be pulled into tension has no such limit, and siphons in a vacuum.

The height a siphon cannot pass

A siphon will not lift water more than about ten metres, and the usual explanation for the limit is also given as the explanation for the mechanism. It cannot be both. A siphon runs in a vacuum, with degassed water, over a crown no atmosphere could support.

fluids · Hydrostatics A pore that lifts 100 m has to be 0.1 µm or finer. Capillary rise against pore radius, both logarithmic, for a liquid of surface tension 72.8 mN/m at a contact angle of 20°. The relation is a straight line of slope −1 — halve the pore and double the rise — and the two horizontal marks are the height in question, 100 m, and the 10.3 m that one atmosphere supports. 0.01 µm lifts 1394.7 m; 0.1 µm lifts 139.5 m; 1 µm lifts 13.9 m; 5 µm lifts 2.8 m; 20 µm lifts 69.7 cm; 50 µm lifts 27.9 cm. The conducting vessels of a tree are tens of microns across and lift under a metre; the pores in the membranes between them are tens of nanometres and would lift kilometres. Those are the same expression at two scales, and only one of them is a pipe.

The column that is pulled, not pushed

A capillary fine enough to lift a hundred metres is far too fine to carry any flow, and one wide enough to carry the flow lifts under a metre. Neither is how the water gets up a tree. The column is under tension — an absolute pressure of −0.88 MPa at the top, which a gas cannot have — held together by cohesion and prevented from tearing by pores a few tens of nanometres across.

fluids · Capillarity The pore size the air decides. The largest pore radius that holds condensed water in equilibrium with air at a given relative humidity, for water at 25 °C, on a logarithmic radius axis. A concave meniscus lowers the vapour pressure over it by exp(−2γVₘ/rRT), so a pore whose meniscus would be tighter than a radius set by the humidity is in equilibrium only when full. The upper curve is the emptying condition, through a hemispherical meniscus with two curvatures; the lower is the filling condition, through the cylindrical film that lines a pore before it closes, with one — so the same pore fills at a higher humidity than it empties at. At 50% humidity a pore empties below 1.51 nm and fills below 0.76 nm; at 90% humidity a pore empties below 9.96 nm and fills below 4.98 nm; at 99% humidity a pore empties below 104 nm and fills below 52 nm. The radii run from molecular at low humidity to a tenth of a micrometre at 99 per cent, and every one was checked by putting it back into the vapour-pressure relation.

The pore that fills from dry air

Water condenses when the air is saturated — on a flat surface. Over a curved one the vapour pressure is different, higher over a drop and lower over a meniscus, and in a pore a few nanometres across it is low enough that the pore fills with liquid from air at half humidity. The water it holds is under a tension of a hundred megapascals, and the pore empties at a lower humidity than it filled at, for a reason that needs no roughness at all.

fluids · Capillarity

Named alongside it

The objects these essays reach for when they reach for this one.

Surface tensionCapillarityLaplace pressureNucleationPressureVapour pressureAtmospheric pressureBoundary conditionsCapillary condensationCapillary lengthChemical potentialContact angle

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