Illustrated Physics
physics, drawn
Concept

Relaxation time — where it appears

The time a disturbed system takes to return most of the way to equilibrium, usually the time for a departure to fall by a factor of e. In a polymer solution it is the time a stretched chain takes to recoil, and comparing it with the time scale of the flow decides whether the liquid behaves elastically.

Named by 7 essays across 5 fields — each of them below, with the objects they name alongside it.

The same liquid climbs a thin rod and is thrown off a thick one. The height of the free surface against distance from the axis, for rods of 10.0, 25.0, 60.0 millimetres radius turning at one revolution a second in the same polymer solution, with the Newtonian answer dashed. Two effects compete and they fall off at different rates: a hoop tension along the curved streamlines pulls the fluid inward and lifts it, falling as the fourth power of the distance, while the centrifugal term pushes it outward and lowers it, falling as the second. Near a thin rod the fourth power wins and the liquid climbs — 2.21 millimetres at the thinnest. Beyond a radius of 34.64 millimetres it does not, and the same fluid at the same speed is thrown outward exactly as water would be. The changeover is a property of the fluid and the rod together, so a demonstration that works on a glass stirring rod fails on a spoon handle.

The liquid that climbs the rod

Stir water with a rod and it is flung outward, leaving a dip at the centre. Stir a polymer solution and it climbs the rod instead. Nothing about the viscosity can produce that, however large it is made — what produces it is a second stress that appears in shear and has no Newtonian counterpart at all, growing as the square of the rate where the familiar one grows in proportion.

fluids · Rheology Above a half, the chains stop letting go. The extensional viscosity of a dilute polymer solution, as a multiple of its zero-shear viscosity, against the accumulated stretch (Hencky strain, the stretch rate times the time), on a logarithmic axis, for stretch rates whose product with the relaxation time is 0.1, 0.4, 0.6, 1. The polymer carries 90 per cent of the viscosity. Dashed curves are the Oldroyd-B dumbbell, integrated from its conformation equation and matching its closed form; solid curves are the same chains with a finite length, FENE-P with L² = 400. At 0.1 the Oldroyd-B viscosity reaches 3.37 and the finite chain 3.37 by a strain of 6; at 0.4 the Oldroyd-B viscosity reaches 9.49 and the finite chain 9.25 by a strain of 6; at 0.6 the Oldroyd-B viscosity reaches 58 and the finite chain 49 by a strain of 6; at 1 the Oldroyd-B viscosity reaches 725 and the finite chain 329 by a strain of 6. Below one half the viscosity settles at a few times the shear value. Above it the Oldroyd-B chain stretches without limit and its resistance grows exponentially, while the finite chain grows until it is nearly fully extended and then stops, hundreds of times higher than it began.

The stretch a chain cannot outrun

A Newtonian liquid pulled into a thread resists exactly three times as hard as it resists being sheared, whatever it is made of. A polymer solution resists three times as hard only until the stretch rate passes one over twice its relaxation time. Past that, its chains can no longer recoil as fast as they are pulled apart, and the same liquid that is barely thicker than water in a stirred beaker becomes hundreds of times stiffer in a thread.

fluids · Rheology Three ships, three local times, one clock. The fair-weather field at sea level, in the same model, as recorded by ships at longitudes 120° W, 0°, 120° E, each plotting it against its own local solar time. An ordinary daily effect — sunshine, heating, turbulence — would peak at the same local time everywhere. This one peaks at 11.4, 19.4, 3.4 hours local time in turn, because every ship is reading the same global potential, which follows the world's storms and peaks at one moment in Universal Time. Seeing the maxima line up in Greenwich time rather than local time, over clean ocean air far from any storm, was how the global circuit was demonstrated: the field in fair weather is the far end of a circuit whose generators are thunderstorms thousands of kilometres away.

The field that keeps Greenwich time

Over a calm ocean, a thousand kilometres from any storm, the air carries a downward electric field of about a hundred volts per metre, and it rises and falls by a sixth once a day. It peaks at the same instant on every ship on every ocean — near seven in the evening in Greenwich, whatever the local clock says. Nothing local can do that. The field is the far end of a circuit whose upper plate is a single conductor round the whole planet, and a conductor has one potential, so every patch of fair-weather sky is reading the sum of all the world's thunderstorms at once.

electromagnetism · Potential Heat that arrives everywhere at once, and heat that waits. The temperature spread from a point of heat released at time zero, in one dimension, at times 0.5, 2, 8 relaxation times, from the diffusion equation (dashed) and from Cattaneo's telegraph equation (solid) with the same diffusivity, distances in units of the signal speed times the relaxation time. At 0.5, the diffusion equation has put 62 per cent of the heat beyond the reach of any signal; the telegraph equation none, and 78 per cent is still in the two fronts; at 2, the diffusion equation has put 32 per cent of the heat beyond the reach of any signal; the telegraph equation none, and 37 per cent is still in the two fronts; at 8, the diffusion equation has put 5 per cent of the heat beyond the reach of any signal; the telegraph equation none, and 1.8 per cent is still in the two fronts. The fronts, drawn as the vertical marks, carry heat outward at the signal speed and decay; behind them the telegraph solution fills in and, after many relaxation times, becomes the diffusion equation's Gaussian.

