Concept

Meniscus — where it appears

The curved surface a liquid takes where it meets a solid wall, whose shape is set by the contact angle and by the balance of surface tension against gravity. Its curvature is what supplies the pressure difference that drives capillary rise.

Named by 5 essays across one field — each of them below, with the objects they name alongside it.

Four tubes, four heights. Water in tubes of radius 0.2, 0.4, 0.8, 1.6 mm, with each meniscus drawn as the spherical cap a 20° contact angle forces and each height computed from it. The narrowest rises 70 mm and the widest 9 mm — in inverse proportion to the radius, with nothing about the glass or the volume of water entering it.

How high water will climb

Water rises up a narrow tube against gravity, and the narrower the tube the higher it goes. The height is set by a curved surface pulling on a circumference while gravity pulls on an area, and the two scale differently — which is the whole of it.

fluids · Capillarity
One line decides whether it climbs for ever. The wetting condition for a corner, drawn as a map. The horizontal axis is the corner's half-angle and the vertical axis the liquid's contact angle with the walls; the diagonal is θ + α = 90°. Below it the meniscus in the corner curves into the liquid, the capillary pressure grows without bound as the corner narrows, and the liquid wicks along it indefinitely. Above it the curvature has the other sign and the liquid stays put. The boundary is tested by evaluating the meniscus a millionth of a degree either side of it at seventeen half-angles, and it wicks on one side and not the other every time. water on clean glass, right-angled corner: α = 45°, θ = 5° — wicks; water on glass, a 20° groove: α = 10°, θ = 40° — wicks; water on plastic, right-angled corner: α = 45°, θ = 75° — does not. A right-angled corner needs a contact angle under 45°, which water on clean glass has and water on most plastics does not.

The corner a liquid never stops climbing

A narrow tube lifts a liquid to a definite height because it has a smallest width. A corner has none, so the capillary suction it can develop is unbounded — and whether the liquid takes advantage is decided by a single inequality between the contact angle and the corner's own angle.

fluids · Surface tension
Like menisci attract, unlike menisci repel. Cross-sections of a water surface with two small floating bodies, drawn with menisci of the shape K₀(r/ℓc) that a small floater makes, exaggerated vertically. Left: two light bodies, each pulling the surface up round itself as buoyancy pushes it up against the surface; each sits on the other's slope and is drawn towards it, as a bubble rises — the two climb together. Right: a light body that raises the surface beside a heavy one that depresses it; each sits on the other's slope the wrong way and they drift apart. The deformations reach a few capillary lengths, 2.71 mm for water, and the rule is the whole of the Cheerios effect: cereal clumps, and cereal gathers at the wall of a bowl the milk wets.

The cereal that gathers at the edge of the bowl

The last few pieces of cereal in a bowl of milk clump together and drift to the side of the bowl. Nothing is pulling on them but the milk's surface. Each floating piece bends the surface round itself, and a second piece sitting on that bend has somewhere to slide: like menisci attract, unlike menisci repel, and the reach of the force is a few capillary lengths, 2.7 millimetres for water. The arithmetic is the arithmetic of charged lines in two dimensions, screened by gravity, and it says why leaves gather on a pond, why bubbles on coffee drift to the cup's rim, and why particles smaller than about ten micrometres do not clump this way at all.

fluids · Capillarity
A floating needle and the water it displaces. A cross-section of a steel darning needle 1.36 mm thick (density 7.85) floating on water, with a contact angle of 100°, its meniscus computed from the balance of surface tension and pressure; one capillary length is 2.73 mm. The needle's centre sits 1.43 mm below the undisturbed surface, and the water meets it 117° from the top, sloping at 37°. Two regions of water have been displaced. Below the level, under the needle, a region whose weight — 21 per cent of the support — is what pressure on the needle's underside supplies. Beside it, the two dents in the surface, whose weight — the other 79 per cent — is exactly the vertical pull of surface tension along the two contact lines. Together they weigh what the needle weighs: Archimedes, counting the dent.

The water the dent displaces

A steel needle laid carefully on water floats, and the usual explanation is that surface tension holds it up instead of buoyancy, as though the two were rival mechanisms. They are not rivals. The needle presses a dent into the surface, and the upward pull of surface tension along its edges is exactly the weight of the water missing from that dent. Archimedes' principle holds without amendment: a floating needle displaces its own weight of water. Most of that water is simply not underneath it.

fluids · Buoyancy
A drop in a tapered tube. A section through a glass tube tapering from 1.2 mm to 0.2 mm in radius over 60 mm, holding a 2 μL plug of water (contact angle 20°), not to scale across. Both menisci curve into the empty tube, so the water just inside each is below atmospheric pressure — by 269 Pa at the narrow end, radius 0.50 mm, and by 252 Pa at the wide end, radius 0.54 mm. The pressure is lower at the narrow end, so the water flows towards it: a net push of 17 Pa, with no gravity, no pump and no motion of the tube.

The drop that runs to the narrow end

Put a drop of water into a glass tube that narrows towards one end and it moves, on its own, towards the narrow end — horizontally, with nothing pushing it. Francis Hauksbee reported it to the Royal Society in 1712, and the explanation is two curved surfaces pulling with different strengths: each meniscus lowers the pressure of the water behind it by an amount that grows as the tube narrows, so the end in the narrower part sucks harder. A drop of mercury, which does not wet glass, goes the other way. Which way a drop goes depends on the cosine of one angle, and, for a short drop, on its length.

fluids · Capillarity

Named alongside it

The objects these essays reach for when they reach for this one.

Surface tensionCapillarityContact angleCapillary lengthLaplace pressureWettingArchimedes principleBessel functionBuoyancyContact angle hysteresisCurvatureGeometry

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