Illustrated Physics
physics, drawn
Concept

Viscoelasticity — where it appears

The behaviour of a material that both stores and dissipates the energy put into it, responding partly as a solid and partly as a liquid. Which it looks like depends on how long the observation lasts compared with the material's own relaxation time, so pitch shatters under a hammer and flows in a funnel.

Named by 7 essays across 3 fields — each of them below, with the objects they name alongside it.

Four answers to one push. Shear stress against shear rate for four fluids. The straight line through the origin is the Newtonian definition and is the only one of the four for which the word viscosity names a number. The Bingham fluid does not move at all until the stress passes 0.4, which is why toothpaste holds a shape on a brush and why wet concrete can be stood in a heap.

The fluid that answers back

For water, stress is proportional to how fast it is sheared, and the constant of proportionality is its viscosity. For paint, blood, ketchup and cornflour in water, it is not — and once the proportionality goes, so does the idea that viscosity is a number a substance has.

fluids · Rheology Solid and liquid are answers about a duration. The relaxation time of seven materials, on a logarithmic axis spanning 39 decades, against the length of one observation. A material behaves as a solid when its relaxation time is longer than the observation and as a liquid when it is shorter, so the vertical line is what decides which — and it is a property of the observer. At 1 s, 4 of these are solids. Move the line six decades to the right and pitch joins the liquids; move it far enough left and water is a glass, which is not a figure of speech but what a picosecond pulse measures.

The liquid that remembers

Pitch shatters like glass under a hammer and flows through a funnel over a decade. Neither behaviour is the true one. What decides which a substance shows is not the substance but the length of the observation, and the ratio between the two has a name and a number.

fluids · Rheology The same liquid climbs a thin rod and is thrown off a thick one. The height of the free surface against distance from the axis, for rods of 10.0, 25.0, 60.0 millimetres radius turning at one revolution a second in the same polymer solution, with the Newtonian answer dashed. Two effects compete and they fall off at different rates: a hoop tension along the curved streamlines pulls the fluid inward and lifts it, falling as the fourth power of the distance, while the centrifugal term pushes it outward and lowers it, falling as the second. Near a thin rod the fourth power wins and the liquid climbs — 2.21 millimetres at the thinnest. Beyond a radius of 34.64 millimetres it does not, and the same fluid at the same speed is thrown outward exactly as water would be. The changeover is a property of the fluid and the rod together, so a demonstration that works on a glass stirring rod fails on a spoon handle.

The liquid that climbs the rod

Stir water with a rod and it is flung outward, leaving a dip at the centre. Stir a polymer solution and it climbs the rod instead. Nothing about the viscosity can produce that, however large it is made — what produces it is a second stress that appears in shear and has no Newtonian counterpart at all, growing as the square of the rate where the familiar one grows in proportion.

fluids · Rheology Above a half, the chains stop letting go. The extensional viscosity of a dilute polymer solution, as a multiple of its zero-shear viscosity, against the accumulated stretch (Hencky strain, the stretch rate times the time), on a logarithmic axis, for stretch rates whose product with the relaxation time is 0.1, 0.4, 0.6, 1. The polymer carries 90 per cent of the viscosity. Dashed curves are the Oldroyd-B dumbbell, integrated from its conformation equation and matching its closed form; solid curves are the same chains with a finite length, FENE-P with L² = 400. At 0.1 the Oldroyd-B viscosity reaches 3.37 and the finite chain 3.37 by a strain of 6; at 0.4 the Oldroyd-B viscosity reaches 9.49 and the finite chain 9.25 by a strain of 6; at 0.6 the Oldroyd-B viscosity reaches 58 and the finite chain 49 by a strain of 6; at 1 the Oldroyd-B viscosity reaches 725 and the finite chain 329 by a strain of 6. Below one half the viscosity settles at a few times the shear value. Above it the Oldroyd-B chain stretches without limit and its resistance grows exponentially, while the finite chain grows until it is nearly fully extended and then stops, hundreds of times higher than it began.

