Concept

Hysteresis — where it appears

A response that depends on the history of the driving rather than only on its present value, so that a cycle traces a loop rather than a line. The area of the loop is the energy lost per cycle, which is what makes rubber grip, what heats a transformer core, and why a wetting front sits at a different place from a drying one.

Named by 19 essays across 4 fields — each of them below, with the objects they name alongside it.

Where a magnet actually sits on its own curve. The second quadrant of a magnet's B–H curve, for a material with a remanence of 1.28 T, and the load lines four shapes of it impose. A magnet's own poles put it in a reverse field of N·M, so the working point is where the curve meets the line B = −μ₀(1−N)/N·H. A long thin magnet with N = 0.02 keeps 98 per cent of its remanence and a squat one with N = 0.7 keeps 30 per cent — the same material, cut differently.

The magnet that has to fight its own field

A bar magnet's own poles put it in a reverse field, so the same material cut short and fat is weak and cut long and thin is strong. And a magnetised material does not have a magnetisation — it has a magnetisation and a history, which is why the word for what it does is the Greek for coming late.

electromagnetism · Magnetisation
Rough contact grows as W^1.000, and one smooth bump as W^0.667. Real contact area against load, both logarithmic, three ways. Plastic flow of the asperities gives A = W/H, a slope of exactly one, which is the account Bowden and Tabor's argument uses. A single elastic sphere gives Hertz's answer, A ∝ W^(2/3), and a friction coefficient falling as W^(−1/3) — Amontons' law would be false. A rough elastic surface, with many asperities spread exponentially in height and integrated here rather than quoted, gives a slope of 1.0000, because pressing harder mostly recruits new contacts rather than enlarging existing ones. The dotted curve repeats that integration with a Gaussian spread of heights and gives 0.9695 — the upper tail of a Gaussian is nearly exponential, so the answer is nearly and not exactly linear. Amontons' law does not need plasticity. It needs roughness, it is exact for one distribution and good to three per cent for another, and it survives whichever way the individual junctions deform.

The grip that is not a coefficient

A friction coefficient is independent of load and of area, and the reason is usually given as plastic flow of the asperities. It is not — a rough elastic surface gives the same law, integrated here to a slope of 1.0000, because pressing harder recruits new contacts rather than enlarging old ones. What breaks the law is a contact that is smooth, or a material that dissipates in its bulk — where μ passes one and stops being a coefficient at all.

mechanics · Friction
A drive at one frequency, and what comes back at three times it. The Fourier components of the steady motion of an oscillator driven at a single frequency ω = 1.35, for drive strengths of 0.02, 0.05, 0.1. The equation is a harmonic oscillator with a cubic term added, and the components are projected out of the integrated motion rather than assumed. A linear oscillator answers only in the first column. This one answers in the third as well, because x³ of a cosine contains a cosine of three times the angle. The third harmonic grows as the drive to the power 3.00 where the fundamental grows as the power 1.00, so it is negligible at small drive and not at large — which is why nonlinearity in an instrument is a specification rather than a yes or no.

The oscillator that answers at three times the question

Push a spring hard enough that the parabola stops being the whole story, and three things happen that a linear oscillator cannot do: it emits frequencies nobody supplied, its resonance leans over, and its amplitude at one drive frequency depends on where the drive has been.

mechanics · Harmonic approximation
A magnetisation curve, and the same curve magnified. On the left, the position of a domain wall against the applied field, over the whole of a crystal. It looks like a curve. On the right, a window 2.0% of its width, taken 42% of the way across, at the magnification a sensitive measurement reaches: the wall does not move at all while the field rises, then jumps, then stops again. The largest jump in the window covers 0.67 units of wall position in no field change at all. There is nothing smooth underneath this — the smooth curve on the left is a staircase with 1400 steps in it, drawn small.

The curve that is really a staircase

A magnetisation curve is drawn as a smooth line and is nothing of the sort. Measured finely enough it is a sequence of jumps of every size, audible as a crackle in a coil, with no typical jump and no smooth motion underneath.

electromagnetism · Magnetisation
Force against slip, and the knee between them. The force a tyre delivers against how much faster its tread is going than the road, for a patch 120 mm long under 4000 N with a friction coefficient of 1. The curve is the integral over the bristles, and the dashed line is the cubic the brush model gives in closed form; they agree to 0.00 per cent of the sliding force. The first slope is 80 kN per unit slip, and it belongs entirely to the elasticity of the rubber — at vanishing slip nothing is sliding, so no friction coefficient can appear in it. Full sliding is reached at 15.0 per cent slip and not before. Everything a driver calls grip lives on the rising part of this curve, at a few per cent of slip, where the patch is partly stuck and partly sliding — and the quantity that decides handling in that region is the slope rather than the friction coefficient at the top.

