Concept

Curvature — where it appears

The second derivative of a potential at its minimum, the one number that sets the frequency of any small oscillation about it. Everything else about the potential's shape is invisible to a small oscillation, which is why unlike systems share an equation and why anharmonic effects need a larger amplitude to show.

Named by 7 essays across 5 fields — each of them below, with the objects they name alongside it.

The small bubble empties into the large one. Two soap bubbles of radius 4 mm and 12 mm joined by an open tube. The excess pressure inside each is 4γ/R — 72.8 Pa and 24.3 Pa — so the 4 mm bubble is at the higher pressure and blows itself into the other. The smaller a bubble gets the harder it pushes, so the process runs away rather than settling: there is no equilibrium anywhere except both bubbles equal.

The small bubble blows up the big one

Connect two soap bubbles of different size and the small one empties into the large one. Everybody expects the opposite, and the reason it happens is one equation with a radius in the denominator — which also means the process runs away rather than settling.

fluids · Surface tension
Which wavelength wins. The growth rate of a disturbance on a liquid thread against kR, the circumference divided by the wavelength. Everything to the right of one decays; the maximum sits at kR = 0.697, which is a wavelength of 9.01 radii or 4.51 diameters. That number, and not a property of any particular liquid, is what sets the spacing of the drops a tap breaks into.

The thread that cannot stay a thread

A stream of water from a tap breaks into drops, and it does so at a spacing that is always about four and a half diameters. Nothing chooses that number — it is the wavelength that grows fastest out of a competition between all of them, and it can be computed before any water is poured.

fluids · Surface tension
One parabola, several wells. Unlike potential wells, each divided by its own curvature at the bottom, against the single parabola ½x² drawn through all of them. They agree near the minimum because a function with a minimum has no linear term there, so the quadratic term is the first thing it has. The labels give where each well departs from the parabola by more than 1% of the parabola's own value there: a pendulum at 0.35, a chemical bond at 0.01, a pair of atoms at 0.0015. A symmetric well has no cubic term and stays close for a long way; a well that is steeper on one side than the other has one, and leaves the parabola almost at once — which is why those numbers differ by factors of hundreds and not by a few per cent.

Every minimum is a parabola

A pendulum, a bond between two atoms and a ship rolling in a swell obey the same equation, and the reason is not that they are alike. It is that a function with a minimum has no linear term there, so the first thing every potential well looks like is the same well.

mechanics · Harmonic approximation
Reflected upside down. A pulse arriving at a join where the impedance rises by a factor of 3, drawn at three moments. The amplitudes are read off the marched wave: the reflected pulse is -0.500 of the incident one and the transmitted pulse is 0.500, against (1−Z₂/Z₁)/(1+Z₂/Z₁) = -0.500 and 2/(1+Z₂/Z₁) = 0.500 from the two matching conditions. The reflection is inverted, which is the same fact as a pulse on a string flipping when it reaches a wall: a wall is a medium of infinite impedance, and the inversion is what keeps the displacement at the join equal to zero. Note that the transmitted amplitude exceeds one where the second medium is lighter, and that this is not a violation of anything: amplitude is not energy.

The equation that lets a shape travel

Newton's second law applied to a piece of string a millimetre long gives T·y″ = µ·ÿ, and the derivation never once asks what the string is made of. Two things fall out immediately: the speed is √(T/µ) and belongs to the medium, and the general solution holds two arbitrary functions rather than one. The second of them is the reflection, which is why a boundary condition can be met at all.

waves · Wave motion
A band 3.60 eV wide, and the curvature is the whole story. Energy against wavenumber for one tight-binding band, α + 2β·cos(ka), with α = -4 eV, β = -0.9 eV and a repeat of 300 pm. The band is 3.60 eV from floor to ceiling and periodic in k, so the zone boundary at ka = π is not an edge of anything: it is where the curve turns over. Near the bottom it is a parabola, which is the free-electron dispersion with a different coefficient — a mass of 0.470 m_e rather than one — and near the top it is a parabola the other way up, a mass of -0.470. The inflection between them is at ka = π/2, and it is the point at which a constant force stops producing any acceleration.

The mass a curve decides

An electron in a solid answers a force with a mass that is nothing to do with the mass of an electron. It is set by how sharply the band bends, it is smaller than the free value in a wide band and larger in a narrow one, and near the top of any band it is negative — which is why aluminium's Hall voltage has the sign of a positive carrier and no adjustment to an electron count can repair it.

quantum · Bands
Every speed there is, on one disc. The whole of velocity space drawn as a disc: the boundary is the speed of light and every possible velocity is a point inside. The rings are equal steps of rapidity — 0.5, 1, 1.5, 2, 2.5 — and they sit at speeds 0.4621, 0.7616, 0.9051, 0.9640, 0.9866 of light. Equal steps of rapidity crowd towards the edge, checked ring by ring, which is the same fact as speeds refusing to add: a boost is a fixed step in rapidity and a shrinking step in speed. The drawing is the Poincaré model, in which angles are true and distances are not — so a shape near the rim is drawn small and is not small, and the boundary is infinitely far away in the geometry although it is a finite circle on the page.

The space that speeds live in

Speeds do not add, and the reason is that the set of all possible velocities is not a flat space. It is a hyperbolic plane of curvature minus one in rapidity — and the rotation two boosts leave behind is exactly the area of the triangle they make in it.

relativity · Velocity addition
One line decides whether it climbs for ever. The wetting condition for a corner, drawn as a map. The horizontal axis is the corner's half-angle and the vertical axis the liquid's contact angle with the walls; the diagonal is θ + α = 90°. Below it the meniscus in the corner curves into the liquid, the capillary pressure grows without bound as the corner narrows, and the liquid wicks along it indefinitely. Above it the curvature has the other sign and the liquid stays put. The boundary is tested by evaluating the meniscus a millionth of a degree either side of it at seventeen half-angles, and it wicks on one side and not the other every time. water on clean glass, right-angled corner: α = 45°, θ = 5° — wicks; water on glass, a 20° groove: α = 10°, θ = 40° — wicks; water on plastic, right-angled corner: α = 45°, θ = 75° — does not. A right-angled corner needs a contact angle under 45°, which water on clean glass has and water on most plastics does not.

The corner a liquid never stops climbing

A narrow tube lifts a liquid to a definite height because it has a smallest width. A corner has none, so the capillary suction it can develop is unbounded — and whether the liquid takes advantage is decided by a single inequality between the contact angle and the corner's own angle.

fluids · Surface tension

Named alongside it

The objects these essays reach for when they reach for this one.

Dispersion relationLaplace pressureSurface tensionInstabilityNormal modesRestoring forceTaylor expansionAnharmonicityBand gapBloch waveBoostBoundary conditions

All concepts