Concept

Density — where it appears

Mass per unit volume, the quantity that decides whether a body floats and the one a compressible body changes as it descends. Comparing it with a fluid's settles flotation only when nothing else is holding the body — a surface, a seal or a wall can override it entirely.

Named by 13 essays across 3 fields — each of them below, with the objects they name alongside it.

Three vessels, one pressure. Three vessels filled to the same depth of 3 m. The pressure on each base is 29.4 kPa — identical, because pressure is set by depth — while the weight of water each holds differs by a factor of 4.7. The base of the flaring vessel carries more force than the water standing over it weighs.

The pressure that only knows depth

A litre of water and a swimming pool press equally hard on a floor at the same depth. Pressure in a still fluid is a scalar with no direction of its own, it depends on how far down and on nothing else, and the shape of the container falls out of the arithmetic entirely.

fluids · Hydrostatics
Where the upward force comes from. A block submerged with its top 1.2 m down. The pressure on the bottom face (19.6 kPa) exceeds that on the top (11.8 kPa) by exactly the weight of a column of water as tall as the block, and the sideways pressures cancel in pairs. Nothing has been added to the physics of pressure to get buoyancy out of it.

The weight of the water that is not there

A submerged object is pushed up by the weight of the fluid it has displaced — not by something like it, not approximately, but exactly. The reason is that the pressures on its faces do not cancel, and the sum that survives has forgotten everything about the object except its shape.

fluids · Buoyancy
The phase boundary of water, from one equation. Pressure against temperature for water on a logarithmic pressure axis spanning 6.6 decades. The vaporisation curve is integrated from Clausius–Clapeyron between the triple point at 273.16 kelvin and 611.7 Pa and the critical point at 647.096 kelvin, with a single latent heat of 43.32 kilojoules per mole — the value the two published points on the curve imply. The measured latent heats are 45.05 at the triple point and 40.65 at the reference point, and the fitted value sits between them, because a constant latent heat is an average over the interval. The sublimation curve below the triple point is not measured but predicted, from the two latent heats adding where all three boundaries meet: 51.1 kilojoules per mole, which reaches 103.2 Pa at 253.1 kelvin against a measured 253.15. The melting curve is drawn at the slope Clapeyron gives it, -13.5 megapascals per kelvin, which is a volume ratio and nothing else: water's solid is 917 against 1000 kilograms per cubic metre for its liquid, so melting shrinks it and the line leans backwards. Across the whole 6.6 decades of this axis that line moves 5.2 kelvin, and one atmosphere shifts the melting point by 0.0075 kelvin. At 1 atmosphere the boundary is crossed at 373.1 kelvin, where water boils. The one place the curve fails is its top end: a constant latent heat reaches 37.4 MPa at the critical temperature where the measured critical pressure is 22.1 MPa, 70 per cent high, because the latent heat falls to zero at the critical point and this curve does not know that.

A boiling point is a pressure, not a temperature

Nothing about water names one hundred degrees; the air does. Where a liquid turns to vapour in its bulk is fixed by what pushes on it, which makes the familiar figure a coordinate on a curve — 71 °C on Everest, 119.5 °C in a sealed pot — and one latent heat draws the whole curve.

thermodynamics · Phase change
Everything is decided against one line at 9.76 K per kilometre. Temperature against height for five environments, with the dry adiabat drawn heavy. A parcel lifted from the ground cools along the adiabat, at g/c_p = 9.76 K/km — a number with no meteorology in it, only gravity and the heat capacity of air. If the environment cools faster than that, a lifted parcel finds itself warmer than its surroundings and keeps going; if it cools more slowly, the parcel finds itself colder and sinks back. -5 K/km gives N² = 5.02e-4 s⁻², a period of 4.7 min; 0 K/km gives N² = 3.32e-4 s⁻², a period of 5.7 min; 6.5 K/km gives N² = 1.11e-4 s⁻², a period of 9.9 min; 9.8 K/km gives N² = -1.43e-6 s⁻², an e-folding time of 835 s; 12 K/km gives N² = -7.63e-5 s⁻², an e-folding time of 114 s. The classification is a comparison of two slopes and nothing else: no density appears in it, and the same cold air is stable under one profile and unstable under another.