The grip that needs a little slipping

A wheel that transmits any force at all is not rolling. Part of its contact patch is stuck to the road and part is already sliding, and the force it delivers is a measure of how much has given up. The useful part of the curve is a few per cent of slip, the peak is not the end of it, and everything past the peak is unstable.

mechanics · Friction
A hundred thousand taps, and still not finished. The packing fraction of a column of grains against the number of taps it has been given, on a logarithmic horizontal scale, for several tap intensities. The grains start where pouring leaves them, around 0.55, and climb towards something near 0.64. At an intensity of 1.2 the packing reaches 0.6318 after a hundred thousand taps; At an intensity of 2 the packing reaches 0.6327 after a hundred thousand taps; At an intensity of 3 the packing reaches 0.6338 after a hundred thousand taps, which is still 0.0097 short of the asymptote. The shape is what matters. On a logarithmic axis the curve is close to a straight line over four decades, which means the packing improves by about the same amount for each factor of ten in the number of taps — not for each additional thousand. Going from a hundred taps to a thousand buys as much as going from a thousand to ten thousand. An exponential relaxation is over after a few time constants and this is not one. There is no number of taps after which the column is packed; there is only a number after which the next improvement is too small to measure.

The pile that is never finished settling

Tap a jar of grains and it settles. Keep tapping and it goes on settling — logarithmically, so that each factor of ten in the number of taps buys the same small improvement as the last. There is no number of taps after which the column is packed; there is only a number after which the next improvement is too small to measure, and the asymptote everyone quotes is a fitted number rather than a measured one.

fluids · Granular matter
The pore size the air decides. The largest pore radius that holds condensed water in equilibrium with air at a given relative humidity, for water at 25 °C, on a logarithmic radius axis. A concave meniscus lowers the vapour pressure over it by exp(−2γVₘ/rRT), so a pore whose meniscus would be tighter than a radius set by the humidity is in equilibrium only when full. The upper curve is the emptying condition, through a hemispherical meniscus with two curvatures; the lower is the filling condition, through the cylindrical film that lines a pore before it closes, with one — so the same pore fills at a higher humidity than it empties at. At 50% humidity a pore empties below 1.51 nm and fills below 0.76 nm; at 90% humidity a pore empties below 9.96 nm and fills below 4.98 nm; at 99% humidity a pore empties below 104 nm and fills below 52 nm. The radii run from molecular at low humidity to a tenth of a micrometre at 99 per cent, and every one was checked by putting it back into the vapour-pressure relation.

The pore that fills from dry air

Water condenses when the air is saturated — on a flat surface. Over a curved one the vapour pressure is different, higher over a drop and lower over a meniscus, and in a pore a few nanometres across it is low enough that the pore fills with liquid from air at half humidity. The water it holds is under a tension of a hundred megapascals, and the pore empties at a lower humidity than it filled at, for a reason that needs no roughness at all.

fluids · Capillarity
Above a half, the chains stop letting go. The extensional viscosity of a dilute polymer solution, as a multiple of its zero-shear viscosity, against the accumulated stretch (Hencky strain, the stretch rate times the time), on a logarithmic axis, for stretch rates whose product with the relaxation time is 0.1, 0.4, 0.6, 1. The polymer carries 90 per cent of the viscosity. Dashed curves are the Oldroyd-B dumbbell, integrated from its conformation equation and matching its closed form; solid curves are the same chains with a finite length, FENE-P with L² = 400. At 0.1 the Oldroyd-B viscosity reaches 3.37 and the finite chain 3.37 by a strain of 6; at 0.4 the Oldroyd-B viscosity reaches 9.49 and the finite chain 9.25 by a strain of 6; at 0.6 the Oldroyd-B viscosity reaches 58 and the finite chain 49 by a strain of 6; at 1 the Oldroyd-B viscosity reaches 725 and the finite chain 329 by a strain of 6. Below one half the viscosity settles at a few times the shear value. Above it the Oldroyd-B chain stretches without limit and its resistance grows exponentially, while the finite chain grows until it is nearly fully extended and then stops, hundreds of times higher than it began.

