Illustrated Physics
physics, drawn
Concept

Equipartition — where it appears

The theorem that every quadratic term in a system's energy carries half of kT in equilibrium, whatever the coefficient in front of it. It fails once a mode's quantum of energy exceeds kT, which is why heat capacities rise in steps and why the classical prediction for a solid is wrong at low temperature.

Named by 24 essays across 7 fields — each of them below, with the objects they name alongside it.

Molecular speeds at 4 temperatures. The distribution of molecular speeds in a gas, with each curve enclosing the same area. Raising the temperature moves the peak right and lowers it: the same molecules, spread over a wider range of speeds.

The speeds in a still room

The air in a quiet room is not still. Every molecule in it is moving at hundreds of metres per second, and temperature is a single number summarising an entire distribution.

thermodynamics · Kinetic theory Pressure, counted as momentum arriving at a wall. Molecules with speeds drawn from the Maxwell–Boltzmann distribution and directions drawn uniformly in the plane of the figure. Those moving toward the wall will bounce off it, reversing the component perpendicular to it and delivering twice that momentum each — and pressure is nothing but the rate at which that momentum arrives. Because the directions here lie in a plane rather than in space, the perpendicular component carries half the energy rather than the third it carries in a real gas.

Pressure is a rate of arrival, and the gas law falls out of counting

Nothing in a gas is pushing on the walls. Molecules arrive, bounce, and leave, and pressure is the momentum they deliver per second — from which the ideal gas law follows with no thermodynamics in it at all.

thermodynamics · Kinetic theory Heating 1 kg of water from -20°C to 130°C. Temperature against heat added for 1 kilogram of water taken from -20 to 130 degrees Celsius. The two flat stretches are the melting and the boiling, where 334 and 2260 kilojoules go in and the temperature does not move. Melting costs as much as warming the water by 80 degrees; boiling costs as much as warming it by 541, which is 73 per cent of the whole journey.

The heat that changes no temperature, and where it actually goes

A kettle reaches a hundred degrees in a minute and takes five more to boil dry. The heat going in during those five minutes changes nothing a thermometer can see, and it is most of the energy in the whole process.

thermodynamics · Phase change The blackbody spectrum, against what classical physics predicted. Spectral exitance against wavelength for a blackbody at 3000, 4000, 5000 kelvin, in kilowatts per square metre per nanometre. Each curve peaks at the wavelength Wien's displacement law gives — 966 nm at 3000 K, 724 nm at 4000 K, 580 nm at 5000 K — and falls to nothing at short wavelengths.

The curve that would not come down

Classical physics predicted that a warm object radiates infinite power at short wavelengths. Every step of the derivation was correct, the prediction was absurd, and closing the gap required assuming that energy comes in lumps.

quantum · Blackbody Seven walks from one point. 7 random walks of 400 steps each, all starting at the same place. None of them goes anywhere in particular and none of them stays put; the typical distance reached after n steps is the square root of n, so quadrupling the time doubles the spread. The tracks are seeded, so this is a property of the figure rather than of any one run.

The jiggle that proved atoms

A pollen grain in still water never stops moving. For eighty years that was a curiosity with no explanation; then it became the measurement that settled whether matter is made of particles, by turning a microscope and a stopwatch into a count of how many molecules are in a mole.

thermodynamics · Diffusion The staircase equipartition cannot climb. The heat capacity of hydrogen at constant volume, in units of R, against temperature on a logarithmic axis. The three translational directions contribute 3/2 at every temperature. The two rotations switch on near 85.4 K — the temperature at which kT matches the first rotational step — taking the total to 5/2, computed here by summing the rigid rotor's partition function over two hundred levels rather than by assuming the plateau. The vibration switches on near 6332 K, taking it to 7/2. At 50 K the value is 2.469; at 300 K the value is 2.502; at 5000 K the value is 3.376. Classical equipartition predicts 7/2 at every temperature, including at four kelvin, and the size of the steps is set by ħ — which is how a heat capacity measures a quantum constant.

