Illustrated Physics
physics, drawn
Concept

Band gap — where it appears

A range of frequencies or energies at which a periodic medium supports no travelling wave at all. It opens wherever two ways of travelling would otherwise share a frequency, so its position is set by the repeat and its width by the contrast between the repeating parts.

Named by 15 essays across 4 fields — each of them below, with the objects they name alongside it.

One well, two wells, and the band they become. The energy levels of a chain of identical wells, for 1, 2, 3, 6, 12, 40 of them, with an on-site energy of -4 eV and a coupling of -0.9 eV between neighbours. One well has one level. Two split it into two, 1.80 eV apart. By 40 the levels have filled a band 3.59 eV wide, which is closing on the limit of four times the coupling, 3.60 eV — and no further widening happens however many more wells are added. The count of levels grows with the number of wells; the width of the band does not.

What happens when the wells get close

Two atoms brought together split one level into two. A thousand split it into a thousand, packed into a band whose width stops growing after the third. Whether that band is full or half full is the whole difference between a wire and a window.

quantum · Bands The frequencies a repeat will not carry. The band structure of a medium made of quarter-wave layers of index 1 and 2, repeated for ever: frequency against Bloch phase across one cell, in the reduced zone. Inside a band the phase runs from 0 to π and the wave travels. Between bands there is no real phase at all, and the shaded strips are frequencies at which the medium supports nothing — not a weakly transmitted wave, no wave. Gap 1 runs from 0.784 to 1.216; Gap 2 runs from 2.784 to 3.216, in units of the quarter-wave design frequency. The first, measured off the drawn band edges, is 0.4327 wide against the 0.4327 of (4/π)·arcsin|r| — the same number computed from the Fresnel ratio of the two indices alone, agreeing to 2.6e-14 per cent. Every band edge sits where the phase is 0 or π, which is to say where the wave's own period fits the repeat a whole number of times: the gap is a property of the periodicity, and the materials only decide how wide it is.

The gap a repeat opens

Stack two transparent materials in alternating layers and there is a band of frequencies the stack will not carry — not weakly, not with loss, but not at all. Nothing has been absorbed and neither material has a resonance there. What forbids those frequencies is the repeat itself, and the width of the band has a closed form containing only the ratio of the two indices.

waves · Periodic media The one frequency a broken repeat lets through. Transmission through a quarter-wave stack whose repeat is broken once, on a logarithmic scale, against frequency in units of the quarter-wave design frequency. The perfect stack forbids this whole band; adding a single half-wave layer at the centre opens one line inside it, at exactly the middle of the gap, through which the stack transmits everything. With 4 pairs either side the line is 2.50e-3 wide, a quality factor of 400, on a background of 4.5e-4; With 6 pairs either side the line is 1.56e-4 wide, a quality factor of 6410, on a background of 6.3e-6; With 8 pairs either side the line is 1.00e-5 wide, a quality factor of 100000, on a background of 9.2e-8. The line narrows geometrically as the mirrors are made thicker, because the field inside the defect leaks out through a barrier whose transmission falls exponentially with its thickness — so the useful quantity of a band gap turns out to be not what it excludes but how well it can trap what a single flaw is allowed to hold.

The mode that lives in the mistake

A perfect stack of alternating layers refuses a whole band of frequencies — not weakly, not with loss, but not at all. Break the repeat once, by inserting a single layer of the wrong thickness, and exactly one frequency inside that band passes through the whole stack with a transmittance of one. The useful thing about a forbidden band turns out to be not what it excludes but what a single flaw is thereby allowed to hold.

waves · Periodic media A band 3.60 eV wide, and the curvature is the whole story. Energy against wavenumber for one tight-binding band, α + 2β·cos(ka), with α = -4 eV, β = -0.9 eV and a repeat of 300 pm. The band is 3.60 eV from floor to ceiling and periodic in k, so the zone boundary at ka = π is not an edge of anything: it is where the curve turns over. Near the bottom it is a parabola, which is the free-electron dispersion with a different coefficient — a mass of 0.470 m_e rather than one — and near the top it is a parabola the other way up, a mass of -0.470. The inflection between them is at ka = π/2, and it is the point at which a constant force stops producing any acceleration.

