Illustrated Physics
physics, drawn
Concept

Anharmonicity — where it appears

The departure of a potential from the parabola that fits its minimum, which is everything the harmonic approximation discards. A whole class of phenomena lives there and nowhere else: a solid expands when heated only because the well is asymmetric, and a crystal conducts heat at a finite rate only because its modes are coupled.

Named by 10 essays across 5 fields — each of them below, with the objects they name alongside it.

One parabola, several wells. Unlike potential wells, each divided by its own curvature at the bottom, against the single parabola ½x² drawn through all of them. They agree near the minimum because a function with a minimum has no linear term there, so the quadratic term is the first thing it has. The labels give where each well departs from the parabola by more than 1% of the parabola's own value there: a pendulum at 0.35, a chemical bond at 0.01, a pair of atoms at 0.0015. A symmetric well has no cubic term and stays close for a long way; a well that is steeper on one side than the other has one, and leaves the parabola almost at once — which is why those numbers differ by factors of hundreds and not by a few per cent.

Every minimum is a parabola

A pendulum, a bond between two atoms and a ship rolling in a swell obey the same equation, and the reason is not that they are alike. It is that a function with a minimum has no linear term there, so the first thing every potential well looks like is the same well.

mechanics · Harmonic approximation The average position of something that is only shaking. The mean displacement of an oscillator against temperature, taken as a Boltzmann average over each well rather than from any expansion of it, with the temperature measured against each well's own depth so that unlike bonds can share an axis. A symmetric well gives exactly zero at every temperature — heating a harmonic solid makes it vibrate harder and does not make it larger. The others drift outward, because the outward side is the shallower one, and the measured slopes are a pendulum 0.000, a chemical bond 0.766, a pair of atoms 0.150. Thermal expansion is not a property a spring has; it is one a spring lacks.

Why heating a perfect spring changes nothing

A harmonic solid vibrates harder when heated and does not get any longer. Thermal expansion lives entirely in the term that the harmonic approximation throws away — and so does the fact that a solid conducts heat at a finite rate, which is the same discarded term doing a second job nobody would have connected to the first.

thermodynamics · Harmonic approximation An average that follows Newton's law exactly. The centre of a wavepacket in a harmonic well, and the classical orbit started from the same place, drawn on top of each other. They agree to 5.5e-6 over 2.2 periods, which is the split-step integrator's own error and not a physical gap. This is exact and it is exact for every state of a harmonic oscillator, however wide, however lumpy, however far from classical: the theorem needs ⟨−V′(x)⟩ = −V′(⟨x⟩), which for a linear restoring force is true term by term. It is worth being suspicious of how strong that looks. The harmonic oscillator is the one potential where the average force over a state and the force at the state's centre cannot differ, so it is the worst possible example from which to conclude that quantum averages follow classical paths.

The average that obeys Newton

Ehrenfest's theorem says the centre of a wavepacket moves according to the average force over the state. That is exact, it is often quoted as the reason classical mechanics survives, and the two statements are not the same — because the average of a force is the force at the average only when the force is linear, which is to say almost never.

quantum · Correspondence A drive at one frequency, and what comes back at three times it. The Fourier components of the steady motion of an oscillator driven at a single frequency ω = 1.35, for drive strengths of 0.02, 0.05, 0.1. The equation is a harmonic oscillator with a cubic term added, and the components are projected out of the integrated motion rather than assumed. A linear oscillator answers only in the first column. This one answers in the third as well, because x³ of a cosine contains a cosine of three times the angle. The third harmonic grows as the drive to the power 3.00 where the fundamental grows as the power 1.00, so it is negligible at small drive and not at large — which is why nonlinearity in an instrument is a specification rather than a yes or no.

The oscillator that answers at three times the question

Push a spring hard enough that the parabola stops being the whole story, and three things happen that a linear oscillator cannot do: it emits frequencies nobody supplied, its resonance leans over, and its amplitude at one drive frequency depends on where the drive has been.

mechanics · Harmonic approximation The energy that goes and comes back. A chain of 32 masses with springs a few per cent nonlinear, started with all its energy in its longest mode, with the energy of the first five modes followed against time in units of that mode's own period. The first mode gives up most of what it has — down to 9 per cent by 104 periods — and the energy appears in the second, third and fourth. Then it comes back: at 154 periods the first mode holds 98 per cent of the total again. Equipartition would put an equal share in every one of the thirty-two modes and leave it there. What happens instead is that a handful of modes trade with each other and return almost exactly to where they began, and go on doing so. The total energy is checked against its starting value throughout and holds to 9.2e-5, so nothing here is the integrator losing track of what it was given.

The energy that refuses to be shared

Put all the energy of a chain of masses into its longest mode and add a few per cent of nonlinearity, and equipartition says it should spread out among all thirty-two modes and stay there. It does not. It leaks into three or four neighbours and then comes back — almost exactly — and goes on doing so, and the calculation that found this was expected to be a demonstration that it would not happen.

thermodynamics · Equipartition A swing that dies away and comes back. The envelope of the mean position of a coherent state with 9 quanta on average, in an oscillator whose levels carry a small quadratic term, Eₙ = n + n²/240, over one revival time of 240 oscillator periods. The swing collapses within about 9.1 periods, when the packet has spread round its orbit, and it stays at zero for most of the run. It returns whole at half the revival time, on the opposite side, and whole again at the full revival time; the envelope is summed from the state's energy components and checked against α·exp(−2n̄ sin²χt) to a part in a hundred million. The dashed curve is a classical ensemble started from the same distribution, each member orbiting at the frequency its own energy gives: it collapses in the same way and never returns, its swing at the half and full revival times 0.1% and 0.1% of the start.