The stretch a chain cannot outrun

A Newtonian liquid pulled into a thread resists exactly three times as hard as it resists being sheared, whatever it is made of. A polymer solution resists three times as hard only until the stretch rate passes one over twice its relaxation time. Past that, its chains can no longer recoil as fast as they are pulled apart, and the same liquid that is barely thicker than water in a stirred beaker becomes hundreds of times stiffer in a thread.

fluids · Rheology
Two energies with opposite slopes, and the width between them. The energy per unit area of a domain wall in iron, against the width the wall is assumed to have, split into the two terms that decide it. The exchange term falls as one over the width, because a reversal spread over more atoms turns through a smaller angle between each neighbouring pair. The anisotropy term rises in proportion to the width, because every atom inside the wall points away from an easy direction and pays for it. The sum has a least value, found here by scanning four hundred thousand widths: 92.9 nanometres and 4.46 millijoules per square metre. Neither constant is a dimension of the sample, so neither is the width: it is the first length in magnetism that belongs to the material. The assumed profile turns at a uniform rate, which is not the cheapest way to turn, so this width is 41 per cent above the conventional πδ of the exact profile, and this energy 11 per cent above the exact 4√(AK). A trial function can only ever overestimate, and eleven per cent is how much this one costs.

The first length that belongs to the substance

Every length in magnetism so far has been a length of the sample — a demagnetising factor is a shape, an avalanche cutoff is a sample's own restoring field. A domain wall's width is not. It is √(A/K), made of two material constants and nothing else, and across seven ordinary magnets it runs from two and a half nanometres to nine hundred.

electromagnetism · Magnetisation
The barrier a reverse field takes away. The energy of a single-domain particle against the direction its moment points, in units of its anisotropy energy, for four strengths of reverse field along the easy axis. With no field the two directions are equally good and the barrier between them is exactly the anisotropy energy. A reverse field tilts the landscape and lowers the barrier out of the forward well as the square of the field: at 0.0 of the anisotropy field the barrier is 1.000 KV, at 0.1 of the anisotropy field the barrier is 0.810 KV, at 0.3 of the anisotropy field the barrier is 0.490 KV, at 0.6 of the anisotropy field the barrier is 0.160 KV. Each barrier is located by scanning two hundred thousand directions for the stationary points rather than by substituting the formula. The whole of the argument follows from the barrier being finite: a particle does not need the field that removes the barrier, only time enough to be shaken over what is left of it.

Nothing keeps a magnetisation for ever

A magnetised particle sits in a well with a barrier between it and the other direction, and a barrier of finite height is crossed eventually. So remanence has a lifetime, coercivity is a different number depending on how fast it is measured, and a grain below about twenty nanometres of iron forgets within a second at room temperature.

electromagnetism · Magnetisation
Shake more gently and the grains choose a side. The steady share of the grains in each of two shaken compartments joined by a slot, against B, the parameter that grows as the shaking gets gentler. Below B = 4 the only steady state is an equal share, and it is stable. At B = 4 it becomes unstable and two clustered states appear, continuously, one with each compartment full: the fuller compartment holds 0.855 of the grains at B = 5, 0.929 at 6 and 0.979 at 8. Which compartment fills is decided by the first fluctuation. Nothing in the rules prefers either side, and the equal state that the rules would suggest is the one the grains avoid.

The sand that chooses a side

Divide a box of grains into two compartments with a slot in the wall between them and shake it from below. Shaken hard, the grains share themselves equally, as molecules of a gas would. Shaken a little more gently, they gather in one compartment and leave the other almost empty, and the crowded side is cold and the empty side hot. Nothing sorted them. Every collision between grains loses energy, and a compartment that happens to hold a few more grains loses more of it and stops throwing grains over the wall.

fluids · Granular matter
The shear a pushed contact carries, and where it gives. Across a Hertzian contact of radius a, the normal pressure as a fraction of its peak, which is also the friction limit μp in units of μp₀ (dashed), and the shear traction for a sideways push of 0.3, 0.6, 0.9 times the load that would slide it, μP. Where the shear reaches the dashed ceiling the surfaces slip; inside, they stick. At 0.3 μP the stuck disc has a radius of 0.89a, so 21 per cent of the contact area is slipping; at 0.6 μP the stuck disc has a radius of 0.74a, so 46 per cent of the contact area is slipping; at 0.9 μP the stuck disc has a radius of 0.46a, so 78 per cent of the contact area is slipping. The shear is highest just inside the slipping ring and, in an elastic contact that simply stuck everywhere, would be infinite at the rim: slip at the edge is what removes that singularity.