The stretch a chain cannot outrun

A Newtonian liquid pulled into a thread resists exactly three times as hard as it resists being sheared, whatever it is made of. A polymer solution resists three times as hard only until the stretch rate passes one over twice its relaxation time. Past that, its chains can no longer recoil as fast as they are pulled apart, and the same liquid that is barely thicker than water in a stirred beaker becomes hundreds of times stiffer in a thread.

fluids · Rheology The heat an eccentricity buys. The power tides dissipate inside Io against the eccentricity of its orbit, from (21/2)(k₂/Q) G M² R⁵ n e²/a⁶ with k₂/Q = 0.015: it grows as the square of the eccentricity. At Io's forced eccentricity, 0.0041, it is 9.3 × 10¹³ W, against about 1.0 × 10¹⁴ W measured from Io's infrared glow — the same to within the uncertainty of both — and against 4.7 × 10¹³ W for the whole of the Earth's internal heat, from a body forty-three times Io's volume. Halve the eccentricity and the heating falls fourfold; take it away and Io would freeze.

The moon kept molten by its neighbours

Io is the most volcanic body known, with hundreds of active vents and lava hotter than any erupting on the Earth, on a moon smaller than the Earth's own and far too small to have kept any heat from its formation. The heat is made continuously, by tides: Jupiter stretches Io, and because Io's orbit is slightly eccentric the stretch changes every day and a half, flexing the rock and warming it. Tides should have rounded the orbit off in a hundred thousand years and switched the heating off. They cannot, because two other moons keep tugging the orbit back into its oval, and the heat Io radiates is paid for by Jupiter's spin.

astrophysics · Self-gravity The pressure under a wheel rolling on a soft surface. The pressure under a rigid wheel of radius 30 cm carrying 3 kN per metre of width as it rolls over a rubber-like bed, against position along the contact (ahead of the axle to the right), scaled to the largest pressure and the widest contact, at three speeds. The bed relaxes with times of 2 and 20 ms. At 1 mm/s the pressure is symmetric and its resultant passes through the axle. At 1.0 m/s the material ahead is being squeezed faster than it can flow and pushes back harder than the recovering material behind, which lags and lets go early: the resultant sits 6.39 mm ahead of the axle. At 1000 m/s the bed has no time to relax at all and behaves as a stiffer elastic solid, symmetric again. A wheel is held back by where its support pushes, not by any sliding.

The push a millimetre ahead of the axle

A wheel rolling freely on a flat road slows down, and nothing in it slides. What holds it back is where the road pushes on it: not directly under the axle but a little ahead, because the material in front of the contact is being squeezed and pushes back harder than the material behind, which is recovering and lags. A car tyre's push is about three millimetres ahead of its axle, a train wheel's about two-thirds of a millimetre, and that offset, divided by the radius, is the whole of rolling resistance. It peaks at the speed where the time under the wheel matches the time the material takes to relax, and the same loss, at a different frequency, is what gives a tyre its grip.

mechanics · Friction Nine drops in eighty-four years. The time between successive drops of the pitch in Thomas Parnell's funnel, cut open in 1930, against the year each drop fell: 8.2, 7.2, 8.1, 8.3, 8.7, 9.3, 12.4, 13.4 years. The first seven intervals average 8.3 years and scatter by about a year either way; after the building was air-conditioned in the late 1980s the next two took 12.4 and 13.4, averaging 12.9. Read as a viscometer through the funnel's geometry, the early rate gives a viscosity of about 2.3 × 10⁸ Pa·s — some two hundred billion times water's.

The drop that takes a decade

In 1927 a physics professor in Brisbane poured heated pitch into a sealed funnel, waited three years for it to settle, and cut the stem. Nine drops have fallen since. The record is a viscometer read about once a decade, and it gives the pitch a viscosity two hundred billion times water's. It also records the building's air-conditioning: after 1988 the drops slowed from eight years apart to thirteen, and a fall of a degree and a half in the average temperature is enough to explain it. The same reasoning, applied to medieval window panes, settles an old story without guessing what glass does at room temperature.

fluids · Viscosity

Named alongside it

The objects these essays reach for when they reach for this one.

Relaxation timeViscosityConstitutive lawDissipationHysteresisPolymer solutionRheologyWeissenberg numberActivation energyArrheniusCoil stretch transitionContact mechanics

All concepts