The layer a parcel cannot leave

Whether a column of air overturns is not decided by its density but by a difference of two gradients — the rate the environment cools with height, and the rate a lifted parcel cools on its own. Subtract one from the other and what is left is a restoring force per unit displacement, so a stable atmosphere rings at a period of minutes and an unstable one has no period at all.

fluids · Stratification
The distance that does not know how big the moon is. How close a satellite held together by its own gravity can orbit before the tide pulls it apart, in units of the primary's radius, against how much denser the primary is than the satellite. The curve is the distance at which the tidal stretch across the satellite's own body equals the satellite's surface gravity. Setting those two equal cancels the satellite's radius on both sides, so a boulder and a thousand-kilometre moon of the same material break up at exactly the same distance — the limit is a ratio of densities and nothing else, and it goes as the cube root of that ratio, measured here as 0.3333. For ice around a planet of density 687 kg/m³ the rigid limit is 1.15 radii and the limit for a body that can deform under the tide is 2.23, because a satellite pulled into an egg presents a longer body to the tide and gives way sooner. Saturn's rings end at 2.27 radii, just outside that second number, and its innermost round moon orbits at 3.08 — so the boundary between a ring and a moon falls where this calculation puts it. What this calculation leaves out is strength: a body small enough for its material strength to beat its own gravity ignores the limit entirely, which is why Phobos is well inside Mars's and still in one piece, and why the Shoemaker–Levy fragments were held together by nothing at all.

The distance that forgets the moon

A satellite held together by its own gravity comes apart if it orbits too close, and the distance at which it does contains no reference to its size. Both the tide pulling it apart and the gravity holding it together are proportional to its radius, so the radius cancels twice over and what is left is a ratio of two densities.

astrophysics · Self-gravity
Melting curves, and the one that leans the wrong way. Melting temperature against pressure for water, benzene, naphthalene, each measured from its own melting point at one atmosphere, with pressure in bars. The slope of every coexistence line is the latent heat divided by the temperature and the change in volume, and the latent heat of melting is positive for everything — so the sign of the slope is the sign of the volume change, and nothing else. Almost everything expands on melting and its line leans forwards. Water's solid is less dense than its liquid, so its line leans backwards at 135 bars a kelvin: pressing on ice at just below zero melts it, and it takes 135 atmospheres to gain a single degree. The anomaly is not in the thermodynamics; it is in the fact that ice floats.

The melting curve that leans the wrong way

The slope of any coexistence line is the latent heat divided by the temperature and the change in volume. Latent heat is always positive, so the sign of the slope is the sign of the volume change — and for water the volume change is negative, which is the whole of why ice floats and why the melting curve leans backwards.

thermodynamics · Phase change
A body at an interface, and the difference that holds it. The net upward force on a ten-centimetre cube straddling the boundary between two fluids, against how far its underside sits below that boundary — each curve scaled by its own largest value so that three very different cases fit on one axis. The displaced weight has to be counted twice, once with each density, so the force is linear in the displacement with a stiffness set by gravity, the cube's cross-section and the difference of the two densities — the difference, and neither of them alone. air over water holds the cube with its underside 60 per cent of the way through, at a stiffness of 97.8 newtons per metre; oil over water holds the cube with its underside 47 per cent of the way through, at a stiffness of 14.5 newtons per metre; water over mercury holds the cube with its underside 24 per cent of the way through, at a stiffness of 1229.4 newtons per metre. Both numbers are read off the drawn curve rather than substituted. The consequence is the one worth the figure: a body at an oil–water interface is held six times less stiffly than the same body at an air–water one, because the density difference is six times smaller, and the ordinary intuition that a denser fluid holds a body more firmly is exactly wrong — what matters is the contrast across the surface the body is sitting in.