The contact that slips before it slides

Static friction is supposed to hold perfectly until the load reaches μ times the normal force and then give way. Two elastic bodies pressed together do something else. Push a ball sideways on a flat with any force at all and a ring at the edge of their contact is already slipping, while the centre stays stuck. As the push grows the ring spreads inward, and gross sliding is only the moment the stuck centre shrinks to nothing. Shake the push back and forth and the ring slips each way on every cycle. The contact then loses energy though it never slides, as the cube of how hard it is shaken.

mechanics · Friction
The boiling curve, which turns back. Heat flux from a horizontal surface into water boiling at one atmosphere, on a logarithmic axis, against how far the surface is above the boiling point, also logarithmic, from standard correlations. At a few degrees heat leaves by convection; from about 5 K bubbles nucleate and the flux climbs as the cube of the superheat, to the critical heat flux of 1.11 MW/m² at 20 K. Beyond it the flux FALLS as the surface gets hotter — the transition regime, drawn dashed as the interpolation it is — down to 19 kW/m² at 67 K, the Leidenfrost point, where a continuous film of vapour insulates the surface. Past that, film boiling and radiation let the flux rise again, slowly: 310 kW/m² at 1000 K above boiling. Between the crisis and the Leidenfrost point, a surface 3 times hotter passes 58 times less heat.

The boiling curve that turns back

Heat a surface under water and more heat flows from it the hotter it gets — up to a point. Past about twenty degrees above boiling the bubbles crowd together, merge, and begin to blanket the surface with vapour, and from then on a hotter surface passes less heat, not more, until by a few hundred degrees above boiling it is wrapped in an insulating film and passes fifty times less than it did at its best. Shigeo Nukiyama found the turn in 1934 by melting wires. It is why a water drop skates for a minute on a very hot pan but vanishes in two seconds on a merely hot one, and why every boiler, steam generator and water-cooled reactor is designed around a number called the critical heat flux.

thermodynamics · Phase change
The pressure under a wheel rolling on a soft surface. The pressure under a rigid wheel of radius 30 cm carrying 3 kN per metre of width as it rolls over a rubber-like bed, against position along the contact (ahead of the axle to the right), scaled to the largest pressure and the widest contact, at three speeds. The bed relaxes with times of 2 and 20 ms. At 1 mm/s the pressure is symmetric and its resultant passes through the axle. At 1.0 m/s the material ahead is being squeezed faster than it can flow and pushes back harder than the recovering material behind, which lags and lets go early: the resultant sits 6.39 mm ahead of the axle. At 1000 m/s the bed has no time to relax at all and behaves as a stiffer elastic solid, symmetric again. A wheel is held back by where its support pushes, not by any sliding.

The push a millimetre ahead of the axle

A wheel rolling freely on a flat road slows down, and nothing in it slides. What holds it back is where the road pushes on it: not directly under the axle but a little ahead, because the material in front of the contact is being squeezed and pushes back harder than the material behind, which is recovering and lags. A car tyre's push is about three millimetres ahead of its axle, a train wheel's about two-thirds of a millimetre, and that offset, divided by the radius, is the whole of rolling resistance. It peaks at the speed where the time under the wheel matches the time the material takes to relax, and the same loss, at a different frequency, is what gives a tyre its grip.

mechanics · Friction
How a field enters a superconductor that pins it. The magnetic field inside a slab of type-II superconductor, against position across its thickness, as an applied field is raised from zero, in units of the full-penetration field H = Jc a. Each line is the profile at an applied field of 0.5 H, 1.0 H, 1.5 H, 2.0 H. The field enters from both faces as a wedge whose slope is the most current the pinned vortices can carry, Jc; at 0.5 H it reaches halfway to the middle, at H* it just reaches the middle, and beyond that the whole slab carries Jc and the profile rides up with the applied field. A type-I superconductor would show no field inside at all, and a normal metal the applied field everywhere.

The field a superconductor keeps after all

A superconductor is famous for throwing magnetic field out, and the experiment that showed it is the one that made superconductivity a state of matter. Most superconductors that are actually used do something closer to the opposite: they let the field in as threads, grip the threads where they are, and keep them when the field is taken away. The result is a slope of field inside the material that is as steep as the grip allows and no steeper, which is all that is needed to explain why such a superconductor has a hysteresis loop, heats up in an alternating field, can hang a magnet underneath itself, and can be made into a magnet stronger than any of iron.

electromagnetism · Superconductivity
Two ways for a swing to die. A mass on a spring released 10.6 dead-band widths from rest, against time in units of 1/ω. Red: sliding on a dry surface, whose friction is a constant force; each swing is exactly a cosine, and the turning points fall in a straight line by two dead-band widths per half-cycle until the mass stops, 2.5 cycles after release, at −0.60. Blue: the same mass with viscous damping (damping ratio 0.05), whose force is proportional to speed; the swings shrink by the same fraction each cycle, along an exponential, and never stop. The period is the same in both and the same as with no damping at all to within the viscous case's 0.13 per cent.