Half a kT for every way of moving

A heat capacity ought to be a count. Every quadratic term in a system's energy carries half a kT of it, so warming a gas is a matter of enumerating the ways its molecules can move — and the fact that the count comes out wrong for hydrogen is how a thermometer measured Planck's constant.

thermodynamics · Equipartition Newton's answer, Laplace's, and the measurement. The speed of sound in 4 gases at 273.15 K. The short bar is Newton's √(RT/M), which assumes the compressions stay at one temperature; the long one is the same multiplied by √γ, which is what they come to if no heat crosses between a compression and the rarefaction beside it; the upright mark is the measured value. Newton's is 15.5% low for air, 22.5% low for helium, 22.5% low for argon, 12.0% low for carbon dioxide, and the corrected one is right to 0.05% for every gas here. Turning it round: γ read off each pair of bars is 1.400 for air, 1.665 for helium, 1.666 for argon, 1.290 for carbon dioxide, which is 1 + 2/f with f = 5.0, 3.0, 3.0, 6.9 ways of holding energy — three for the monatomic gases, five for the diatomic ones, and nearly seven for carbon dioxide, whose bending modes have begun to take a share at this temperature and its stretch has not. A speed measured with a stopwatch counts the ways a molecule can move.

The correction that took a century

Newton derived the speed of sound in 1687 and got 290 metres a second against a measured 340. The arithmetic was right; the assumption was not. Heat cannot cross a wavelength in a period, so the compressions are adiabatic — and the factor that repairs the answer turns out to be a count of the ways a molecule can move.

waves · Wave motion How much of copper's electron sea a temperature can reach. The probability that a state of a given energy is occupied, in copper, at 4 temperatures, with energy measured in units of the Fermi energy — 7.04 eV here. At absolute zero the curve is a step: every state below the ceiling is full and every state above it is empty. Raising the temperature rounds the step, and rounds it over a range of about kT, which is the whole point — at room temperature kT is 0.0259 eV against a ceiling of 7.04 eV, so the rounding is 1.6 per cent of the way down the sea and everything deeper is untouched. An electron in the deep is not held there by a force; it simply has nowhere to go, because every state it could be promoted to is occupied. at 0 K the step is spread over 0.00 per cent of E_F, at 300 K the step is spread over 1.61 per cent of E_F, at 3000 K the step is spread over 16.13 per cent of E_F, at 20000 K the step is spread over 107.52 per cent of E_F.

The pressure that is not a temperature

Copper's conduction electrons are at a temperature of eighty thousand kelvin, in a wire that is at room temperature. That is not a figure of speech, it is what the exclusion principle does to a mole of particles, and it explains the largest unexplained number in the theory of metals.

quantum · Exclusion The average position of something that is only shaking. The mean displacement of an oscillator against temperature, taken as a Boltzmann average over each well rather than from any expansion of it, with the temperature measured against each well's own depth so that unlike bonds can share an axis. A symmetric well gives exactly zero at every temperature — heating a harmonic solid makes it vibrate harder and does not make it larger. The others drift outward, because the outward side is the shallower one, and the measured slopes are a pendulum 0.000, a chemical bond 0.766, a pair of atoms 0.150. Thermal expansion is not a property a spring has; it is one a spring lacks.

Why heating a perfect spring changes nothing

A harmonic solid vibrates harder when heated and does not get any longer. Thermal expansion lives entirely in the term that the harmonic approximation throws away — and so does the fact that a solid conducts heat at a finite rate, which is the same discarded term doing a second job nobody would have connected to the first.

thermodynamics · Harmonic approximation The line that slopes the wrong way. Mean temperature against total energy, for a self-gravitating sphere at nine radii. The points fall on a straight line of negative slope: taking energy away makes the body hotter. The heat capacity read off the drawing is -4.10e+34 J/K against the -4.10e+34 J/K the theorem gives, and the sign is the whole content. The dashed line is an ordinary gas in a rigid box, whose temperature rises when energy is added, as everything one can put a thermometer in does.

