Illustrated Physics
physics, drawn
Concept

Pressure — where it appears

Force per unit area in a fluid, a scalar with no direction of its own, delivered as the momentum molecules bring to a wall each second. It acts equally in every direction at a point, which is why the force on a surface is perpendicular to it whatever its orientation.

Named by 16 essays across 4 fields — each of them below, with the objects they name alongside it.

Molecular speeds at 4 temperatures. The distribution of molecular speeds in a gas, with each curve enclosing the same area. Raising the temperature moves the peak right and lowers it: the same molecules, spread over a wider range of speeds.

The speeds in a still room

The air in a quiet room is not still. Every molecule in it is moving at hundreds of metres per second, and temperature is a single number summarising an entire distribution.

thermodynamics · Kinetic theory Pressure, counted as momentum arriving at a wall. Molecules with speeds drawn from the Maxwell–Boltzmann distribution and directions drawn uniformly in the plane of the figure. Those moving toward the wall will bounce off it, reversing the component perpendicular to it and delivering twice that momentum each — and pressure is nothing but the rate at which that momentum arrives. Because the directions here lie in a plane rather than in space, the perpendicular component carries half the energy rather than the third it carries in a real gas.

Pressure is a rate of arrival, and the gas law falls out of counting

Nothing in a gas is pushing on the walls. Molecules arrive, bounce, and leave, and pressure is the momentum they deliver per second — from which the ideal gas law follows with no thermodynamics in it at all.

thermodynamics · Kinetic theory Three vessels, one pressure. Three vessels filled to the same depth of 3 m. The pressure on each base is 29.4 kPa — identical, because pressure is set by depth — while the weight of water each holds differs by a factor of 4.7. The base of the flaring vessel carries more force than the water standing over it weighs.

The pressure that only knows depth

A litre of water and a swimming pool press equally hard on a floor at the same depth. Pressure in a still fluid is a scalar with no direction of its own, it depends on how far down and on nothing else, and the shape of the container falls out of the arithmetic entirely.

fluids · Hydrostatics Force multiplied, distance paid. Two pistons on one body of fluid, of areas in the ratio 16 to 1. A force of 200 N on the small one holds 3.20 kN on the large one, and pushing the small piston 16 cm raises the large one by 10.0 mm. The two products are the same number: nothing is gained except the shape of the bargain.

Force multiplied, and nothing gained

A push on a small piston becomes a much larger push on a large one, in the ratio of their areas, with no machinery in between except the liquid. What the liquid will not do is give anything away — the distances shrink by the same factor the forces grow by, and the product is untouched.

fluids · Hydrostatics Where the upward force comes from. A block submerged with its top 1.2 m down. The pressure on the bottom face (19.6 kPa) exceeds that on the top (11.8 kPa) by exactly the weight of a column of water as tall as the block, and the sideways pressures cancel in pairs. Nothing has been added to the physics of pressure to get buoyancy out of it.

The weight of the water that is not there

A submerged object is pushed up by the weight of the fluid it has displaced — not by something like it, not approximately, but exactly. The reason is that the pressures on its faces do not cancel, and the sum that survives has forgotten everything about the object except its shape.

fluids · Buoyancy The parabola in a pipe, and what it integrates to. Steady flow in a round pipe: the velocity is a parabola, zero at the wall and greatest on the axis, and its average over the cross-section is 0.500 of the peak — exactly a half, by integration. Because the profile scales with r² and the area with r² as well, the flow goes as the fourth power of the radius: widening a pipe from 1 to 2 mm multiplies it by 16.

The fourth power in a pipe

Halve a pipe's radius and the flow through it falls to a sixteenth. The exponent is four rather than two, because narrowing a pipe both removes cross-section and slows what is left — and one law with that exponent in it governs a blood vessel, a hypodermic needle and a water main.

fluids · Viscosity The phase boundary of water, from one equation. Pressure against temperature for water on a logarithmic pressure axis spanning 6.6 decades. The vaporisation curve is integrated from Clausius–Clapeyron between the triple point at 273.16 kelvin and 611.7 Pa and the critical point at 647.096 kelvin, with a single latent heat of 43.32 kilojoules per mole — the value the two published points on the curve imply. The measured latent heats are 45.05 at the triple point and 40.65 at the reference point, and the fitted value sits between them, because a constant latent heat is an average over the interval. The sublimation curve below the triple point is not measured but predicted, from the two latent heats adding where all three boundaries meet: 51.1 kilojoules per mole, which reaches 103.2 Pa at 253.1 kelvin against a measured 253.15. The melting curve is drawn at the slope Clapeyron gives it, -13.5 megapascals per kelvin, which is a volume ratio and nothing else: water's solid is 917 against 1000 kilograms per cubic metre for its liquid, so melting shrinks it and the line leans backwards. Across the whole 6.6 decades of this axis that line moves 5.2 kelvin, and one atmosphere shifts the melting point by 0.0075 kelvin. At 1 atmosphere the boundary is crossed at 373.1 kelvin, where water boils. The one place the curve fails is its top end: a constant latent heat reaches 37.4 MPa at the critical temperature where the measured critical pressure is 22.1 MPa, 70 per cent high, because the latent heat falls to zero at the critical point and this curve does not know that.