The heat that arrives before it could

Release a pulse of heat at one point, and the diffusion equation — the law that has described heat flow since Fourier — says the temperature rises everywhere at once, however far away. A thermometer a kilometre off registers a change the instant the heat is released. That is an infinite signal speed, and relativity forbids it. The flaw is harmless for a kettle and fatal for a relativistic fluid. The repair is a relaxation time: heat flow takes a moment to respond to a temperature gradient. With it the equation carries heat at a finite speed, sends a sharp front ahead of the spreading warmth, and turns short-wavelength heat into a damped wave.

relativity · Relativistic thermodynamics The pressure under a wheel rolling on a soft surface. The pressure under a rigid wheel of radius 30 cm carrying 3 kN per metre of width as it rolls over a rubber-like bed, against position along the contact (ahead of the axle to the right), scaled to the largest pressure and the widest contact, at three speeds. The bed relaxes with times of 2 and 20 ms. At 1 mm/s the pressure is symmetric and its resultant passes through the axle. At 1.0 m/s the material ahead is being squeezed faster than it can flow and pushes back harder than the recovering material behind, which lags and lets go early: the resultant sits 6.39 mm ahead of the axle. At 1000 m/s the bed has no time to relax at all and behaves as a stiffer elastic solid, symmetric again. A wheel is held back by where its support pushes, not by any sliding.

The push a millimetre ahead of the axle

A wheel rolling freely on a flat road slows down, and nothing in it slides. What holds it back is where the road pushes on it: not directly under the axle but a little ahead, because the material in front of the contact is being squeezed and pushes back harder than the material behind, which is recovering and lags. A car tyre's push is about three millimetres ahead of its axle, a train wheel's about two-thirds of a millimetre, and that offset, divided by the radius, is the whole of rolling resistance. It peaks at the speed where the time under the wheel matches the time the material takes to relax, and the same loss, at a different frequency, is what gives a tyre its grip.

mechanics · Friction The period of a ball bouncing on a gas. The period of a 16 mm steel ball (16.8 g) oscillating in a vertical tube that fits it on top of a flask, against the flask's volume on a logarithmic axis, for helium, air and carbon dioxide at room temperature, if every compression is adiabatic: T = 2π√(mV/γPA²). On a 10 litre flask the ball swings with a period of 0.983 s on helium, 1.072 s on air and 1.117 s on carbon dioxide. The gas is the spring, and its stiffness is γ times the pressure: the gas whose molecules have fewest ways to store energy is the stiffest, because less of the work done in compressing it goes into motions that do not push on the walls.

The ball that weighs how a gas stores heat

Drop a steel ball into a glass tube that fits it closely, on top of a flask of gas, and it does not fall to the bottom. It bounces, up and down, on the gas trapped beneath it, with a period of about a second. The gas is a spring, and its stiffness is the pressure multiplied by a number that counts how many ways the gas's molecules can hold energy. So a stopwatch on a bouncing ball measures something that otherwise needs a calorimeter: whether the molecules can rotate, whether they can vibrate, and how far a vibration has woken up at the temperature of the room.

thermodynamics · Equipartition Nine drops in eighty-four years. The time between successive drops of the pitch in Thomas Parnell's funnel, cut open in 1930, against the year each drop fell: 8.2, 7.2, 8.1, 8.3, 8.7, 9.3, 12.4, 13.4 years. The first seven intervals average 8.3 years and scatter by about a year either way; after the building was air-conditioned in the late 1980s the next two took 12.4 and 13.4, averaging 12.9. Read as a viscometer through the funnel's geometry, the early rate gives a viscosity of about 2.3 × 10⁸ Pa·s — some two hundred billion times water's.

The drop that takes a decade

In 1927 a physics professor in Brisbane poured heated pitch into a sealed funnel, waited three years for it to settle, and cut the stem. Nine drops have fallen since. The record is a viscometer read about once a decade, and it gives the pitch a viscosity two hundred billion times water's. It also records the building's air-conditioning: after 1988 the drops slowed from eight years apart to thirteen, and a fall of a degree and a half in the average temperature is enough to explain it. The same reasoning, applied to medieval window panes, settles an old story without guessing what glass does at room temperature.

fluids · Viscosity

Named alongside it

The objects these essays reach for when they reach for this one.

ViscoelasticityHysteresisPolymer solutionWeissenberg numberActivation energyAdiabatic indexAdiabatic processArrheniusCapacitanceCausalityCoil stretch transitionConductivity

All concepts