The mass a curve decides

An electron in a solid answers a force with a mass that is nothing to do with the mass of an electron. It is set by how sharply the band bends, it is smaller than the free value in a wide band and larger in a narrow one, and near the top of any band it is negative — which is why aluminium's Hall voltage has the sign of a positive carrier and no adjustment to an electron count can repair it.

quantum · Bands Two levels that refuse to cross. On the left, the energies of a two-state system as one state is swept past the other, for couplings of 0, 0.05, 0.15, 0.35 electronvolts. With no coupling at all the two levels cross, which is the dotted pair. With any coupling whatever they do not: the eigenvalues are plus and minus half the square root of the squared detuning plus four times the squared coupling, so the closest approach is exactly twice the coupling — measured off the drawn curves as 0.000, 0.100, 0.300, 0.700 eV against 2V, agreeing to 0.0e+0. Far from the crossing the curves rejoin the uncoupled lines, so the repulsion is local: it is largest where the two states are degenerate and dies away as the square of the coupling divided by the detuning. On the right is what makes this more than a picture of two hyperbolas — the character of the upper state, meaning how much of the first basis state is in it. It swaps completely across a region whose width is set by the coupling, so the level that arrives as one thing leaves as the other. That exchange of identity is why the phrase avoided crossing is misleading: nothing is avoided, the labels are.

The crossing that never happens

Two energy levels swept past one another do not cross. Any coupling between them, however small, opens a gap of exactly twice the coupling — and the two levels exchange their identities across it, so the state that arrives as one thing leaves as the other while the labels are what avoided anything.

quantum · Bands The chain's dispersion, and the frequency it stops at. Frequency against wavenumber for a chain of equal masses joined by equal springs, in units where the spacing, the mass and the spring are one. At long wavelength the curve is a straight line through the origin — the chain behaves as a continuous string with a sound speed, and the departure from the line is second order in the wavenumber, which is why a lattice is invisible until the wavelength approaches the spacing. At the zone edge, where neighbouring masses move in exact opposition, the curve flattens: the frequency stops rising, the group velocity falls to zero, and the mode is a standing wave that carries nothing. Above that frequency there is no travelling solution at all.

The frequency a lattice cannot carry

A continuous string carries every note. A row of masses joined by springs does not: there is a highest frequency, set by nothing but the time one mass takes to be pushed back by its neighbours, and above it a disturbance does not travel at all.

waves · Periodic media Two states at zero that only one side of the chain has. Every energy level of a chain of 20 cells, 40 sites, whose couplings alternate between v inside a cell and w = 1 between cells, against the ratio v/w from 0 to 2. The bulk levels fill two bands, bounded by the dashed lines ±|v − w| and ±(v + w), with a gap between them that closes at v = w. For v < w two levels sit at zero energy, in the middle of the gap, drawn in the warning colour: at v/w = 0.5 they are within a millionth of the coupling of zero. For v > w the gap is empty — at v/w = 1.5 the nearest level to zero is 0.527. Nothing about the chain's middle distinguishes the two sides of v = w; the difference is at its ends.

The end that knows how the middle was cut

A chain whose links alternate, strong and weak, has the same bands whichever kind of link is counted as inside a cell. The infinite chain cannot tell the two choices apart. A finite chain can: cut it so that a weak link is outermost and each end holds a state at exactly zero energy, in the middle of the gap; cut it the other way and it holds none. What decides is not anything at the ends but a whole number counted from the bulk — how many times a loop winds round a point.

waves · Periodic media A gap that every angle from air falls into. The stop bands of a stack of quarter-wave layers of index 4.6 and 1.6 — tellurium and polystyrene, the pair of the first such mirror — against frequency, in units of the design frequency, and the parallel index β = n₀ sin θ₀ the light brings along the layers; TE polarisation on the right, TM on the left. Shaded regions are gaps. Light from air can only have β between −1 and 1, the vertical lines; within those lines the gaps for both polarisations overlap between f = 0.848 and 1.321, the band marked across the figure, so every angle of incidence and both polarisations are reflected: a relative width of 43.6%. The TM gap narrows as β grows and closes at the internal Brewster index, 1.51, which light from air cannot reach.

