Concept

Domain wall — where it appears

The boundary between two regions of a material that have settled into different but equivalent arrangements. Examples are opposite magnetisations or opposite bond patterns; its energy sets how easily the regions grow, and some walls bind states of their own.

Named by 5 essays across 2 fields — each of them below, with the objects they name alongside it.

A magnetisation curve, and the same curve magnified. On the left, the position of a domain wall against the applied field, over the whole of a crystal. It looks like a curve. On the right, a window 2.0% of its width, taken 42% of the way across, at the magnification a sensitive measurement reaches: the wall does not move at all while the field rises, then jumps, then stops again. The largest jump in the window covers 0.67 units of wall position in no field change at all. There is nothing smooth underneath this — the smooth curve on the left is a staircase with 1400 steps in it, drawn small.

The curve that is really a staircase

A magnetisation curve is drawn as a smooth line and is nothing of the sort. Measured finely enough it is a sequence of jumps of every size, audible as a crackle in a coil, with no typical jump and no smooth motion underneath.

electromagnetism · Magnetisation
Two states at zero that only one side of the chain has. Every energy level of a chain of 20 cells, 40 sites, whose couplings alternate between v inside a cell and w = 1 between cells, against the ratio v/w from 0 to 2. The bulk levels fill two bands, bounded by the dashed lines ±|v − w| and ±(v + w), with a gap between them that closes at v = w. For v < w two levels sit at zero energy, in the middle of the gap, drawn in the warning colour: at v/w = 0.5 they are within a millionth of the coupling of zero. For v > w the gap is empty — at v/w = 1.5 the nearest level to zero is 0.527. Nothing about the chain's middle distinguishes the two sides of v = w; the difference is at its ends.

The end that knows how the middle was cut

A chain whose links alternate, strong and weak, has the same bands whichever kind of link is counted as inside a cell. The infinite chain cannot tell the two choices apart. A finite chain can: cut it so that a weak link is outermost and each end holds a state at exactly zero energy, in the middle of the gap; cut it the other way and it holds none. What decides is not anything at the ends but a whole number counted from the bulk — how many times a loop winds round a point.

waves · Periodic media
Two energies with opposite slopes, and the width between them. The energy per unit area of a domain wall in iron, against the width the wall is assumed to have, split into the two terms that decide it. The exchange term falls as one over the width, because a reversal spread over more atoms turns through a smaller angle between each neighbouring pair. The anisotropy term rises in proportion to the width, because every atom inside the wall points away from an easy direction and pays for it. The sum has a least value, found here by scanning four hundred thousand widths: 92.9 nanometres and 4.46 millijoules per square metre. Neither constant is a dimension of the sample, so neither is the width: it is the first length in magnetism that belongs to the material. The assumed profile turns at a uniform rate, which is not the cheapest way to turn, so this width is 41 per cent above the conventional πδ of the exact profile, and this energy 11 per cent above the exact 4√(AK). A trial function can only ever overestimate, and eleven per cent is how much this one costs.

The first length that belongs to the substance

Every length in magnetism so far has been a length of the sample — a demagnetising factor is a shape, an avalanche cutoff is a sample's own restoring field. A domain wall's width is not. It is √(A/K), made of two material constants and nothing else, and across seven ordinary magnets it runs from two and a half nanometres to nine hundred.

electromagnetism · Magnetisation
The tilt that starts the reversal, in a well of soft crystal. A planar defect three wall parameters wide (three times √(A/K)) in which the crystal's anisotropy falls to zero, drawn as the anisotropy K(x) across it; the curve is the shape of the first tilt of the magnetisation to become unstable as a reverse field is raised, the lowest mode of −A d²/dx² + K(x), and the dashed line is its eigenvalue. The equation is Schrödinger's, with the exchange stiffness A in place of ħ²/2m and the anisotropy as the potential, and the reversal begins in its ground state. Here the ground state lies at 0.373 K, so the magnet reverses at 37 per cent of the anisotropy field. The mode reaches out of the well a distance of about √(A/K) on each side, because exchange will not let the tilt change abruptly.

The magnet that reverses where its crystal is weakest

A perfect crystal of neodymium-iron-boron should hold its magnetisation against a reverse field of 7.7 tesla. The best magnets made of it give way at one to three. The shortfall, known for eighty years as Brown's paradox, is not a failure of the crystal but of its edges: reversal begins wherever the crystal is weakest, in a layer a few nanometres thick. Working out how weak that layer can afford to be turns out to be a problem already solved in quantum mechanics — the nucleation field is the ground-state energy of a particle in a well shaped like the defect.

electromagnetism · Magnetisation
Flux leaving a plate in stripes and spreading into a uniform field. A cross-section through a superconducting plate in the intermediate state near its top surface (below the line), with a normal fraction of 0.40: normal laminae (shaded) each carry the critical field straight up, the superconducting laminae between them carry none. Lengths are in units of the period of the pattern. Above the surface the field lines (solid) are computed from the stray field of the stripes: they fan out from each normal lamina and close up over the superconducting ones, and within about a third of a period the field is uniform at 0.40 of the critical field — the applied field, which is all a distant observer measures. The fanning field stores energy, and it stores more the wider the stripes are, because a wider pattern's non-uniformity reaches further out. That is half of what sets the period.

The stripes a superconductor makes of a field

A superconductor expels a magnetic field, but only if the field it pushes aside stays below the critical field everywhere at its surface — and for anything but a long rod held along the field, the field it pushes aside piles up at its edges. A flat plate laid across a field cannot expel any of it. It splits instead into interleaved bands of normal metal carrying exactly the critical field and superconducting metal carrying none, in the proportion flux demands, and the bands have a definite width. Walls between the two cost energy and favour few, broad bands; the field fanning out of the surface favours many narrow ones. The compromise is the geometric mean of the plate's thickness and a microscopic length.

electromagnetism · Superconductivity

Named alongside it

The objects these essays reach for when they reach for this one.

CoercivityDemagnetising fieldExchange lengthHysteresisMagnetisationAnisotropyAvalancheBand gapBulk boundary correspondenceChiral symmetryCritical fieldDemagnetising factor

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