Concept

Boundary condition — where it appears

What a field or a wave is required to do at the edge of the region it lives in — vanish, be flat, or match something outside. It is what turns a differential equation with a continuum of solutions into a discrete set of modes, and it decides both which frequencies exist and how many there are below any given one.

Named by 15 essays across 5 fields — each of them below, with the objects they name alongside it.

Two ways to weaken a surface. Surface tension is a property of a surface rather than a constant of a liquid, and this shows how far it moves. The steep curve is water with ethanol dissolved in it, against ethanol mole fraction, through nine measured points: two per cent of ethanol takes the tension from 72 to 56.4 mN/m, a fall of 22% for a change of composition small enough to taste and not to see. The initial slope is 837 mN/m per unit of mole fraction, because ethanol collects preferentially at the surface and a little of it covers a great deal of area. The gentle line is pure water against temperature, read on the same horizontal axis as degrees rather than fraction: about 0.15 mN/m per degree, so a difference of ten degrees across a surface is worth about a millinewton per metre. Neither dependence would be interesting if surfaces were uniform. What makes them matter is that a difference in tension across a surface is a force along it, and nothing in the liquid prevents such a difference from existing.

The surface that pulls toward the stronger side

Surface tension is usually treated as a constant of a liquid, and it is not — it depends on temperature and on what is dissolved, and a difference in it along a surface is a force along that surface — which drags the liquid underneath and needs no pressure difference at all.

fluids · Surface tension
How many modes a square has below a given wavenumber. The number of vibration modes of a square with wavenumber below k, counted exactly — every eigenvalue of this region is a closed form, so the staircase is the true count and not an estimate. There are 265 of them below k = 60. The smooth curves are what Weyl's law predicts. The upper one is the leading term alone, the area times k² over 4π, and it is too high by 21.5 modes at the right-hand edge; the lower one subtracts the perimeter term, the perimeter times k over 4π, and is out by 2.4. The content of the law is that the count depends on the region through its area and its perimeter and — to this order — through nothing else at all: not through its shape, not through where its corners are, not through whether it is convex. The staircase's steps are the individual modes, and they cluster where two different pairs of indices give the same wavenumber. That the count is smooth in the large while being a staircase in the small is what makes a mode count usable in thermodynamics, where it appears as a density of states and never as a list.

How many ways there are to vibrate

A drum has infinitely many modes, and below any given frequency it has a finite number of them. That number turns out to depend on the drum's area and the length of its rim and — to the accuracy anybody uses — on nothing else about its shape. Almost every result in thermal physics that involves waves is an application of that count.

waves · Standing waves
A refraction with no wave in it. Field lines crossing the boundary between two dielectrics whose permittivities differ by a factor of 4, at incidences of 12°, 26°, 40°, 54°, 68°. Nothing is oscillating and nothing is travelling: these are static fields, and the only inputs are that the component of E along the surface is the same on both sides and that the component of D across it is. Dividing one condition by the other gives the ratio of the tangents of the two angles, and it comes out equal to the ratio of the permittivities — measured off the constructed directions as 4.000, 4.000, 4.000, 4.000, 4.000, against 4. The lines bend towards the surface on the side with the larger permittivity, which is the opposite sense from a light ray entering glass, and the chart on the right shows the whole relation: it is a version of Snell's law with the sines replaced by tangents, and there is no speed anywhere in it. Two things follow that are worth carrying. A field line meeting a surface at grazing incidence stays nearly parallel to it whatever the materials, so the ratio matters least where the field is largest along the surface. And in the limit of a very large ratio every line comes out very nearly perpendicular on the low side, which is the electrostatic ancestor of a conductor's boundary condition — a conductor is the ratio taken to infinity.

A refraction with no wave in it

A field line crossing from one dielectric into another bends, by a law that looks exactly like Snell's with the sines replaced by tangents. Nothing is oscillating, nothing is travelling, and no speed appears anywhere in the derivation — only the two conditions that say what a boundary may and may not do to a field.

electromagnetism · Dielectrics
How far into the ground a surface wave goes. The horizontal and vertical displacements of a Rayleigh wave against depth, in wavelengths, at Poisson's ratio 0.25, each divided by the largest displacement anywhere. Both fall off exponentially, and at one wavelength down the vertical component is 19.3 per cent of its surface value — so the wave is confined to a skin about a wavelength thick, and the thickness is set by the wavelength rather than by anything about the material. The horizontal component changes sign at 0.193 wavelengths, which is not a node of a standing wave but a reversal: above that depth the ground moves one way round its elliptical orbit and below it the other. A long-period wave therefore samples deep rock and a short-period one samples only the surface, which is what makes a seismogram's dispersion a measurement of the structure underneath.