The mirror that works from every direction

A stack of alternating transparent layers reflects nearly all the light of one colour arriving straight on, and less as the light tilts, because tilting moves the forbidden band. A structure that repeats in only one direction ought therefore to be a mirror for only a range of directions. It is not, if the layers differ enough: light arriving from air cannot bring enough sideways momentum to escape the forbidden band at any angle, for either polarisation, and a flat stack of plastic and tellurium reflects every angle over a band of frequencies almost half as wide as its centre.

waves · Periodic media The edge that is a straight line, not a step. The absorption of gallium arsenide near its own band gap of 1.424 electronvolts, on a logarithmic axis, at 4 temperatures. Below the gap the absorption does not stop; it falls exponentially, along a straight line whose slope is an energy, and the straightness holds over several decades. Raising the temperature makes the line shallower — the tail reaches further below the gap — and the slope runs from 5.6 millielectronvolts at 10 kelvin to 7.5 at 300, a factor of 1.33. The lines pivot about a point just above the gap rather than rotating about nothing, which is what makes the slope a single number worth quoting. The band gap's own shift with temperature has been removed here, so that the fan is the tail's doing and not the gap's.

Below the gap, where there is nothing to absorb

A semiconductor is supposed to be transparent below its band gap, and it is not. The absorption falls exponentially instead, over seven decades, along a straight line whose slope is an energy of a few millielectronvolts — and the description that produces that line has no states in the gap at all. What the slope measures is how much the gap itself is moving about.

waves · Attenuation The light of a diode at room temperature is as bright as a surface thousands of kelvin hot. How many photons occupy each mode of the light, on a logarithmic scale, against photon energy. The lowest curve is the thermal glow of a 1.42 eV semiconductor at 300 K with no voltage across it. The solid curve above it is the same device with 1.3 V across it, emitting only above its gap. The dashed curve is a blackbody at 2571 K, the temperature whose light has the same occupation as the diode's at 1.472 eV, just above the gap. They cross there and nowhere else: the diode's occupation falls a factor e every 25.9 meV, as its lattice's temperature requires, and the blackbody's every 222 meV. No single temperature describes the diode's light. At each photon energy it has a brightness temperature, and that temperature is 300 K multiplied by ε/(ε − qV).

The glow that carries a voltage

Thermal radiation has no chemical potential, because walls make and destroy photons freely. A light-emitting diode is a body that glows at room temperature with a voltage written into its light — Planck's law with the voltage as the photons' chemical potential — which is why its light can be as bright as a surface thousands of kelvin hot, why at low voltage it can put out more light than the power it draws and cool itself doing so, and why a reverse voltage makes a surface look colder than it is.

thermodynamics · Chemical potential A repeat in space gaps the frequencies; a repeat in time gaps the wavenumbers. Two media with the same modulation depth, 0.2, computed the same way. Left: permittivity repeating in space, a stack of layers. For each frequency the wave equation is integrated across one spatial period, and the Bloch wavenumber drawn against frequency; between frequencies 0.478 and 0.526 (in units of c over the period) there is no real wavenumber, so light of those frequencies cannot travel and is reflected. Right: permittivity repeating in time. For each wavenumber the equation is integrated across one period, and the frequency drawn against wavenumber; between wavenumbers 0.474 and 0.518 there is no real frequency. The axes of the two panels are swapped, and so is everything else: the spatial gap is a band of frequencies that decays in space, the temporal gap is a band of wavenumbers that grows in time.

The crystal made of moments

A stack of layers that repeats in space refuses a band of frequencies and reflects them. A medium that repeats in time — its refractive index swung up and down everywhere at once — refuses a band of wavenumbers instead, and a wave with a wavenumber in that band does not reflect. It grows, exponentially, drawing on whatever is swinging the index. The construction is exact, the gap is computable from one period of the modulation, and the obstacle to building one for light is how fast a material would have to change.

optics · Refraction Electrons and holes in silicon against the donors added. The concentrations of free electrons and holes in silicon at 300 K against the concentration of donor atoms added, on logarithmic axes, solved from charge neutrality and the product law n·p = nᵢ². Below the intrinsic concentration of 10¹⁰ per cubic centimetre the donors change almost nothing. Above it the electrons follow the donors one for one and the holes fall in exact proportion: a hundred times more donors, a hundred times fewer holes. At 10¹⁶ donors the electrons outnumber the holes by 10¹² to one. The dashed line is √(n·p), which does not move at all across ten decades of doping — checked to a part in a billion.