The return a classical cloud never makes

Put a swinging quantum packet in a well whose frequency depends a little on the amplitude and it spreads round its orbit until its swing has vanished. That part is not quantum at all: a cloud of classical oscillators does exactly the same. What no classical cloud can do is come back — and the quantum packet reassembles whole, on schedule, splitting into copies on the way, because its energies are discrete.

quantum · Correspondence A pendulum with unequal steps. The potential −EJ cos φ of the junction against its phase, at EJ/EC = 50, with the lowest 4 levels of the circuit drawn across the well between their classical turning points, in units of the charging energy. The transitions are 18.94, 17.79, 16.50, each smaller than the one below it; a harmonic well of the same curvature would space them all at the square root of 8·EJ·EC, 20.00. The spacing shrinks because the cosine is flatter than a parabola away from its bottom, and the shrinking is what lets a microwave pulse tuned to the lowest transition leave the next one alone.

The circuit that forgets its charge

A tiny superconducting island joined to its surroundings through a Josephson junction has discrete energy levels, and two of them make a quantum bit. The first such circuits were ruined by stray charges on nearby surfaces, which moved their levels and scrambled any superposition within a nanosecond. The cure was to make the junction's energy fifty times the charging energy. That makes the levels exponentially insensitive to charge while costing only a power-law loss in the unequal spacing that lets one transition be driven alone.

electromagnetism · Superconductivity A pendulum swung 30° with a sideways push, seen from above. The path of the bob of a 1 m pendulum free to swing in any direction, seen from directly above, released 30° from the vertical with a sideways push that would, for a small swing, make an ellipse 0.3 as wide as it is long. The path is an ellipse that turns: its long axis advances 5.30° every half swing, in the same sense as the bob goes round, where Airy's small-amplitude rate (3/8) ωab/L² gives 5.06°. Nothing outside the pendulum turns it — the pivot is fixed and there is no Earth rotation in this calculation. A pendulum on a turning Earth that is meant to show the Earth's rotation has this turning to contend with too.

The ellipse a pendulum turns by itself

Let a pendulum swing in any direction and give it a small sideways push, and its bob traces an ellipse. For a small swing the ellipse closes. For a larger one it turns, steadily, in the sense the bob is going round — with nothing outside the pendulum turning it. Airy worked out the rate in 1851, the same year Foucault hung his pendulum in the Panthéon, and the two effects are the same size for a pendulum a metre long whose ellipse is a twentieth of a millimetre wide.

mechanics · Pendulum A relativistic mass on a spring, at four amplitudes, scaled to one size. The displacement of a mass on an ideal spring against time, over two periods, with the mass's inertia growing with its energy as relativity requires, at amplitudes of 0.2, 1, 3, 10 times c/ω₀ — the distance light travels in one radian of the slow oscillation. Each curve is divided by its own amplitude and its own period so that shape alone is compared. The small swing is the familiar sine. The large one is a triangle: the mass spends almost the whole cycle moving at nearly the speed of light, turning round abruptly at each end. Periods: 1.007, 1.175, 2.132, 6.431 times the slow period.

The spring that becomes a light-clock

A mass on an ideal spring keeps the same period however far it swings — that is what makes it a clock. Give the mass the inertia relativity demands, pull it back far enough, and the clock breaks. The speed can never pass c, so a large swing spends almost all its time moving at nearly the speed of light, turning round abruptly at each end: the sine becomes a triangle, the period grows until it is simply the time light takes to cross the swing four times, and a clock riding on the mass ages a small fraction of what one beside it does.

relativity · Relativistic dynamics The area under the spacings is the bond. The gap between each vibrational level and the next, against level number, for a Morse well and a Lennard-Jones well with the same depth and the same curvature at the bottom, Λ = 100, in units of the well depth. The sum of the gaps from the lowest level up is the energy needed to break the bond from there. For the Morse well the gaps fall in a straight line to zero, and a straight line through the first 5 of them, extended to zero, encloses 0.9473 against the true 0.9473. For the Lennard-Jones well the gaps start almost the same and fall slightly faster at first — which is what the straight line sees — then trail off in a long tail of small gaps near the top; the same extrapolation from the first 5 encloses 0.7988 against the true 0.9474 — 15.7 per cent short, because the straight line cannot see the crowded levels its data never reached.

The spectrum that weighs a bond

A vibrational spectrum measured near the bottom of a molecule's well gives its curvature, and the curvature says nothing about how deep the well is. Measured further up, it says everything. The levels of a real bond crowd together towards the top, the gap between neighbours falls towards zero, and the sum of all the gaps is the energy it takes to break the bond. A straight line drawn through the gaps that have been measured, and extended to zero, was for decades how bond energies were found — and for a bond with the tail of two neutral atoms it comes out a sixth short.

mechanics · Harmonic approximation

Named alongside it

The objects these essays reach for when they reach for this one.

Harmonic approximationSimple harmonic motionAmplitude dependenceClassical limitCoherent stateDecoherenceEquipartitionHarmonic oscillatorIsochronismNonlinearityPotential wellTaylor expansion

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