The arrow of time
Collisions are easier than forces, and momentum is the reason
Nobody knows what happens inside a collision. Momentum conservation makes that ignorance irrelevant, which is the whole trick — and energy, deliberately, is not conserved.
Entropy is a count, and the arrow of time is arithmetic
Nothing in mechanics prefers a direction. Entropy is not a force pushing things toward disorder — it is the observation that some outcomes have vastly more ways of happening than others.
The ceiling on every engine, set before it was designed
There is a maximum efficiency no heat engine can exceed, and it depends on nothing but two temperatures. Not the fuel, not the working substance, not the cleverness of the engineer.
The hill that gives it back, and the forces that do not
Potential energy turns a question about motion into a picture of a landscape. It works for gravity and springs, it fails for friction, and the difference between those two cases is the whole of what makes energy useful.
The frequency that gets an answer, and the quarter cycle nobody mentions
Push an oscillator at its own frequency and the response grows enormously. The reason is not that the push is in step with the motion — at resonance it is a quarter cycle out, and that is precisely why it works.
The equation that only runs forwards, and the walk underneath it
A drop of ink spreads and never gathers. The equation describing it is one of the few in physics that is not reversible — and underneath it is nothing but a coin being tossed.
The packet that moves at another speed than its own crests
Watch a group of water waves and the individual crests run forward through it, rise in the middle, and vanish off the front. The group travels at half the speed of the crests, and both numbers are real.
The heat that changes no temperature, and where it actually goes
A kettle reaches a hundred degrees in a minute and takes five more to boil dry. The heat going in during those five minutes changes nothing a thermometer can see, and it is most of the energy in the whole process.
A nucleus with no clock
A half-life is a precise number and no individual nucleus has one. Each has the same chance of decaying in the next second as it had on the day it formed, and the exponential curve is a property of the population rather than of any member of it.
The entropy that lives on a surface
Throw a cup of tea through a horizon and the entropy of the outside world falls. Either the second law is wrong or the horizon has an entropy of its own — and the only quantity available for it turns out to be its area, in units of a length made from gravity, quantum mechanics and the speed of light together.
The exponential that decides everything
Maximising the number of ways a reservoir can arrange what is left after taking E out of it gives one factor, e to the minus E over kT. Its exponent is a ratio, which is why a barrier of a third of an electronvolt — nothing at all by chemical standards — is the difference between instantly and never.
What a system actually minimises
A ball falls to the bottom of a bowl and a gas fills a room, and neither of those is the rule. A system in contact with a large reservoir minimises U − TS, and the minus sign is the reservoir's own entropy written in the system's variables — which is why a rubber band pulls harder when it is heated.
How far a wave can remember
Split a beam, delay one half, and put them back together. The fringes are bright while the delay is short and fade as it grows, and the distance at which they die is fixed by nothing but the width of the source's spectral line. Watching them fade is reading the line shape.
The packet that will not keep its shape
A group velocity is only the first thing a dispersion relation says. The second is that the packet spreads — at a rate fixed by its own bandwidth and by the curvature of ω(k) — so a short pulse comes apart quickly and a long one hardly at all. It is a trade quantum mechanics is usually given credit for, and classical waves make it too.
The engine that pays back more than it takes
Carnot's argument puts a ceiling on how much work a flow of heat can be made to do. Run the same cycle backwards and the ceiling inverts into a floor that is greater than one — so a machine can deliver three or four joules of heat for every joule it consumes, and a perfectly efficient electric heater is the worst way to warm a room.
The three ways of coming to rest
An oscillator with friction in it can swing and fade, arrive and stop, or crawl back so slowly it looks stuck. One equation and one number decide which. The number is not what most people would guess, and neither is the value that returns fastest.
The magnet that falls slowly
Drop a magnet down a copper pipe and it takes several seconds to fall a metre, drifting rather than falling. Nothing touches it, the copper is not magnetic, and there is no circuit anywhere. The pipe arrives warm.