The ball of gas that heats up as it cools

Take energy away from a self-gravitating cloud and its temperature rises. Its heat capacity is negative, which nothing else stable does, and the consequence is that a star radiating into cold space is not cooling down — it is running up, and its whole life is a slow fall it cannot stop.

astrophysics · Self-gravity What a coordinate is worth, by the shape of its energy. The mean energy stored in one coordinate, in units of kT, against the power with which that coordinate enters the energy. The curve is 1/n and the points are the same average obtained by integrating the Boltzmann weight numerically, agreeing to 3.3e-7 per cent at worst. an energy going as |x|^1 holds 1.0000 kT; an energy going as |x|^1.5 holds 0.6667 kT; an energy going as |x|^2 holds 0.5000 kT; an energy going as |x|^3 holds 0.3333 kT; an energy going as |x|^4 holds 0.2500 kT; an energy going as |x|^6 holds 0.1667 kT. The familiar half a kT is the case n = 2 and nothing more general than that: a coordinate whose energy is linear in it — the momentum of an ultrarelativistic particle, or a field with no restoring force but a constant tension — carries a whole kT, and one confined by a very steep wall carries almost nothing. Equipartition is a theorem about quadratic terms, and calling it a theorem about degrees of freedom is the substitution that makes it fail.

The share that is not half a kT

Equipartition is quoted as half a kT for every degree of freedom, and it is nothing of the kind. It is half a kT for every *quadratic* term. A coordinate whose energy is linear in it carries a whole kT, and a gas hot enough that its particles' energy is pc rather than p²/2m therefore holds twice what the counting says — which drops its ratio of specific heats to four thirds and puts a star on the edge of being able to hold itself up.

thermodynamics · Equipartition A force that points across the beam, not along it. The intensity of a beam focused to a waist of 0.5 µm, and the force it exerts on a 60 nm polystyrene sphere in water, across the beam. The force is not a pressure and does not point along the light: it is the pull on an induced dipole sitting in a non-uniform field, proportional to the gradient of the intensity rather than to the intensity, and it points up the gradient — towards the bright axis from either side. It vanishes exactly on the axis, which is what makes the axis a trap rather than a place. The well is 47 times kT deep at 100 milliwatts, which is why the particle stays: thermal motion explores it and does not escape it. The stiffness near the bottom is 3.070 piconewtons per micrometre, and a particle in a spring that stiff wanders 36 nanometres from centre.

The light that pulls rather than pushes

Radiation pressure is momentum arriving, and it points along the beam. A gradient of intensity does something else entirely — it polarises a particle and then pulls the induced dipole up the gradient — so a focused beam holds a particle at its waist against the push, and the force that does it is not a pressure at all.

astrophysics · Radiation pressure A ratio in the exponent. The Boltzmann factor against the energy of a state measured in units of kT, with the logarithm up the axis so that the straight line is the whole content. Every kT of energy costs a factor of e, so 5, 12, 20 times kT are factors of 10^-2.2, 10^-5.2, 10^-8.7. At 295 K, kT is 25.4 meV, so a barrier of 0.4 eV is 15.7 kT and a factor of 1.5e-7. That is the sense in which a third of an electronvolt is not a small energy: it is small compared with a chemical bond and enormous compared with kT, and it is the second comparison that decides whether anything happens.

The temperature a molecule does not have

Temperature fixes a system's average energy and nothing more. The actual energy wanders, by an amount tied to the heat capacity, and the relative size of the wandering falls as one over the square root of the number of degrees of freedom — so a mole has a temperature and a molecule does not.

thermodynamics · Equipartition The energy that goes and comes back. A chain of 32 masses with springs a few per cent nonlinear, started with all its energy in its longest mode, with the energy of the first five modes followed against time in units of that mode's own period. The first mode gives up most of what it has — down to 9 per cent by 104 periods — and the energy appears in the second, third and fourth. Then it comes back: at 154 periods the first mode holds 98 per cent of the total again. Equipartition would put an equal share in every one of the thirty-two modes and leave it there. What happens instead is that a handful of modes trade with each other and return almost exactly to where they began, and go on doing so. The total energy is checked against its starting value throughout and holds to 9.2e-5, so nothing here is the integrator losing track of what it was given.

The energy that refuses to be shared

Put all the energy of a chain of masses into its longest mode and add a few per cent of nonlinearity, and equipartition says it should spread out among all thirty-two modes and stay there. It does not. It leaks into three or four neighbours and then comes back — almost exactly — and goes on doing so, and the calculation that found this was expected to be a demonstration that it would not happen.

thermodynamics · Equipartition The condition three modes never quite satisfy. By how much three modes of a thirty-two mass chain fail to be in resonance — the sum of two mode frequencies minus the frequency of their sum, on a logarithmic scale, against the second of the two modes for four choices of the first. The leading nonlinear term couples modes in threes and the exchange accumulates only where this quantity is zero. It never is: the chain's dispersion is a sine, a sine is concave, and the sum of two of its values always exceeds the value at their sum. The smallest mismatch anywhere on the chain is at the two lowest modes and equals 2.156e-4 — which the scan finds and which is the cube of pi over four times the cube of one more than the mode count, checked here on chains from eight masses to two hundred and fifty-six. That closed form is the whole of why this is a finite-chain problem: the mismatch falls as the cube of the length, so a long enough chain is arbitrarily close to resonant and the continuum limit is exactly resonant, which is where the solitary waves come from.