The product doping cannot move

Add one phosphorus atom for every five million silicon atoms and the crystal's free electrons multiply a millionfold — and its holes fall a millionfold, although nothing was done to them. Add a drop of acid to water and the hydroxide ions vanish in exactly the proportion the hydrogen ions grow. Both are one law: when a reaction makes two species together, equilibrium fixes the sum of their chemical potentials, and so the product of their concentrations. Every semiconductor device is built on the minority carriers that law leaves behind.

thermodynamics · Chemical potential A seabed that reflects one wavelength. The fraction of a surface wave's amplitude reflected by a patch of sinusoidal sandbars 50 m apart and 0.8 m in amplitude, in 4 m of water, against the wavelength of the incoming wave, for 4 bars and 8 bars, from the shallow-water equations integrated through the patch. 4 bars reflect 56 per cent of the amplitude at 99.8 m; 8 bars reflect 86 per cent of the amplitude at 100.4 m, close to twice the bar spacing, where each bar's small reflection returns in step with the others. Away from that wavelength the reflections cancel, and the more bars there are, the narrower the band they reflect.

The sandbars that reflect the sea

A stack of alternating layers reflects the one colour whose half-wavelength matches the repeat. A row of sandbars on a gently sloping seabed is the same arrangement for ocean waves, and it does the same thing. Waves twice as long as the bar spacing are sent back out to sea, one small reflection per bar, all adding in step. A patch of eight bars can return most of the swell that meets it. The reflected wave, added to the incoming one, makes a standing pattern whose nodes are spaced exactly like the bars. Sand gathers in that pattern, so a field of bars can build its own next bar.

waves · Periodic media Absorption below and above the gap. The light absorbed by a direct-gap crystal against photon energy measured from the gap, in units of the exciton's Rydberg, from Elliott's formula with each line broadened to a half-width of 0.06 Rydberg (solid), beside the absorption the same crystal would have if electron and hole did not attract (dashed), which rises from zero as the square root of the energy above the gap. Below the gap the attraction adds a series of lines at −1, −1/4, −1/9 … Rydberg, the hydrogen series scaled down, with strengths falling as 1/n³, crowding towards the gap. Above it the continuum is lifted: the attraction pulls each free pair together, and at the gap itself the absorption is a finite step rather than zero.

The hydrogen atom inside a crystal

Light absorbed by a semiconductor lifts an electron across the gap and leaves a hole behind, and the two attract. In an ordinary crystal they bind into a copy of the hydrogen atom, with the same series of levels and the same 1/n² — but the crystal screens their attraction and lends them light masses, so the copy is a few thousand times shallower and several hundred times larger. That rescaling is the whole theory, it predicts lines below the gap and a finite step at it where no attraction would give a smooth rise from zero, and it says which crystals keep their excitons at room temperature.

quantum · Bands A light panel that blocks one band as a heavy one would. Sound transmission loss at normal incidence against frequency, on a logarithmic frequency axis. Dashed: a limp panel of 2 kg/m², following the mass law, 13.4 dB at 300 Hz. Dotted: the same panel made 3 kg/m² by adding 1 kg/m² of plain mass, 16.8 dB. Solid: the 2 kg/m² panel with the same added mass hung on springs tuned to 300 Hz (damping 0.02). It blocks 35 dB at 300 Hz — the loss the mass law would give a wall 26 kg/m² heavy — and just above, at 367 Hz, falls to 5.2 dB, far below even the bare panel's 15.1: there the panel lets sound through more easily than if the resonators were not there.

The wall made heavy only at one note

A wall stops sound by being hard to shake, and how hard a plain wall is to shake is its weight: that is the mass law, and it makes quiet walls heavy. Hang small masses on springs inside a light panel, tuned to one frequency, and near that frequency the panel becomes many times harder to shake than it weighs, because the hidden masses swing against it. A two-kilogram panel then blocks a tone as a wall thirteen times heavier would. The price comes just above the tuning, where the panel's dynamic mass passes through zero and it lets sound through more easily than if the masses were not there.

waves · Impedance

Named alongside it

The objects these essays reach for when they reach for this one.

Bloch wavePeriodic mediaDispersion relationTransfer matrixAbsorptionThe Boltzmann factorChemical potentialConductivityDetailed balanceEffective massEvanescent waveGroup velocity

All concepts