Concept

Constitutive law — where it appears

The relation a particular material supplies between stress and deformation, which the equations of motion do not contain and cannot supply. A Newtonian liquid's is stress proportional to rate; a Bingham paste's has a threshold below which the rate is zero, and that single difference produces a plug down the middle of every pipe it flows in.

Named by 4 essays across 2 fields — each of them below, with the objects they name alongside it.

Four answers to one push. Shear stress against shear rate for four fluids. The straight line through the origin is the Newtonian definition and is the only one of the four for which the word viscosity names a number. The Bingham fluid does not move at all until the stress passes 0.4, which is why toothpaste holds a shape on a brush and why wet concrete can be stood in a heap.

The fluid that answers back

For water, stress is proportional to how fast it is sheared, and the constant of proportionality is its viscosity. For paint, blood, ketchup and cornflour in water, it is not — and once the proportionality goes, so does the idea that viscosity is a number a substance has.

fluids · Rheology
The thickness a paste can hold on a slope. The greatest thickness a yield-stress fluid can rest at without flowing, against the angle of the surface it is resting on, on a logarithmic vertical axis, for four materials. A layer of thickness h puts a shear stress ρgh sin α on its own base; it stays put while that is below the yield stress and flows when it is not, so the critical thickness is τ_y divided by ρg sin α and it depends on nothing else — not on the viscosity, not on how long it is left, not on how it was put there. On a vertical wall the numbers are 1.4 mm of ketchup, 9.2 mm of mayonnaise, 15.7 mm of toothpaste, 15.1 mm of basaltic lava, which is why toothpaste stays on a brush and ketchup does not stay on a plate held up. Read the other way it is a measurement: a lava flow that came to rest 3 centimetres thick on a 30° slope had a yield stress of about 400 pascals, and that is how the rheology of a flow nobody was standing next to is recovered from its shape a thousand years later. The model stops where the layer is thin enough for surface tension to matter and where the material's yield stress depends on how long it has been left alone, which for most of these it does.

The paste that holds up its own hill

Toothpaste stands on a brush and ketchup does not stand on a plate, and the difference is a single number with the units of a pressure. Below it a material does not flow slowly — it does not flow. That threshold turns a rheological property into a length, and the length is why a lava flow's thickness says what the lava was made of.

fluids · Rheology
The same liquid climbs a thin rod and is thrown off a thick one. The height of the free surface against distance from the axis, for rods of 10.0, 25.0, 60.0 millimetres radius turning at one revolution a second in the same polymer solution, with the Newtonian answer dashed. Two effects compete and they fall off at different rates: a hoop tension along the curved streamlines pulls the fluid inward and lifts it, falling as the fourth power of the distance, while the centrifugal term pushes it outward and lowers it, falling as the second. Near a thin rod the fourth power wins and the liquid climbs — 2.21 millimetres at the thinnest. Beyond a radius of 34.64 millimetres it does not, and the same fluid at the same speed is thrown outward exactly as water would be. The changeover is a property of the fluid and the rod together, so a demonstration that works on a glass stirring rod fails on a spoon handle.

The liquid that climbs the rod

Stir water with a rod and it is flung outward, leaving a dip at the centre. Stir a polymer solution and it climbs the rod instead. Nothing about the viscosity can produce that, however large it is made — what produces it is a second stress that appears in shear and has no Newtonian counterpart at all, growing as the square of the rate where the familiar one grows in proportion.

fluids · Rheology
Two fields of the same magnet, and inside they point opposite ways. A uniformly magnetised sphere, with the field lines of B on the left and of H on the right, both computed from the exact solution — uniform inside, a dipole outside. Outside the sphere the two pictures are identical up to a constant, because there B is μ₀ times H and nothing else. Inside they are opposite: B is 0.67 tesla pointing along the magnetisation and H is 267 kiloamps a metre pointing against it. The B lines close on themselves and never end; the H lines begin on the top face and end on the bottom, which is what a field with sources looks like. Nothing about the magnet changed between the two panels — only which currents the circulation is allowed to count.

The field that points against the magnet it is in

There are two magnetic fields in use and the difference between them is which currents a loop is allowed to count. The consequence nobody expects on being told the definitions: inside a permanent magnet H points the other way from B. It has to — a loop inside the magnet threads no wire, so its H circulation is zero, and the only arrangement left has H running backwards.

electromagnetism · Ampere law

Named alongside it

The objects these essays reach for when they reach for this one.

Shear stressViscoelasticityViscosityYield stressAmpere lawApparent viscosityBingham plasticBound chargeBoundary conditionsCreeping flowDemagnetising fieldDipole

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