The mass that makes another stand still
Bolt a small mass on a spring to a machine that is shaking itself apart, tune it to the frequency that is doing the damage, and the machine stops moving. Not moves less — stops, exactly, at that one frequency. The price is two new resonances either side of it, and the whole device is a bet that the drive stays where it was put.
The viscosity that does not care how much gas there is
Pump most of the air out of a vessel and the air that is left is exactly as viscous as it was. Maxwell derived that in 1860, did not believe it, and spent six years building an apparatus to measure it — which is a better description of how a prediction becomes knowledge than any amount of agreement would have been.
The ring the drop leaves behind
A drop of coffee dries into a ring rather than a disc, and nothing about coffee is responsible. The pattern is produced by a boundary condition — an edge that cannot move — and it survives replacing the coffee with anything else that will stay suspended.
The size the light cannot blow away
Radiation pressure and gravity both fall as the inverse square of distance, so their ratio is a property of the grain and not of where it is. What follows is a band of sizes that get blown out — with a lower edge as well as an upper one — and a drag, on everything else, that is the same pressure read one order further in v/c.
The magnet that has to fight its own field
A bar magnet's own poles put it in a reverse field, so the same material cut short and fat is weak and cut long and thin is strong. And a magnetised material does not have a magnetisation — it has a magnetisation and a history, which is why the word for what it does is the Greek for coming late.
The liquid that remembers
Pitch shatters like glass under a hammer and flows through a funnel over a decade. Neither behaviour is the true one. What decides which a substance shows is not the substance but the length of the observation, and the ratio between the two has a name and a number.
The orbit that has to shrink
Two masses in orbit radiate gravitational waves and lose energy, so the orbit tightens, so they go faster and radiate harder. The runaway takes 10²³ years for the Earth and the Sun and eight minutes for the last thousand kilometres of a black-hole pair — and the same one-line formula gives both.
The ball of gas that heats up as it cools
Take energy away from a self-gravitating cloud and its temperature rises. Its heat capacity is negative, which nothing else stable does, and the consequence is that a star radiating into cold space is not cooling down — it is running up, and its whole life is a slow fall it cannot stop.
The rotation a return trip doubles
Quartz turns the plane of polarisation and so does glass in a magnetic field. The two look identical on the way through and are opposites on the way back — the crystal undoes its own rotation exactly, and the magnet adds to it. That difference is the whole of why a one-way street for light can be built at all, and why nothing passive will ever be one.
The measurement that never touched it
A balanced interferometer sends every photon to one output and none at all to the other. Put an object in one arm and the empty port starts clicking — and a click there is caused by a photon that cannot have gone near the object, because a photon that goes near it is absorbed. The object has been found by light that never met it.
The bit that has to be paid for
One molecule in a box, a partition, and the knowledge of which side it went — enough, between them, to extract work from a single reservoir, which the second law forbids. The engine is real and the arithmetic is right. What closes the loophole is that the cycle does not finish until the knowledge has been thrown away, and throwing away one bit costs exactly what the expansion delivered.
The engine that has to finish
Carnot's ceiling is exact and it is reached only by an engine that takes for ever, because a reversible heat flow needs a vanishing temperature difference to drive it. Ask instead for the most power rather than the most work per joule of heat, and the answer is a different function of the same two temperatures — and three measured power stations sit on it rather than on the ceiling.
The glow that says nothing about the surface
A thermal camera pointed at a saucepan of boiling water reads a hundred degrees. Pointed at a polished aluminium block at the same temperature it reads about twenty-five, and the instrument is working perfectly. What it is measuring is emissivity as much as temperature — and a surface's emissivity is forced to equal its absorptivity, at every wavelength and every angle, by an argument with no physics of matter in it at all.
The knot the field cannot untie
A perfectly conducting fluid cannot change which field line joins which piece of it. So two flux systems pushed together may be squashed indefinitely and can never merge, and the energy of the squashing accumulates with nowhere to go. The release happens only where the perfect conductivity locally fails — in a sheet three metres thick inside a structure ten thousand kilometres across — and the rate that follows is a hundred thousand times too slow for the flares that are observed.