The condition three modes never meet

Whether two modes of a chain can hand energy to a third is arithmetic on the dispersion relation, and for a chain of masses the answer is never: a sine is concave, so the sum of two frequencies always exceeds the frequency of their sum. The smallest shortfall anywhere on a chain of N masses is π³/4(N+1)³ — never zero, and never far from it — and a shortfall turns a transfer into a beat.

thermodynamics · Equipartition The modes of a wire, counted. Nyquist's argument of 1928, with its count performed. Two resistors joined by a lossless line are in equilibrium, and the line is a one-dimensional cavity whose standing waves are spaced c/2L apart in frequency. Each mode has an electric and a magnetic energy, both quadratic, so equipartition gives it kT — the same half a kT per quadratic term that a heat capacity counts. The upper points are how many modes fall in a band of a hundred and thirty-seven megahertz, for five line lengths, from 17 on a thirteen-metre line to 8,558 on one of six kilometres. The lower points are the power each end therefore receives, as a fraction of kTΔf, and they converge on one: a longer line has proportionally more modes and takes proportionally longer to deliver them, so the length cancels. The longest line lands within 0.005 per cent and the shortest is 4.5 per cent low, because thirteen metres holds only seventeen whole modes in the band and the remainder is a real granularity rather than an error. What is left in the limit is kTΔf — a noise power with no resistance in it at all, and none of the line's properties either.

Half a kT in a piece of wire

Count the quadratic terms in a molecule's energy and equipartition gives a heat capacity. Count them on a transmission line instead and the same theorem gives a resistor's noise voltage — 4kTRΔf, with nothing in it about what the resistor is made of. A fifty-ohm input at room temperature says 0.91 nanovolts in every root hertz, and no design removes it.

thermodynamics · Equipartition Twice the kinetic energy, and what it equals. Twice the time-averaged kinetic energy of a bound orbit, divided by its time-averaged potential energy, against the power with which that potential depends on separation. Each point is a measurement: an eccentric orbit integrated for more than a hundred radial periods, with the two averages accumulated along it, and the radius checked to vary by at least a fifth so that the orbit is not trivially circular. The line is the exponent itself, and the points miss it by at most 6.6e-4. Two cases carry everything. At n = 2, a harmonic well, the two energies are equal — which is the ordinary equipartition statement, half a kT to the kinetic term and half a kT to the potential one. At n = −1, which is gravity and the Coulomb force, twice the kinetic energy equals minus the potential energy, so the total energy of a bound system is minus its kinetic energy. Nothing about temperature entered, and nothing about equilibrium: the relation holds for one orbit averaged over time as well as for a crowd averaged over members.

Weighing what cannot be put on a scale

Summed over every coordinate of a bound system, equipartition stops being a statement about temperature and becomes a relation between two averages: twice the kinetic energy equals n times the potential energy for a potential going as the nth power. For gravity that fixes a bound system's total energy from how fast its parts move — so a Doppler shift and an angular size return a mass, and for the Coma cluster the mass they return is fifty times the mass that shines.

thermodynamics · Equipartition The same thermal motion, spread three ways. How the thermal jiggling of a spring-mounted mass is distributed over frequency, for quality factors 3, 30, 300, with frequency in units of the resonance and the spectrum in units that make the area under each curve its mean-square displacement. All three curves enclose exactly the same area, kT/k — 1.000, 1.000, 1.000 of it in the units drawn — because equipartition fixes the energy in the spring and not how fast it changes. What the damping chooses is where that motion goes: a high Q concentrates it in a peak 100 times taller than the low-Q one, and leaves the rest of the spectrum 100 times quieter at 10 times the resonance frequency.

