Concept

Curvature — where it appears

The second derivative of a potential at its minimum, the one number that sets the frequency of any small oscillation about it. Everything else about the potential's shape is invisible to a small oscillation, which is why unlike systems share an equation and why anharmonic effects need a larger amplitude to show.

Named by 9 essays across 5 fields — each of them below, with the objects they name alongside it.

The small bubble empties into the large one. Two soap bubbles of radius 4 mm and 12 mm joined by an open tube. The excess pressure inside each is 4γ/R — 72.8 Pa and 24.3 Pa — so the 4 mm bubble is at the higher pressure and blows itself into the other. The smaller a bubble gets the harder it pushes, so the process runs away rather than settling: there is no equilibrium anywhere except both bubbles equal.

The small bubble blows up the big one

Connect two soap bubbles of different size and the small one empties into the large one. Everybody expects the opposite, and the reason it happens is one equation with a radius in the denominator — which also means the process runs away rather than settling.

fluids · Surface tension
Which wavelength wins. The growth rate of a disturbance on a liquid thread against kR, the circumference divided by the wavelength. Everything to the right of one decays; the maximum sits at kR = 0.697, which is a wavelength of 9.01 radii or 4.51 diameters. That number, and not a property of any particular liquid, is what sets the spacing of the drops a tap breaks into.

The thread that cannot stay a thread

A stream of water from a tap breaks into drops, and it does so at a spacing that is always about four and a half diameters. Nothing chooses that number — it is the wavelength that grows fastest out of a competition between all of them, and it can be computed before any water is poured.

fluids · Surface tension
One parabola, several wells. Unlike potential wells, each divided by its own curvature at the bottom, against the single parabola ½x² drawn through all of them. They agree near the minimum because a function with a minimum has no linear term there, so the quadratic term is the first thing it has. The labels give where each well departs from the parabola by more than 1% of the parabola's own value there: a pendulum at 0.35, a chemical bond at 0.01, a pair of atoms at 0.0015. A symmetric well has no cubic term and stays close for a long way; a well that is steeper on one side than the other has one, and leaves the parabola almost at once — which is why those numbers differ by factors of hundreds and not by a few per cent.

Every minimum is a parabola

A pendulum, a bond between two atoms and a ship rolling in a swell obey the same equation, and the reason is not that they are alike. It is that a function with a minimum has no linear term there, so the first thing every potential well looks like is the same well.

mechanics · Harmonic approximation
Reflected upside down. A pulse arriving at a join where the impedance rises by a factor of 3, drawn at three moments. The amplitudes are read off the marched wave: the reflected pulse is -0.500 of the incident one and the transmitted pulse is 0.500, against (1−Z₂/Z₁)/(1+Z₂/Z₁) = -0.500 and 2/(1+Z₂/Z₁) = 0.500 from the two matching conditions. The reflection is inverted, which is the same fact as a pulse on a string flipping when it reaches a wall: a wall is a medium of infinite impedance, and the inversion is what keeps the displacement at the join equal to zero. Note that the transmitted amplitude exceeds one where the second medium is lighter, and that this is not a violation of anything: amplitude is not energy.

The equation that lets a shape travel

Newton's second law applied to a piece of string a millimetre long gives T·y″ = µ·ÿ, and the derivation never once asks what the string is made of. Two things fall out immediately: the speed is √(T/µ) and belongs to the medium, and the general solution holds two arbitrary functions rather than one. The second of them is the reflection, which is why a boundary condition can be met at all.

waves · Wave motion
A band 3.60 eV wide, and the curvature is the whole story. Energy against wavenumber for one tight-binding band, α + 2β·cos(ka), with α = -4 eV, β = -0.9 eV and a repeat of 300 pm. The band is 3.60 eV from floor to ceiling and periodic in k, so the zone boundary at ka = π is not an edge of anything: it is where the curve turns over. Near the bottom it is a parabola, which is the free-electron dispersion with a different coefficient — a mass of 0.470 m_e rather than one — and near the top it is a parabola the other way up, a mass of -0.470. The inflection between them is at ka = π/2, and it is the point at which a constant force stops producing any acceleration.