A boiling point is a pressure, not a temperature

Nothing about water names one hundred degrees; the air does. Where a liquid turns to vapour in its bulk is fixed by what pushes on it, which makes the familiar figure a coordinate on a curve — 71 °C on Everest, 119.5 °C in a sealed pot — and one latent heat draws the whole curve.

thermodynamics · Phase change A siphon's pressure, and the 10.09 m it cannot pass. The absolute pressure of the liquid along a siphon, from the upper surface, over the crown, and down to an outlet 1.2 m below the surface, for 4 crown heights. The profile is hydrostatic and depends on nothing but height: the tube's shape, its length and its bore do not appear. At the crown the liquid is below atmospheric pressure by ρg times the lift, and the whole question of how high a siphon can reach is whether that number stays above the liquid's vapour pressure — 2.34 kPa for water at 20 °C, which puts the ceiling at 10.09 m. a 2 m crown sits at 81.7 kPa and holds, a 6 m crown sits at 42.5 kPa and holds, a 9.5 m crown sits at 8.1 kPa and holds, a 11.5 m crown sits at -11.5 kPa and is below the vapour pressure, so it boils. The ceiling is a property of the liquid, not of the mechanism: a degassed liquid that can be pulled into tension has no such limit, and siphons in a vacuum.

The height a siphon cannot pass

A siphon will not lift water more than about ten metres, and the usual explanation for the limit is also given as the explanation for the mechanism. It cannot be both. A siphon runs in a vacuum, with degassed water, over a crown no atmosphere could support.

fluids · Hydrostatics The same block, one of them with no upthrust at all. Two identical blocks 0.8 m tall with their tops 1.2 m under the surface, drawn with the pressure on every wetted face at its true relative size. On the right the block is clear of the floor and the pressure on its underside exceeds that on its top by 7.8 kPa, which is ρgh and is exactly Archimedes' 7.8 kPa. On the left the bedding is perfect and there is no water under it, so nothing pushes up: the resultant is 11.8 kPa downward and the block presses on the floor with more than its own weight. Buoyancy is not something the fluid has. It is what the bottom face is doing, and a face the fluid cannot reach does nothing.

The block the water does not lift

A block bedded flat on the bottom of a tank, with no water underneath it, feels no upthrust at all. It is fully submerged, Archimedes' principle is not suspended, and it presses on the floor with more than its own weight — because buoyancy is not something a fluid has, it is what the bottom face is doing, and a face the water cannot reach does nothing.

fluids · Buoyancy Thrust against the air it is supposed to be pushing on. The thrust of one F-1 engine against ambient pressure, in atmospheres. It is 6.78 meganewtons at sea level and 7.77 in vacuum — 14.6 per cent more with the air taken away. The line falls at exactly 9.787 newtons per pascal, which is the nozzle's exit area, because the term is (p_e − p_a)·A_e: the ambient pressure pushes on the exit plane from outside and there is nothing to push back on it. The account in which the exhaust shoves against the atmosphere makes the opposite prediction — thrust falling with the pressure and vanishing in vacuum — and it is not a small disagreement about a coefficient. It has the sign wrong. A rocket works better in vacuum than in air, and every engine ever fired has said so.

The push that needs nothing to push against

A rocket engine produces more thrust in vacuum than at sea level — fifteen per cent more, for the engine drawn here, and the extra is exactly the ambient pressure times the nozzle's exit area. The account in which the exhaust shoves against the atmosphere does not merely overstate a coefficient. It has the sign wrong, and every engine ever fired has said so.

mechanics · Momentum A pore that lifts 100 m has to be 0.1 µm or finer. Capillary rise against pore radius, both logarithmic, for a liquid of surface tension 72.8 mN/m at a contact angle of 20°. The relation is a straight line of slope −1 — halve the pore and double the rise — and the two horizontal marks are the height in question, 100 m, and the 10.3 m that one atmosphere supports. 0.01 µm lifts 1394.7 m; 0.1 µm lifts 139.5 m; 1 µm lifts 13.9 m; 5 µm lifts 2.8 m; 20 µm lifts 69.7 cm; 50 µm lifts 27.9 cm. The conducting vessels of a tree are tens of microns across and lift under a metre; the pores in the membranes between them are tens of nanometres and would lift kilometres. Those are the same expression at two scales, and only one of them is a pipe.

The column that is pulled, not pushed

A capillary fine enough to lift a hundred metres is far too fine to carry any flow, and one wide enough to carry the flow lifts under a metre. Neither is how the water gets up a tree. The column is under tension — an absolute pressure of −0.88 MPa at the top, which a gas cannot have — held together by cohesion and prevented from tearing by pores a few tens of nanometres across.

fluids · Capillarity Melting curves, and the one that leans the wrong way. Melting temperature against pressure for water, benzene, naphthalene, each measured from its own melting point at one atmosphere, with pressure in bars. The slope of every coexistence line is the latent heat divided by the temperature and the change in volume, and the latent heat of melting is positive for everything — so the sign of the slope is the sign of the volume change, and nothing else. Almost everything expands on melting and its line leans forwards. Water's solid is less dense than its liquid, so its line leans backwards at 135 bars a kelvin: pressing on ice at just below zero melts it, and it takes 135 atmospheres to gain a single degree. The anomaly is not in the thermodynamics; it is in the fact that ice floats.