The noise a high Q moves out of the way

Anything held by a spring at a temperature jiggles, and equipartition says exactly how much: the mean square of its displacement is kT divided by the spring's stiffness, whatever the spring is made of and however it is damped. That looks like a floor no measurement can go below. It is a floor on the total, and the total can be moved. An oscillator with little damping puts almost all of its thermal motion into a narrow peak at its own frequency and leaves every other frequency quiet — which is why the mirrors of gravitational-wave detectors hang from fibres of glass that ring for minutes.

thermodynamics · Equipartition The Casimir pressure between warm plates, from vacuum to heat. The attractive pressure between two parallel, perfectly reflecting plates at 300 K against their separation, on logarithmic axes, from the Lifshitz sum over Matsubara frequencies. Dashed: the zero-temperature law π²ħc/240a⁴. Dotted: the classical law ζ(3)kT/4πa³, which contains no Planck constant. At 1 μm the full pressure is 0.0013 Pa, within 0.2 per cent of the vacuum value; at 10 μm it is 3.96·10⁻⁷ Pa, 3.05 times the vacuum value and within 0.002 per cent of the classical law. The two laws cross at 3.28 μm; the thermal length ħc/kT is 7.63 μm. The second solid curve removes one term — the static magnetic fluctuation, which a metal of finite conductivity does not reflect — and sits 15 per cent lower at 1 μm and a factor of two lower far out. The plates are otherwise ideal mirrors: a model, chosen to isolate that one term.

The force that forgets Planck's constant

Two mirrors in a vacuum attract, with a pressure that contains Planck's constant and nothing else about the world but the speed of light. Warm the mirrors and pull them apart, and past a few micrometres at room temperature the Planck constant drops out of the answer. The force is still there and is now larger than the vacuum alone would give, but it has become classical: a count of thermal fluctuations of the static field, with kT of energy each. Half of that classical force comes from one fluctuation — a static magnetic field — and whether a real metal mirror reflects it is a question that has divided the people who measure the force for twenty years.

electromagnetism · Retardation What the heat shares out, and what it does not. Two averages per particle in the Maxwell–Jüttner gas, in units of kT, against kT/mc² on a logarithmic scale: the momentum times the velocity, p·v, whose average over the three directions gives the pressure, and the kinetic energy. The first is 3 at every temperature, computed here by averaging over the distribution and equal to 3 to four decimal places across the whole figure — so the pressure is exactly nkT, the ideal gas law, from a gas colder than a star to one hotter than the early universe. The kinetic energy is not shared out the same way. It is 1.506 kT when the gas is cold, Boltzmann's 3/2, and rises to 3.00 kT when it is ultra-relativistic, because for a fast particle the energy is p·c and p·v, which is what equipartition hands out, is the whole of it rather than twice it.

The gas law relativity leaves exact

Heat a gas until its particles move at nearly the speed of light and almost everything Maxwell and Boltzmann said about it changes. The speeds pile up just below c instead of spreading out. The energy per particle climbs from three halves of kT to three. The heat capacity doubles, and the ratio of heat capacities falls from five-thirds to four-thirds. One law survives untouched: the pressure is still exactly nkT, at a thousand degrees or a hundred thousand million. The reason it survives is the reason the others change. What heat hands out equally to every way of moving is not energy but momentum times velocity, and for slow particles those happen to differ only by a factor of two.

relativity · Relativistic thermodynamics A heat capacity that goes up and comes down. The heat capacity per system, in units of Boltzmann's constant, against temperature in units of the level spacing over k: for a system with two levels (red), Schottky's hump x²eˣ/(1 + eˣ)², x = Δ/kT, and for a harmonic oscillator with the same spacing (blue), which climbs to one k and stays there. Both are frozen out when kT is well below the gap. The oscillator then fills its unending stack of levels and reaches equipartition's value. The two-level system peaks at 0.439k when kT = 0.417Δ, and then, with both levels nearly equally occupied and nothing higher to go to, it stops absorbing heat: its capacity falls back towards zero as 1/T².