The entropy that is still there at zero
The third law says a perfect crystal has no entropy at absolute zero. Ice has 3.41 joules per kelvin per mole left over, and the number can be recovered from one line of counting — two hydrogens near each oxygen and two far, six legal arrangements out of sixteen, R ln(3/2). The law has an escape clause and the escape clause is measurable.
The mass no cold matter can hold up
A white dwarf gets smaller as it gets heavier, which no ordinary object does. Follow that curve upward and the radius reaches zero at 1.46 solar masses — because once the electrons are relativistic the pressure goes as the four-thirds power of the density, and for that exponent alone the mass of a self-gravitating ball does not depend on its radius at all.
The answer that cannot come first
A medium absorbs at some frequencies and bends light at all of them, and those look like two separate facts to be measured separately. They are one fact. The requirement that a material respond after it is asked rather than before ties the absorption at every frequency to the refraction at every other, by an integral — and a material given the two halves independently answers before the question arrives.
What it costs to take the salt out
Salt dissolves in water because mixing is overwhelmingly the more probable arrangement, and separating the two again means paying back what the mixing gave away. The bill can be computed before any apparatus is chosen — 0.79 kilowatt-hours for the first cubic metre from seawater — and it rises with every further cubic metre taken, because what is left behind is saltier than what was started with.
The thickness that goes both ways
Heat a liquid and it thins; heat a gas and it thickens. The two are not a strong effect and a weak one but opposite signs, differing by a factor of thirty in size as well — and the word viscosity names one measurement made on two mechanisms that have almost nothing in common.
The light that takes a hundred thousand years to leave
A neutrino made in the Sun's core is at the surface in two and a third seconds. A photon made beside it takes something like a hundred thousand years, through the same material, over the same seven hundred thousand kilometres — and the whole of the difference is one length, entering the answer squared.
Hotter than any temperature there is
A system whose energy has a ceiling can be pushed past the point where adding energy adds entropy. Its temperature is then negative — and negative temperatures are not cold. They sit above every positive temperature on the only scale that decides which way heat flows, and a working laser is at one.
The wave that dies with nothing to rub against
Every damping in this collection so far removes energy from a wave and puts it somewhere warmer. This one removes it and produces no heat at all: there are no collisions in the equation, the entropy is unchanged, the whole thing runs backwards perfectly, and the wave still dies exponentially. What it dies into is structure in velocity too fine for a field to see.
The two equations that are not laws of motion
Maxwell's equations are usually presented as four laws of equal standing. Two of them contain no time derivative at all, which means they cannot be evolution equations: they are conditions on the field at one instant. What makes them consistent with the other two is that the other two preserve them exactly — and one of the two preservations holds only because charge is conserved.
The second experiment that cannot disagree
Heat one end of a wire and a voltage appears across it. Pass a current through the same wire at uniform temperature and it carries heat. Those are two different experiments with two different apparatus, and the coefficient in front is the same number in both — not approximately, and not for some materials. The reason is that the equations of motion underneath look the same run backwards.
Swap the ends and nothing changes
Put a source at one end of the most complicated arrangement of materials anybody can build and a detector at the other, then exchange them. The reading is identical — not approximately, not on average, but to every digit the arithmetic has. Two things in physics break it, and neither of them is a shape.
The summer that reaches the cellar in December
Drive the diffusion equation at its boundary instead of releasing something into it and the solution is a decaying, lagging oscillation with a single length in it. That length governs both the shrinking and the delay, which is why the depth at which the ground is coldest in August is fixed by the same number as the depth at which the seasons stop being felt at all.
The big one comes to the top
Shake a jar of mixed grains and it sorts itself, which is the opposite of what shaking a mixture of gases does. There is no thermodynamic paradox in it because there is no temperature to speak of — and the mechanism is a piece of geometry with an exact number in it: a sphere fits through the gap between three touching spheres only below a radius ratio of 0.1547.
