Concept

Conductivity — where it appears

How readily a material carries current for a given field, being the one property of a metal that eddy-current braking depends on. It is the reciprocal of resistivity, spans twenty-four orders of magnitude between a metal and a good insulator, and falls with temperature in a metal while rising in a semiconductor.

Named by 7 essays across 4 fields — each of them below, with the objects they name alongside it.

One well, two wells, and the band they become. The energy levels of a chain of identical wells, for 1, 2, 3, 6, 12, 40 of them, with an on-site energy of -4 eV and a coupling of -0.9 eV between neighbours. One well has one level. Two split it into two, 1.80 eV apart. By 40 the levels have filled a band 3.59 eV wide, which is closing on the limit of four times the coupling, 3.60 eV — and no further widening happens however many more wells are added. The count of levels grows with the number of wells; the width of the band does not.

What happens when the wells get close

Two atoms brought together split one level into two. A thousand split it into a thousand, packed into a band whose width stops growing after the third. Whether that band is full or half full is the whole difference between a wire and a window.

quantum · Bands
A metre of tube, with and without the metal. The magnet's position against time over a 1.00 m drop, integrated from Newton's second law with the eddy-current drag included, and the same fall with the drag switched off. The braked descent takes 2.09 s against 0.45 s in free fall. After a transient of about 50 milliseconds — the mass divided by the drag coefficient, and the only timescale in the problem — the trace is a straight line, which is to say the magnet is falling at a constant 49.0 cm/s. Every joule of the 118 mJ of gravitational energy released has gone into resistive heating of the wall, and none into the magnet's kinetic energy, since that is the same at the bottom as it was a moment after the start.

The magnet that falls slowly

Drop a magnet down a copper pipe and it takes several seconds to fall a metre, drifting rather than falling. Nothing touches it, the copper is not magnetic, and there is no circuit anywhere. The pipe arrives warm.

electromagnetism · Induction
The field near a neutral point. Field lines near a magnetic null, traced by following the local field direction rather than plotted from the closed form. The field is B ∝ (y, k²x) with k = 1, whose lines are the hyperbolae y² − k²x² = constant and whose separatrices are the straight lines y = ±1x. At k = 1 the X is symmetric and the current density is exactly zero: the field is curl-free, and nothing is stored in it beyond the field itself. The four quadrants are four separate flux systems, and which of them a given line belongs to is the quantity a frozen-in field is not allowed to alter.

The knot the field cannot untie

A perfectly conducting fluid cannot change which field line joins which piece of it. So two flux systems pushed together may be squashed indefinitely and can never merge, and the energy of the squashing accumulates with nowhere to go. The release happens only where the perfect conductivity locally fails — in a sheet three metres thick inside a structure ten thousand kilometres across — and the rate that follows is a hundred thousand times too slow for the flares that are observed.

astrophysics · Flux freezing
A band 3.60 eV wide, and the curvature is the whole story. Energy against wavenumber for one tight-binding band, α + 2β·cos(ka), with α = -4 eV, β = -0.9 eV and a repeat of 300 pm. The band is 3.60 eV from floor to ceiling and periodic in k, so the zone boundary at ka = π is not an edge of anything: it is where the curve turns over. Near the bottom it is a parabola, which is the free-electron dispersion with a different coefficient — a mass of 0.470 m_e rather than one — and near the top it is a parabola the other way up, a mass of -0.470. The inflection between them is at ka = π/2, and it is the point at which a constant force stops producing any acceleration.

The mass a curve decides

An electron in a solid answers a force with a mass that is nothing to do with the mass of an electron. It is set by how sharply the band bends, it is smaller than the free value in a wide band and larger in a narrow one, and near the top of any band it is negative — which is why aluminium's Hall voltage has the sign of a positive carrier and no adjustment to an electron count can repair it.

quantum · Bands
Skin depth against frequency, over eleven decades. The skin depth of copper, stainless steel, seawater, mu-metal against frequency, both axes logarithmic. Every line has the same slope, −½, because the depth goes as the inverse square root of the frequency for all of them; what separates them is conductivity and permeability, which enter the same way. Three points are marked and each is a practical fact. Copper at mains frequency has a skin depth of 9.22 mm, so a busbar of that thickness carries current throughout and a thicker one does not. Copper at a gigahertz has 2.1 µm, so the current in a microwave component runs in a layer thinner than the plating and the surface finish becomes the conductor. Seawater at the frequency navies use to signal submerged submarines has 28.9 m, which is why that link is measured in tens of hertz and carries a few characters a minute. Mu-metal is the outlier and the reason it exists: its conductivity is forty times worse than copper's and its permeability twenty thousand times better, so at low frequency it is the one material on the chart that is thin.

How far a field gets into metal

The first three rungs of this ladder all say the field inside a conductor is zero, and all three assume the electrons have had time to move. Give them less time and the field gets in — 9.2 millimetres into copper at mains frequency, 2.1 microns at a gigahertz — and the metal box that silences a radio does almost nothing about the cable running past it.

electromagnetism · Conductors
The current crowding into a contact spot. A meridional section through a circular contact between two solids, with the spot at the centre. The closed curves are equipotentials and the curves running through the spot are current lines, each carrying an equal share. Both are exact: in the coordinates built on the spot's rim the equipotentials are confocal spheroids and the current lines confocal hyperboloids, and in this section they are ellipses and hyperbolas. What the picture shows is that the current has to converge from a region many spot radii across and then spread again, and that the potential falls almost entirely within a few radii of the contact. The equipotential drawn at 12% of the drop sits 5.2 radii away, and everything beyond it contributes that last 12%.

The resistance that is a length

Two metals touching do not touch over the area they appear to. Current crosses at a few small spots and has to converge into each one, and the resistance of that convergence contains no area and no path length — only the size of the spot, divided into the resistivity.

electromagnetism · Conductors
One dimensionless group between an engine and Carnot. The efficiency of a thermoelectric couple against the temperature of its hot side, with the cold side at 300 kelvin, for 4 values of the figure of merit, and the Carnot ceiling drawn above them. The expression has exactly one material quantity in it — the dimensionless group formed from the Seebeck coefficient squared, the electrical conductivity, the temperature and the thermal conductivity — and everything else is the two temperatures. At 600 kelvin, a figure of merit of one gives 10.8 per cent against a Carnot ceiling of 50.0, and a figure of merit of four gives 22.6. The approach to the ceiling is slow: every doubling of the group buys less than the last, so the difference between a good material and a perfect one is smaller than the difference between a poor material and a good one.

An engine with one number in it

A thermoelectric couple has no moving part and no working fluid, and its efficiency is the Carnot value multiplied by a factor containing exactly one dimensionless group of material properties. Sixty years of effort have moved that group from about one to about two, and the reason it is hard is that its three ingredients are not independent: raising the conductivity ruins the coefficient it is squared against, and the only lever that is really free is the heat the lattice carries.

thermodynamics · Heat engines

Named alongside it

The objects these essays reach for when they reach for this one.

Band gapDissipationEddy currentsFlux freezingBand structureBloch waveThe Boltzmann factorBoundary conditionsCarnot efficiencyConductorConductorsConservation of energy

All concepts