The heat capacity that goes up and comes down

Equipartition promises every way a system can move a fixed share of heat, and for a harmonic oscillator the promise is kept: once the temperature is high enough, it holds one k per oscillator and goes on holding it. A system with only two levels cannot keep it. It absorbs heat while its upper level is filling, then stops — the two levels equally full and nowhere higher to go — so its heat capacity rises to a peak and falls back to zero. The hump, named after Walter Schottky, is the signature of a degree of freedom with a ceiling, and the area under it counts how many states were there.

thermodynamics · Equipartition The period of a ball bouncing on a gas. The period of a 16 mm steel ball (16.8 g) oscillating in a vertical tube that fits it on top of a flask, against the flask's volume on a logarithmic axis, for helium, air and carbon dioxide at room temperature, if every compression is adiabatic: T = 2π√(mV/γPA²). On a 10 litre flask the ball swings with a period of 0.983 s on helium, 1.072 s on air and 1.117 s on carbon dioxide. The gas is the spring, and its stiffness is γ times the pressure: the gas whose molecules have fewest ways to store energy is the stiffest, because less of the work done in compressing it goes into motions that do not push on the walls.

The ball that weighs how a gas stores heat

Drop a steel ball into a glass tube that fits it closely, on top of a flask of gas, and it does not fall to the bottom. It bounces, up and down, on the gas trapped beneath it, with a period of about a second. The gas is a spring, and its stiffness is the pressure multiplied by a number that counts how many ways the gas's molecules can hold energy. So a stopwatch on a bouncing ball measures something that otherwise needs a calorimeter: whether the molecules can rotate, whether they can vibrate, and how far a vibration has woken up at the temperature of the room.

thermodynamics · Equipartition How a sphere of gas rings. The acoustic pressure against distance from the centre of a spherical cavity, for its three lowest radial modes, in which the gas breathes in and out in spherical shells: sin(zr/a)/(zr/a), with z = 4.4934, 7.7253, 10.9041 the roots of tan z = z that make the gas's motion vanish at the wall. Filled with argon at the triple point of water, 273.16 K, a sphere 62 mm in radius rings in these modes at 3551, 6104, 8616 Hz. Radial modes are the ones precision work uses: they have no motion along the wall, so the wall's roughness and the gas's viscosity there barely touch them, and their frequencies are set by the volume rather than the shape — a slightly imperfect sphere shifts them only at second order.

The note that fixed the kelvin

A sphere of argon, struck, rings at a pitch set by the speed of sound in it, and the speed of sound in argon contains only one quantity nobody could compute: the constant that converts a temperature into an energy. Argon's atoms can hold energy in exactly three ways, so its heat capacity is a count rather than a measurement, and its speed of sound is (5/3)kT/m with nothing left over. Ring the sphere at the temperature of melting ice, measure its size with radio waves in the same cavity, and Boltzmann's constant comes out to a part in a million. In 2019 that number stopped being measured and became the definition.

thermodynamics · Equipartition A surface whose thickness depends on how much of it is looked at. The rms roughness of a water surface at 20 °C, in nanometres, against the size of the patch over which it is measured, from the thermal ripples that fit inside the patch — with gravity (solid) and without it (dashed) — for ripples down to a molecular wavelength of 0.6 nm. Over 10 nm the surface is 0.16 nm rough; over a micrometre, 0.26; over a millimetre, 0.36; and beyond a few millimetres gravity flattens the longest ripples and the roughness stops at 0.390 nm. In free fall it would keep growing as the square root of the logarithm: 0.43 nm over a metre. An X-ray reflectivity measurement sees the ripples smaller than its own coherence length, typically some micrometres, and reports a thickness of about a third of a nanometre — a number that belongs to the instrument as much as to the water.

The surface whose thickness depends on the view

The surface of a glass of water looks like a perfect plane, and over most distances it nearly is. But it is at room temperature, and every ripple it could carry — from a few molecules long to a few millimetres — is shaken by heat with its own share of thermal energy. The ripples are tiny, a fraction of a nanometre high, and they add up in an odd way: every factor of ten in wavelength contributes the same amount of roughness. So the thickness of a water surface has no single value. It depends logarithmically on how large a patch is looked at, until gravity stops it at a few millimetres, and the X-ray measurements that report a third of a nanometre are reporting a property of their own resolution as much as of the water.

fluids · Surface tension

Named alongside it

The objects these essays reach for when they reach for this one.

Heat capacityDegrees of freedomTemperatureAdiabatic indexThe Boltzmann factorBrownian motionKinetic theoryFluctuation dissipationThe ideal gas lawResonanceStatistical mechanicsThermal equilibrium

All concepts