The swing that dies in a straight line

A pendulum in air loses the same fraction of its swing every cycle, so its amplitude falls along an exponential and, in principle, never quite reaches zero. A mass on a spring sliding over a dry surface does something else. Its friction is a fixed force, so it loses a fixed amount of amplitude every half-swing — the swings shrink in a straight line — and it stops completely, after a countable number of swings, somewhere inside a band around its natural position whose width is the friction divided by the stiffness. Where in that band it stops depends on where it started, which is why a barometer with friction in it is tapped before it is read.

mechanics · Friction
An ice sheet resting on a bed below the sea. A section along the flow of an ice sheet on the MISMIP benchmark bed, which lies below sea level beyond 480 km from the divide and deepens inland between 974 and 1265 km. Dashed: the height the ice surface would stand at if the ice were just thick enough to touch the bed — 1.11 times the water's depth thick, a ninth of it above the sea. At the rate factor drawn, the balance of snowfall against export has three solutions: grounding lines at 800, 1124, 1376 km. The outer two are stable; the middle one, on the stretch where the bed deepens inland, is not. The ice drawn — its surface a plastic profile, a sketch rather than a solution — rests on the bed out to 1376 km, where it must be 803 m thick to touch it, and floats beyond as a shelf.

The grounding line with nowhere to stop

Where an ice sheet flowing into the sea lifts off its bed and begins to float, buoyancy fixes how thick it is: just thick enough to touch the rock, about 1.1 times the depth of the water. The ice crossing that line goes as the 19/4 power of the thickness, so twice the depth sends out twenty-seven times the ice. On a bed that deepens inland, a grounding line that retreats a little moves into deeper water, exports more, and retreats further. No steady state can sit there, and an ice sheet whose edge reaches such a slope crosses the whole of it.

fluids · Buoyancy
Salt that takes in water from the air at three-quarters humidity. The water held by a crystal of common salt, in grams per gram of salt, against the relative humidity of the air around it at 25 °C, with the humidity rising (solid) and falling (dashed). Rising, the crystal stays dry until 75.2 per cent and then dissolves at once into a drop holding 2.79 g of water per gram — the saturated solution — which goes on drinking as the air gets damper: 4.24 g at 85 per cent, 11.5 g at 95. Falling, the drop does not crystallise at 75 per cent. It sheds water along the same curve, becomes supersaturated, and stays liquid down to about 45 per cent before a crystal finally nucleates and it dries out at once.

The salt that dissolves in the air's own water

Leave a dish of salt in a bathroom and it does not just clump; on a humid enough day it turns into a puddle, though no water was poured on it. Above 75 per cent humidity, common salt pulls water out of the air until it has dissolved itself. The number is not a property of salt's attraction for water in any vague sense. It is the vapour pressure of a saturated salt solution, read as a fraction of pure water's: wherever the air holds more water than that, the solution is the state with the lower chemical potential. Bring the humidity back down, and the puddle does not turn back into salt until the air is far drier — about 45 per cent.

thermodynamics · Chemical potential
A loop, and the butterfly it makes. Left: magnetisation against applied field for a model ferromagnet, as a fraction of saturation, with the field in units of the coercive field — the rising branch and the falling one, crossing zero magnetisation at plus and minus one. Right: the strain the same material shows along the field, as a fraction of its saturation magnetostriction, on the same two branches. Because the strain goes as the square of the magnetisation it does not care which way the magnetisation points, so it is the same at full positive and full negative saturation, and it falls to nothing at the two points where the magnetisation passes through zero — the coercive fields. A loop traced once produces a butterfly traced once: the strain goes through two full stretches for every one cycle of the field.

The hum at twice the mains

A transformer hums, and the note is not the frequency of the mains but twice it: a hundred hertz in Europe, a hundred and twenty in America. The reason is that iron changes shape when it is magnetised, by a few parts in a million, and the change does not care which way the magnetisation points. A core driven at fifty cycles a second therefore stretches a hundred times a second. The same evenness makes the strain trace a butterfly against the field, puts harmonics at every even multiple of the mains and none at the odd ones, and makes the hum climb steeply as the steel nears saturation.

electromagnetism · Magnetisation

Named alongside it

The objects these essays reach for when they reach for this one.

FrictionInstabilityMagnetisationCoercivityContact areaDissipationMetastabilityChemical potentialContact mechanicsDampingDemagnetising fieldDomain wall

All concepts