The melting curve that leans the wrong way

The slope of any coexistence line is the latent heat divided by the temperature and the change in volume. Latent heat is always positive, so the sign of the slope is the sign of the volume change — and for water the volume change is negative, which is the whole of why ice floats and why the melting curve leans backwards.

thermodynamics · Phase change The pair potential, and the two things it does to a gas. The Lennard-Jones potential between two molecules, in units of its own depth and range, with the Mayer function it produces at 1, 3, 8 times the well depth in temperature. The virial coefficient is minus the integral of that function over volume, so the two parts of the potential contribute with opposite signs: the steep repulsive core makes the function minus one there, giving a positive contribution — molecules take up room — and the attractive well makes it positive, giving a negative one. At low temperature the attraction dominates and a gas is easier to compress than an ideal one; at high temperature the core dominates and it is harder. Between them is one temperature at which they cancel.

The first correction to the gas law

An ideal gas has no forces between its molecules. The first correction to what it does is computable from those forces alone — one integral over the pair potential — and its sign flips at a temperature where a real gas obeys the ideal law without being ideal at all.

thermodynamics · Kinetic theory The wedge that proves it. A wedge of water 4 mm on its vertical side, at a depth of 3 m, with the pressure on each of its three faces as an unknown. The two force balances decide them. Horizontally, the sloping face's push has a component that must exactly cancel the vertical face's, and since the sloping face is longer by exactly the factor its slope reduces the component by, the two pressures are equal — the geometry cancels, at every angle, for every size. Vertically the same cancellation happens except for the wedge's own weight, which needs the bottom face to carry 0.0667 per cent more. That excess falls in proportion to the size of the wedge, so at a point it is nothing and the three pressures are one number. Pressure being the same in every direction is the conclusion of that argument, not an assumption in it.

The push that has no direction

That the pressure at a point in a still fluid is the same whichever way the surface faces is not a definition. It is a theorem, and its proof is an argument about how two kinds of force scale with size — which is also the exact statement of when it stops being true.

fluids · Hydrostatics What the plane between them carries. The stress transmitted across the plane halfway between two charges of 10 nC held 1 cm apart, against distance from the axis in units of the half-separation. For two like charges the field on that plane lies entirely in it — checked here rather than assumed — so the plane sees only the pressure across the lines, the stress is negative everywhere, and the two halves are pushed apart. For opposite charges the field on the plane is entirely perpendicular to it, the plane sees only the tension along the lines, the stress is positive, and the halves are pulled together. Faraday's two words for a field line, tension along it and pressure across it, are exactly these two curves; the whole content of the tensor is that they are the same quantity, ε₀E²/2, wearing two signs. The force is what is left after integrating either curve over the plane, and both integrals come to the same magnitude — the Coulomb force — which is the next figure.

The force read off a surface that touches nothing

Draw any closed surface through empty space, measure the field on it, and the sum of one expression over that surface is the total force on everything inside — whatever the contents are, and without knowing anything about them. The expression is Maxwell's stress tensor, and it turns Faraday's guess about tension along a field line into an exact statement.

electromagnetism · Field energy The pressure at which an oil becomes a glass. Viscosity against pressure for 4 liquids on a logarithmic axis, from Barus's rule with the pressure coefficient each one actually has. The rule is an exponential, so a gigapascal multiplies an ordinary oil's viscosity by a hundred million or more, and the curves cross the line conventionally taken to mark a glass — a million million pascal-seconds — at 1.37 GPa for a mineral oil, 0.98 GPa for a traction fluid. The vertical line is the peak pressure inside the loaded contact this figure is about, 1.32 gigapascals, computed from the Hertz solution for that geometry and load. Water is drawn for contrast: its pressure coefficient is thirty times smaller, it never approaches a glass over this range, and that is why it is useless as a lubricant in a rolling contact however clean it is. Each curve is drawn solid up to the glass line and dashed above it, because past that point the material is not a liquid and its viscosity is not what decides how it shears — the exponential continues, and the substance it was written for does not.

The oil that is a glass for a quarter of a millisecond

Every other account of viscosity here varies the temperature. Pressure does something larger and in the same direction for every liquid: viscosity rises exponentially, by a factor of ten to the eight or more at the gigapascal inside a loaded gear tooth. That is not a curiosity — it is the only reason there is a film there at all. Remove the pressure dependence from the calculation and the predicted film is five nanometres, under the roughness, and the surfaces touch.

fluids · Viscosity

Named alongside it

The objects these essays reach for when they reach for this one.

DensityEquilibriumSurface tensionBuoyancyHydrostatic equilibriumHydrostaticsTemperatureViscosityThe Boltzmann factorBoundary conditionsCapillarityCavitation

All concepts