The body that displaces two things

Every earlier argument has a body wetted by one fluid, so the displaced weight is a volume times a density. A body at an interface displaces two, and what holds it is the *difference* between them — so the same block is held six times less stiffly at an oil–water boundary than at an air–water one. In a continuously stratified column the neutral depth becomes stable, which is the exact opposite of the compressible case.

fluids · Buoyancy
Water gets denser the deeper it is. The density of seawater at 0 °C and a salinity of 35 against depth, from the surface to the 10.99 km of the Challenger Deep, with the pressure integrated down the column from the equation of state rather than assumed. At the surface it is 1028.1 kg/m³. At the ocean's mean depth of 3.68 km it is 1045.3, 1.67 per cent more; at the bottom of the deepest trench it is 1076.5, 4.71 per cent more. An incompressible ocean would be the vertical line. The curve is almost straight; what curvature it has, too little to see here, is the water stiffening as it is squeezed: its secant bulk modulus rises by 3.24 pascals for every pascal of pressure.

The sea that stands lower because water gives

Water is the textbook incompressible fluid, and at the bottom of the ocean it is 4.7 per cent denser than at the top. That squeezing lowers the whole sea by about thirty metres, adds the weight of 266 metres of water to the pressure in the deepest trench, and speeds sound up so steadily with depth that it digs a channel in which a low note can cross an ocean.

fluids · Hydrostatics
The thin parcel that keeps sinking. A parcel pushed one centimetre down a column in which heat stabilises and salt destabilises, with a density ratio of 2, integrated for three hours, for parcels whose pattern of sinking and rising water repeats every 2 m, 20 cm, 6 cm. The 2 m parcel keeps its heat and its salt and swings back and forth with the buoyancy period of 23.6 minutes. The 20 cm parcel crosses its starting level 8 times while its swing dies away, and is left sinking slowly, at the 0.48 e-folds an hour its width allows; the 6 cm parcel never comes back and passes five centimetres below it after 60 minutes. The thinnest loses its heat to its surroundings in 11 minutes and its salt in 18 hours, so it arrives salty and cooled, heavier than the water around it, and runs away at 2.33 e-folds an hour — the rate the linear dispersion relation gives for that width.

The salt that sinks through a stable sea

Warm salty water lying on cold fresh water is heavier at the bottom at every depth, and by every test of static stability it should stay where it is. It does not. Heat leaks sideways out of a thin tongue of sinking water a hundred times faster than salt does, so the tongue arrives cooled and still salty — heavier than its new surroundings — and keeps going. A column can be stable by density and unstable by diffusion, and most of the subtropical ocean is.

fluids · Stratification
The melting line of water, through five ices. The pressure at which water freezes, in megapascals on a logarithmic axis, against temperature, along each of the five solid phases that meet the liquid, from the international standard equations. Along ordinary ice, Ih, the melting pressure rises as the temperature falls, from 611 Pa at 273.16 K to 209 MPa at 251.165 K — the backwards slope of the familiar melting line. There the liquid meets ice III, and from then on every ice melts at a higher pressure as the temperature rises: ice V, ice VI, and ice VII, which reaches 20.6 GPa at 715 K. The dots are the four triple points where two ices and the liquid coexist. The lowest temperature at which liquid water can exist in equilibrium, 251.165 K, is at the first of them.

