Illustrated Physics
physics, drawn
Concept

Rheology — where it appears

The study of how materials deform and flow, covering everything between a solid that holds its shape and a liquid that does not. Its two axes are the rate a material is deformed at and the time over which it is watched, and a quoted viscosity is a measurement condition until both are stated.

Named by 6 essays across one field — each of them below, with the objects they name alongside it.

Four answers to one push. Shear stress against shear rate for four fluids. The straight line through the origin is the Newtonian definition and is the only one of the four for which the word viscosity names a number. The Bingham fluid does not move at all until the stress passes 0.4, which is why toothpaste holds a shape on a brush and why wet concrete can be stood in a heap.

The fluid that answers back

For water, stress is proportional to how fast it is sheared, and the constant of proportionality is its viscosity. For paint, blood, ketchup and cornflour in water, it is not — and once the proportionality goes, so does the idea that viscosity is a number a substance has.

fluids · Rheology Solid and liquid are answers about a duration. The relaxation time of seven materials, on a logarithmic axis spanning 39 decades, against the length of one observation. A material behaves as a solid when its relaxation time is longer than the observation and as a liquid when it is shorter, so the vertical line is what decides which — and it is a property of the observer. At 1 s, 4 of these are solids. Move the line six decades to the right and pitch joins the liquids; move it far enough left and water is a glass, which is not a figure of speech but what a picosecond pulse measures.

The liquid that remembers

Pitch shatters like glass under a hammer and flows through a funnel over a decade. Neither behaviour is the true one. What decides which a substance shows is not the substance but the length of the observation, and the ratio between the two has a name and a number.

fluids · Rheology The same paste stopping or running, according to the push. A thixotropic paste, sheared hard and then held under a constant stress: its viscosity against time, on a logarithmic axis, for stresses of 1.5, 1.8, 2.0, 2.4 Pa. Its structure builds at rest and is broken by flow, and the model's critical stress is 1.89 Pa. Below it the paste's viscosity climbs without limit: it slows, its structure builds faster than the slowing flow can break it, and it creeps to a stop, its viscosity growing in the end as the 1.5 power of time. Above it the viscosity falls: it speeds up, breaks its structure faster, and runs at a steady rate. After a thousand seconds the viscosities stand at 514.1, 238.3, 2.0, 1.5 Pa s: stresses a few per cent apart have gone opposite ways — a bifurcation, not a smooth change — and the paste hesitates longest when the stress is closest to the critical value.

The paste that forgets it was stirred

A jar of clay slurry left on a shelf sets like a jelly; shaken, it pours. That is thixotropy, and the tempting description — its viscosity falls when it is stirred — misses what makes it strange. A thixotropic paste has no viscosity at a given rate of stirring until it has been told how long it has been stirring, and under a steady push it cannot settle on a slow flow at all. Push slightly less than a critical stress and it creeps to a halt; push slightly more and it runs. Between the two there is nothing, and a paste made to flow slowly splits into a layer that flows and a layer that does not.

fluids · Rheology Blood's viscosity, measured in tubes of different sizes. The viscosity of blood at a haematocrit of 45 per cent, as a multiple of the plasma's, measured in glass tubes of each diameter (the fit of Pries and colleagues to many experiments), against the diameter on a logarithmic axis, with the two-layer model of a core inside a cell-free sleeve 2.5 μm thick, the core 4 times as viscous as plasma (dashed). In wide tubes blood is 3.20 times as viscous as plasma. From about half a millimetre down it gets steadily thinner, to 1.25 times at 6.8 μm — about the size of one red cell — and then climbs steeply, to 5.5 at 3 μm, where cells must fold to get through at all. Which viscosity blood has depends on the tube it is in.

The viscosity that belongs to the tube

Measure the viscosity of blood in a wide glass tube and it is about three times that of the plasma it is made from. Measure it in a tube a tenth of a millimetre across and it is lower; in one a hundredth of a millimetre across, lower still, barely more than plasma's. Then, below about six micrometres, it shoots up. The blood has not changed. The red cells push themselves away from the wall and leave a sleeve of plain plasma a few micrometres thick for the rest to slide in, and in a narrow tube that sleeve is a large part of the flow. A viscosity that depends on the pipe is no longer a property of the fluid alone.

fluids · Rheology A rod in a shear flow turns in fits and starts. The angle between a rigid rod's axis and the flow direction, unwrapped, against the strain of a steady shear flow (shear rate times time), for spheroids of aspect ratio 1, 5, 20 lying in the plane of the shear, each starting along the flow. A sphere (r = 1) turns steadily at half the shear rate. A rod spends most of its time nearly aligned with the flow, turning slowly, and then flips through half a turn quickly; at r = 5 it is within 10° of the flow direction 46 per cent of the time, at r = 20, 82 per cent. Each flip is half of Jeffery's period, π(r + 1/r) units of strain.

The rod that tumbles for ever in a stream

Drop a short rod into honey being sheared between two plates and it does not settle into line with the flow. It lies nearly along the stream for a long time, then flips end over end in a moment, then lies along it again, and it keeps doing that for as long as the shear lasts. George Jeffery worked out the motion in 1922: every orientation belongs to a closed orbit, every orbit takes the same time, and the flow has no way to choose between them — so a suspension of rods never reaches a steady state, and its thickness rises and falls in time with the tumbling.

fluids · Viscosity How a layer of grains moves down a slope. The velocity through a steady layer of 0.5 mm glass beads 20 grains deep flowing down slopes of 22°, 25° and 28°, against height above the rough base in grain diameters; the dashed curve is a Newtonian liquid's parabola, scaled to the 25° surface speed. Because every depth must have friction tan θ, every depth has the same inertial number, and the shear rate grows with the square root of the pressure above it: Bagnold's profile, u ∝ h^(3/2) − (h − z)^(3/2). Its surface speeds are 8.0, 41.0, 113.7 cm/s; compared with a liquid's parabola the shear is spread more evenly through the depth, because the shear rate falls off only as the square root of the depth below the surface rather than in proportion to it.

The sand whose friction depends on how fast it flows

A heap of sand stands at its angle of repose and starts to slide a few degrees steeper; between those angles there are steady avalanches, and their speed is decided by one number. The inertial number compares how long a grain takes to fall into a gap opened under it with how long the flow takes to open the gap. Friction rises with it, from the static value to a ceiling, and that single dependence explains why grains flow steadily on only a twelve-degree window of slopes, why a flowing layer has the velocity profile Bagnold measured, and why a deeper avalanche is faster — but not as a liquid would be.

fluids · Granular matter

Named alongside it

The objects these essays reach for when they reach for this one.

ViscosityYield stressSuspensionViscoelasticityApparent viscosityAspect ratioAvalancheBifurcationBloodConstitutive lawCreepDimensionless number

All concepts