The second law, with a probability attached
Entropy increases, on average. For a small system pulled quickly, individual runs go the other way — and how often is not a matter of taste but an exact number, fixed by a relation with no adjustable constant in it and no requirement that anything be near equilibrium.
The hole that outlives everything and then does not
A black hole radiates at a temperature that rises as it shrinks, so losing energy makes it lose faster. The whole history follows from that one sign: a life proportional to the cube of the mass, nearly nothing happening for almost all of it, and an end that arrives in a second.
The axis a leak of energy chooses
A body spinning with nothing pushing on it keeps its angular momentum exactly, and keeps its kinetic energy only while nothing inside it flexes. At fixed momentum the energy is least for a spin about the axis of greatest inertia — so any leak, however small, has a destination. The first American satellite found this out in orbit.
The engine a fluctuation cannot run
A ratchet lets a shaft turn one way and not the other. Put a paddle in a gas on the same shaft and molecular collisions appear to become a lifted weight — an engine running on one reservoir. It does not work, and following exactly why turns the second law from a prohibition into a mechanism: the pawl is as warm as the gas, and it lifts whenever it is asked to.
The area that is not allowed to shrink
Two black holes merge and the result weighs less than the sum, because three solar masses left as gravitational waves. The horizon area went up by more than half. Mass is the quantity that behaves like energy and it is not the one with a direction; area is, and the theorem saying so has been tested against a real merger.
The pile that is never finished settling
Tap a jar of grains and it settles. Keep tapping and it goes on settling — logarithmically, so that each factor of ten in the number of taps buys the same small improvement as the last. There is no number of taps after which the column is packed; there is only a number after which the next improvement is too small to measure, and the asymptote everyone quotes is a fitted number rather than a measured one.
The solution that is thrown away
Maxwell's equations admit a field that converges on a charge exactly as readily as one that leaves it, and nothing in them prefers either. Retardation is a boundary condition rather than a law. Which boundary condition is right has been argued about for a century, one of the answers makes the arrow of time a property of there being absorbers, and the laboratory version of the question — whether an atom emits at all — has a measured answer that depends on what is listening.
Nothing keeps a magnetisation for ever
A magnetised particle sits in a well with a barrier between it and the other direction, and a barrier of finite height is crossed eventually. So remanence has a lifetime, coercivity is a different number depending on how fast it is measured, and a grain below about twenty nanometres of iron forgets within a second at room temperature.
The ring that does not come back
Every picture of a passing gravitational wave shows a ring of free masses stretched, squeezed and let go. The last frame is wrong. The ring ends a different shape — permanently, with the masses at rest at new separations — by about a fifth of the largest distortion the wave itself produced. What sources the offset is the energy the wave carried away, so the wave is remembering itself, and nobody has measured it.
The wall that moves while the ball is in flight
Energy is conserved because the rules do not depend on the time. Move the walls of a box and the rules do depend on the time, so what is inside gains or loses without limit — and how much depends entirely on how fast. Moved slowly, a wall takes energy at exactly the rate the adiabatic law says; moved faster than the ball travels, it takes none at all, and the same box is a piston or a vacuum according to a speed.
The count that no observer can disagree about
A moving body, it turns out, has no temperature. What it does have is an entropy, and every observer agrees about it — because entropy is the logarithm of a count of arrangements, and a count is a number. That one invariant, with energy and momentum being parts of one object, is enough to compute everything a temperature could not: what happens to the energy density, the entropy density, and the relation between them that having a temperature consists of.
The column that is hotter at the bottom
Two bodies in equilibrium have the same temperature — that is what equilibrium was supposed to mean. In a gravitational field it is false. A column left alone until nothing in it changes is warmer at the bottom by exactly the factor by which clocks there run slow, a part in ten million billion per metre on the Earth and more than a per cent across the outer kilometre of a neutron star, and near a black hole's horizon the equilibrium temperature grows without limit.