The melting line that turns round

Squeeze water and it freezes at a lower temperature — the backwards slope of its melting line, and the reason ice floats. Keep squeezing and the slope reverses. Past two thousand atmospheres ordinary ice gives way to a denser ice, then another, and from there on every ice melts at a higher temperature under more pressure, exactly as a normal substance's does. At twenty thousand atmospheres water freezes into an ice that is still solid at a hundred degrees Celsius; at two hundred thousand, one still solid at four hundred. The famous anomaly belongs to one ice out of five, and the same relation that explained it explains its end.

thermodynamics · Phase change
Why the mixture of two equal waters is heavier than either. A temperature–salinity diagram for seawater near the surface, with lines of equal density (curves) 0.3 kg/m³ apart. Two waters lie on the same line: one at 4 °C and 33.93 g/kg, the other at 16 °C and 36.53 g/kg, both 1026.00 kg/m³. Mixing them in any proportion moves along the straight line between them, because temperature and salt add linearly; the lines of equal density curve, because cold water's density responds less to temperature than warm water's. The straight line lies on the dense side of the curve. An even mixture, at 10 °C and 35.23 g/kg, is 0.182 kg/m³ denser than either parent, and sinks between them.

The mixture heavier than either water

Two bodies of seawater can have exactly the same density — one cold and fresh, one warm and salty — and sit side by side without either wanting to sink. Mix them, and the mixture is denser than both, and sinks. Nothing has been added and nothing removed; the extra weight comes from the fact that water's density is a curved function of temperature while mixing averages temperature in a straight line. The same curvature, at its most extreme, is why a lake overturns twice a year and freezes from the top, and why the open ocean, too salty to have a density maximum above freezing, does neither.

fluids · Stratification
Where the level goes when a floating ice cube melts. The change in level when a 30 g ice cube floating in a glass 7 cm across has melted completely, against the density of the liquid it floats in (the liquid must be denser than ice, 917 kg/m³, or the cube sinks). In fresh water the level does not move: the meltwater exactly fills the volume the ice displaced. In seawater it rises 0.21 mm and in saturated brine 1.3 mm, because the ice was displacing a denser liquid than it melts into; in castor oil, which is lighter than water and does not mix with it, the level falls 0.32 mm as the meltwater sinks beneath the oil. The change is the meltwater's volume minus the displaced volume, m/ρw − m/ρ, spread over the glass.

The floating ice that still raises the sea

An ice cube melting in a glass of water leaves the level exactly where it was, and the reason is exact: a floating body displaces its own weight, and the meltwater has that weight. The same argument is often used to say that melting sea ice and ice shelves cannot raise the sea. It nearly works. The ice was floating in salt water and melts into fresh, which is lighter, so the meltwater overfills the hole by almost three per cent — and the ice that really fills the sea is the part of a grounded glacier above the thickness at which it would float.

fluids · Buoyancy
The height at which hot air stops being light enough. Lift per cubic metre of hot air against height in the standard atmosphere, with the inside at 100 °C and 120 °C, and (dashed) what a 2800 m³ balloon carrying 550 kg plus its envelope needs per cubic metre, 0.241 kg. As the balloon climbs, the outside air thins, and although it also cools — which improves the temperature ratio — the density wins: lift per cubic metre falls by about a tenth for every kilometre. The balloon can climb only to where the curve crosses its need: 6.0 km with the envelope at 120 °C. Above the tropopause the outside temperature stops falling and the lift falls faster still; a hot-air balloon that reaches the stratosphere needs an envelope enormous compared with its load.

The balloon a cold morning lifts

A hot-air balloon is open at the bottom, so the air inside is at the same pressure as the air outside and lighter only because it is hotter. Its lift is the outside air's density times one minus the ratio of the two absolute temperatures — a small number, a third of a kilogram per cubic metre at best — and since the fabric cannot be heated much above a hundred degrees, the lift depends as much on the cold outside as on the heat inside. That is why balloons are the size of houses, why they fly at dawn, why each has a ceiling, and why the pilot must burn for where the balloon will be half a minute from now.

fluids · Buoyancy

Named alongside it

The objects these essays reach for when they reach for this one.

BuoyancyEquilibriumHydrostatic equilibriumPressureStratificationArchimedes principleEquation of stateStabilityCompressibilityDisplaced volumeFree surfaceInstability

All concepts