The mass a curve decides

An electron in a solid answers a force with a mass that is nothing to do with the mass of an electron. It is set by how sharply the band bends, it is smaller than the free value in a wide band and larger in a narrow one, and near the top of any band it is negative — which is why aluminium's Hall voltage has the sign of a positive carrier and no adjustment to an electron count can repair it.

quantum · Bands
Every speed there is, on one disc. The whole of velocity space drawn as a disc: the boundary is the speed of light and every possible velocity is a point inside. The rings are equal steps of rapidity — 0.5, 1, 1.5, 2, 2.5 — and they sit at speeds 0.4621, 0.7616, 0.9051, 0.9640, 0.9866 of light. Equal steps of rapidity crowd towards the edge, checked ring by ring, which is the same fact as speeds refusing to add: a boost is a fixed step in rapidity and a shrinking step in speed. The drawing is the Poincaré model, in which angles are true and distances are not — so a shape near the rim is drawn small and is not small, and the boundary is infinitely far away in the geometry although it is a finite circle on the page.

The space that speeds live in

Speeds do not add, and the reason is that the set of all possible velocities is not a flat space. It is a hyperbolic plane of curvature minus one in rapidity — and the rotation two boosts leave behind is exactly the area of the triangle they make in it.

relativity · Velocity-addition
One line decides whether it climbs for ever. The wetting condition for a corner, drawn as a map. The horizontal axis is the corner's half-angle and the vertical axis the liquid's contact angle with the walls; the diagonal is θ + α = 90°. Below it the meniscus in the corner curves into the liquid, the capillary pressure grows without bound as the corner narrows, and the liquid wicks along it indefinitely. Above it the curvature has the other sign and the liquid stays put. The boundary is tested by evaluating the meniscus a millionth of a degree either side of it at seventeen half-angles, and it wicks on one side and not the other every time. water on clean glass, right-angled corner: α = 45°, θ = 5° — wicks; water on glass, a 20° groove: α = 10°, θ = 40° — wicks; water on plastic, right-angled corner: α = 45°, θ = 75° — does not. A right-angled corner needs a contact angle under 45°, which water on clean glass has and water on most plastics does not.

The corner a liquid never stops climbing

A narrow tube lifts a liquid to a definite height because it has a smallest width. A corner has none, so the capillary suction it can develop is unbounded — and whether the liquid takes advantage is decided by a single inequality between the contact angle and the corner's own angle.

fluids · Surface tension
Six cells of a two-dimensional foam, by number of sides. Cells of a two-dimensional soap froth with three to eight sides, each drawn with its films meeting three at a time at 120°, as surface tension requires. A hexagon can do that with straight sides. A cell with fewer than six sides cannot: to make its corners 120° its sides must bulge outward, so its gas is at higher pressure than its neighbours' and leaks out. A cell with more than six must have sides curving inward, lower pressure, and gains gas. The rate of change of area, in units of πκγ/3 where κ is the films' permeability, is n − 6: −3 for a triangle, +2 for an octagon.

The bubble that grows by counting its sides

A froth of soap bubbles squeezed between two sheets of glass coarsens over a few days: small cells vanish and large ones swell. The obvious guess is that size decides which cells win, as it does for two bubbles joined by a tube, where the small one always empties into the large one. In a froth it is wrong. John von Neumann showed in 1952 that a cell's area changes at a rate fixed entirely by how many sides it has — shrinking if fewer than six, growing if more — and not at all by how big it is. The proof is a single sum of angles.

fluids · Surface tension
The force a rider feels on the way up a loop. The force of the seat on a rider, in multiples of the rider's weight, against how far the track has turned on the way from the bottom (0) to the top of the loop (1), for the 20 m circle and clothoid of the previous figure, each entered at the speed that leaves 0.5 g at the top. On the circle the force jumps the moment the car enters the loop, from 1 g on the straight to 6.5 g, and falls steadily to the top. On the clothoid it starts at 1 g, because the curvature starts at zero, and rises smoothly to 4.3 g partway round before falling. The clothoid's car also enters more slowly — 22.7 m/s against 23.2 — because its tighter top needs less speed to hold the car on.

The loop that is not a circle

A roller coaster's vertical loop looks circular from a distance and is not. A circular loop, entered fast enough for the car to stay on the track at the top, presses its riders into their seats at six times their weight at the bottom — six, whatever the circle's size — and slams that force on in an instant at the entry. The fix, found for railways a century earlier, is a curve whose curvature grows steadily with distance, the Euler spiral: the same curve that describes how light spreads round the edge of a shadow. Tight at the top, gentle at the bottom, it lets the force build instead of arriving all at once.

mechanics · Circular motion

Named alongside it

The objects these essays reach for when they reach for this one.

Laplace pressureSurface tensionDispersion relationInstabilityNormal modesRestoring forceTaylor expansionAnharmonicityBand gapBloch waveBoostBoundary conditions

All concepts