The wave a surface is enough to hold

A pipe guides with walls and a fibre guides with a slower core. A solid needs neither: one free surface binds a wave that is not a bulk wave bouncing but a separate solution, travelling slower than any wave in the material, dying away exponentially into it, and carrying its energy round a circle instead of over a sphere — which is why it is the part of an earthquake that knocks buildings down.

waves · Guided waves
Four modes of a string that is heavier in one place. The first four modes of a string whose mass per unit length rises to 5 times the light end's over a smooth bump centred 62 per cent of the way along, drawn beneath them. Nothing is symmetric any more: the shapes bunch up over the heavy region, where the local wavelength is shorter, and the amplitudes there are smaller. The frequencies are 1.70, 4.01, 6.10, 8.12, which are in the ratios 1.000, 2.361, 3.590, 4.779 rather than 1, 2, 3, 4 — this string has no harmonics and would sound like a bell rather than a violin. What has not changed is the one thing an ordering needs: the interior zeros, marked, run 0, 1, 2, 3 exactly as they do on a uniform string. That is Sturm's theorem, and the nodes here are counted on the computed shapes rather than assumed.

The count that cannot be cheated

A string with a lump in it has no harmonics, no symmetry and no obvious order to its modes. It has one thing left: the nth mode crosses the axis exactly n−1 times, whatever the string is made of. Ordering by frequency and ordering by node count turn out to be the same operation, and in two dimensions the equality quietly becomes an inequality.

waves · Standing waves
Where the refracted ray comes from, drawn with a compass. Wavevectors in units of the vacuum wavenumber, for light arriving at 30° from a medium of index 1.5 at a medium of index 1. Every direction available in the first medium lies on the circle of radius 1.5 and every direction available in the second on the circle of radius 1; the horizontal axis lies in the interface. The boundary cannot change the component along itself, because the two sides have to agree on the phase at every point of the interface, so the refracted wave is fixed by the vertical line at 0.7500 — and where that line cuts the smaller circle is the refracted direction, 48.59° from the normal. Nothing about least time or about wavefronts enters, and the ratio of sines is what the construction reads when the two radii are written as indices. The normal component is not conserved and is not meant to be: it goes from 1.2990 to 0.6614, which is the whole of the difference between the two rays.

The law that only asks about one component

A boundary between two media cannot change the part of a wave that runs along it, because both sides have to agree on the phase at every point of the surface at every instant. That single restriction produces the refracted ray, the critical angle, the evanescent field and every order of a diffraction grating, out of one drawing made with a compass.

optics · Refraction
The outward pull on a charged surface. Electrostatic pressure against the field at a conductor's surface. The quantity is ½ε₀E², the energy density of the field itself, and it is outward whatever the sign of the charge — like charges repel, and a charged surface is trying to fly apart. The factor of a half is the interesting part and is where a first attempt goes wrong: the field is σ/ε₀ outside and zero inside, and the layer of charge feels neither of those but their mean, because no charge exerts a force on itself. 0.5 MV/m gives 1.1 Pa, 1 MV/m gives 4.4 Pa, 2 MV/m gives 17.7 Pa, 3 MV/m gives 39.8 Pa, 5 MV/m gives 110.7 Pa. Those are small pressures — three megavolts per metre is the breakdown field of air and pulls with about a hundredth of an atmosphere — which is why electrostatic forces shape soap films and dust and not much that is stiffer, and why the same pressure set against surface tension has a definite size of drop at which it wins.

The pressure a charge puts on its own metal

Charge on a conductor sits on the surface and tries to leave. The outward pull is half epsilon-nought E squared, the half is because a charge exerts no force on itself, and setting that pull against surface tension gives the largest a charged drop is allowed to be — a number Rayleigh wrote down in 1882 and an industry now depends on.

electromagnetism · Conductors
The year, arriving underground at four different times. Temperature against depth in soil of diffusivity 0.5 mm²/s, at four times of year, measured from the annual mean. The surface swings by ±12 K; the swing underground is smaller and later, and both are governed by one length, δ = √(2D/ω) = 2.24 m. The amplitude falls as e^(−z/δ) — the dashed envelope — and the phase lags by z/δ radians, so the curves lean over as they go down and cross the axis at different depths. At 7.0 m the lag is half a year: the ground there is at its coldest in August and its warmest in February, in antiphase with the sky, with a swing of 0.52 K left. That is a cellar, and it is also why a water main below about a metre and a half does not know that it froze last week.

The summer that reaches the cellar in December

Drive the diffusion equation at its boundary instead of releasing something into it and the solution is a decaying, lagging oscillation with a single length in it. That length governs both the shrinking and the delay, which is why the depth at which the ground is coldest in August is fixed by the same number as the depth at which the seasons stop being felt at all.

thermodynamics · Diffusion
Where a small weight is felt, and where it is not. The fractional change in the frequency of harmonic 3 of a stretched string when a point mass of 0.06 of the string's own mass is placed at each position along it. The solid curve is the exact answer, found by solving the string's frequency equation for the loaded string at each position; the dashed curve is the first-order prediction, minus the mass fraction times the square of the mode shape. The two agree to 10.4 per cent at the antinode, where the shift is largest. Every node is a place where the exact shift is zero to better than a part in a thousand million, and that is not an approximation: a mass at a node is never moved by the mode, so it takes no part in the motion and cannot change its rate. Between the nodes the shift follows the square of the displacement, which is the square of the amplitude — the mass is felt in proportion to the kinetic energy the mode was already keeping there.

The dent that raises the note

Push a wall of a resonator inwards and the pitch goes up or down depending entirely on where the wall is pushed. A mass added at a node changes nothing at all; the same mass at an antinode changes as much as it can. One rule covers a loaded string, a tuned microwave cavity and a bead drawn through a resonator to read out its field.

waves · Standing waves
Two solutions, and nothing in the equations to choose between them. A spherical pulse leaving a point and a spherical pulse arriving at one, each drawn at three times 0.35, 0.6, 0.85 in units where the speed is one. Both are exact solutions of the same wave equation, which is checked here by differencing the drawn samples twice in space and twice in time and requiring the residual to vanish for each. The one on the left is what is always used; the one on the right is discarded, and the equations do not do the discarding. The incoming pulse grows as it converges for the same reason the outgoing one decays as it spreads — the same energy through a smaller sphere — and it is as consistent with conservation as its mirror image is.

The solution that is thrown away

Maxwell's equations admit a field that converges on a charge exactly as readily as one that leaves it, and nothing in them prefers either. Retardation is a boundary condition rather than a law. Which boundary condition is right has been argued about for a century, one of the answers makes the arrow of time a property of there being absorbers, and the laboratory version of the question — whether an atom emits at all — has a measured answer that depends on what is listening.

electromagnetism · Retardation
The pattern that stands still while the air goes through it. Streamlines of a steady 20 metre-per-second wind over a bell-shaped ridge 800 metres high and 6.0 kilometres wide, in air whose buoyancy frequency is 1.05e-2 per second. Nothing in the picture is moving: the air crosses it from left to right at 20 metres a second and the waves stay where they are, because standing still is what selects them. The vertical wavelength is 2πU/N = 11.9 kilometres, and the crests lean upstream as they rise — checked here by finding the maximum displacement a quarter of a wavelength up, which sits well upstream of the ridge. That tilt is the signature of energy travelling upward, and it is the feature every hand-drawn version of this picture gets backwards. Cloud forms at the crest of each wave where the air is highest and coldest, which is why the lens-shaped clouds sit stationary in a moving airstream.

The wave that is required to stand still

A stratified fluid supports internal waves at every wavelength there is. Put a steady wind over a ridge and the requirement that the pattern stay put picks exactly one of them — 2πU/N, and nothing about the mountain appears in it. The clouds that mark the crests sit still while the air goes through them at twenty metres a second, and the momentum the wave carries away is delivered thirty kilometres up.

fluids · Stratification
A reflection that keeps the angle to gravity and not to the wall. An internal wave beam of frequency 0.5N reflecting from a slope of 12°, with the wavelength ratio for slopes of 12°, 20°, 28° computed beside it. The frequency fixes the angle the energy makes with the horizontal — 30.0° here — because the restoring force is gravity and gravity is vertical, so the reflected beam must leave at that same angle whatever the wall is doing. Incident and reflected rays are therefore not mirror images, and the wavelength changes on reflection by sin(θ+α)/sin(θ−α). A flat floor gives one, checked exactly. A slope approaching the ray's own angle gives infinity, checked as the limit, and that is where a basin's internal tide is compressed until it breaks.

The reflection that changes the wavelength

An internal wave's frequency fixes the angle its energy makes with gravity, so a sloping wall cannot send it back the way a mirror would. The reflected beam leaves at the same angle to the vertical rather than the same angle to the wall, its wavelength changes by a factor that diverges when the slope matches the ray, and in a closed basin the changes accumulate until every ray in the fluid lies on one line.

fluids · Stratification
A wave with two directions in it. Light at 60° entering silver, 550 nm, whose index is 0.055 + 3.32i. Phase matching along the boundary fixes the transmitted wave's tangential wavenumber and leaves the normal one to the medium, which supplies a complex answer. The real part decides where the phase goes and the imaginary part where the amplitude does, and they are not the same direction: the surfaces of constant amplitude are parallel to the interface, because the decay is entirely into the metal, while the surfaces of constant phase are tilted by 86.5° from the normal. There is therefore no single refracted angle to quote. The familiar picture, in which one set of parallel planes carries both, requires the absorption to be exactly zero.

The angle that is two angles

Snell's law survives a complex index by giving a complex answer, and a complex angle is not an angle. What the phase-matching argument actually fixes is the tangential wavenumber, and when the medium absorbs, the surfaces of constant phase and the surfaces of constant amplitude stop being parallel. In silver at 550 nanometres the phase fronts run within four degrees of the surface while the amplitude decays straight into it.

optics · Refraction
Two intersections, and the rule that picks one. The phase-matching construction for light arriving at 40° from a medium of index 1 into one of index -1. The circles are each medium's own relation between wavevector and frequency; the vertical line is the tangential wavenumber, which the boundary conserves. The line crosses the second circle twice, and the construction alone does not say which point is the answer — the rule that does is that energy must travel away from the interface. For a positive index the energy runs along the wavevector and the upper point is taken. For a negative one the energy runs against it, so the lower point is taken, the wavevector points back toward the boundary, and the ray leaves at -40.0° — on the same side of the normal as it arrived. Nothing in the drawing has changed except which intersection is circled.

The ray on the wrong side of the normal

The phase-matching construction draws a circle and a line, and the line crosses the circle twice. Every earlier construction silently took the upper intersection. Which one is physical is decided by where the energy goes rather than by where the wavevector points, and in a medium whose group velocity opposes its phase velocity the answer is the other one — so the refracted ray leaves on the same side of the normal it arrived on, a flat slab focuses, and a lens can beat the diffraction limit until loss stops it.

optics · Refraction
Snell's law with space and time exchanged. Two constructions on the same diagram of frequency against wavenumber, with the light lines of a medium of index 1 and of index 1.5. On the left, a boundary in space: the wave crosses a still surface, the frequency is conserved, and the horizontal line at the incident frequency meets the new medium's line at a wavenumber 1.5 times larger — the familiar shortening of the wavelength. On the right, a boundary in time: the whole medium changes at once, the wavenumber is conserved, and the vertical line at the incident wavenumber meets the new medium's line at a frequency 0.667 times the old one. The vertical line also meets the new line's negative-frequency branch, which is a wave running backwards: a reflection in time. A spatial boundary reflects into the same frequency and a temporal one into the same wavelength.

The reflection that needs no surface

Change the refractive index of a whole medium at one instant and a wave already travelling through it splits in two, one part running on and one running back, though there is no surface anywhere for it to reflect from. A boundary in time is Snell's law with space and time exchanged: the wavelength is kept and the frequency changes, momentum is conserved and energy is not.

optics · Refraction

Named alongside it

The objects these essays reach for when they reach for this one.

RefractionDispersion relationEvanescent wavePhase matchingDispersionEigenvalueGroup velocityPermittivityRefractive indexSnell's lawAnisotropyBuoyancy frequency

All concepts