Illustrated Physics
physics, drawn
Concept

Relaxation time — where it appears

The time a disturbed system takes to return most of the way to equilibrium, usually the time for a departure to fall by a factor of e. In a polymer solution it is the time a stretched chain takes to recoil, and comparing it with the time scale of the flow decides whether the liquid behaves elastically.

Named by 3 essays across 2 fields — each of them below, with the objects they name alongside it.

The same liquid climbs a thin rod and is thrown off a thick one. The height of the free surface against distance from the axis, for rods of 10.0, 25.0, 60.0 millimetres radius turning at one revolution a second in the same polymer solution, with the Newtonian answer dashed. Two effects compete and they fall off at different rates: a hoop tension along the curved streamlines pulls the fluid inward and lifts it, falling as the fourth power of the distance, while the centrifugal term pushes it outward and lowers it, falling as the second. Near a thin rod the fourth power wins and the liquid climbs — 2.21 millimetres at the thinnest. Beyond a radius of 34.64 millimetres it does not, and the same fluid at the same speed is thrown outward exactly as water would be. The changeover is a property of the fluid and the rod together, so a demonstration that works on a glass stirring rod fails on a spoon handle.

The liquid that climbs the rod

Stir water with a rod and it is flung outward, leaving a dip at the centre. Stir a polymer solution and it climbs the rod instead. Nothing about the viscosity can produce that, however large it is made — what produces it is a second stress that appears in shear and has no Newtonian counterpart at all, growing as the square of the rate where the familiar one grows in proportion.

fluids · Rheology Above a half, the chains stop letting go. The extensional viscosity of a dilute polymer solution, as a multiple of its zero-shear viscosity, against the accumulated stretch (Hencky strain, the stretch rate times the time), on a logarithmic axis, for stretch rates whose product with the relaxation time is 0.1, 0.4, 0.6, 1. The polymer carries 90 per cent of the viscosity. Dashed curves are the Oldroyd-B dumbbell, integrated from its conformation equation and matching its closed form; solid curves are the same chains with a finite length, FENE-P with L² = 400. At 0.1 the Oldroyd-B viscosity reaches 3.37 and the finite chain 3.37 by a strain of 6; at 0.4 the Oldroyd-B viscosity reaches 9.49 and the finite chain 9.25 by a strain of 6; at 0.6 the Oldroyd-B viscosity reaches 58 and the finite chain 49 by a strain of 6; at 1 the Oldroyd-B viscosity reaches 725 and the finite chain 329 by a strain of 6. Below one half the viscosity settles at a few times the shear value. Above it the Oldroyd-B chain stretches without limit and its resistance grows exponentially, while the finite chain grows until it is nearly fully extended and then stops, hundreds of times higher than it began.

The stretch a chain cannot outrun

A Newtonian liquid pulled into a thread resists exactly three times as hard as it resists being sheared, whatever it is made of. A polymer solution resists three times as hard only until the stretch rate passes one over twice its relaxation time. Past that, its chains can no longer recoil as fast as they are pulled apart, and the same liquid that is barely thicker than water in a stirred beaker becomes hundreds of times stiffer in a thread.

fluids · Rheology Three ships, three local times, one clock. The fair-weather field at sea level, in the same model, as recorded by ships at longitudes 120° W, 0°, 120° E, each plotting it against its own local solar time. An ordinary daily effect — sunshine, heating, turbulence — would peak at the same local time everywhere. This one peaks at 11.4, 19.4, 3.4 hours local time in turn, because every ship is reading the same global potential, which follows the world's storms and peaks at one moment in Universal Time. Seeing the maxima line up in Greenwich time rather than local time, over clean ocean air far from any storm, was how the global circuit was demonstrated: the field in fair weather is the far end of a circuit whose generators are thunderstorms thousands of kilometres away.

The field that keeps Greenwich time

Over a calm ocean, a thousand kilometres from any storm, the air carries a downward electric field of about a hundred volts per metre, and it rises and falls by a sixth once a day. It peaks at the same instant on every ship on every ocean — near seven in the evening in Greenwich, whatever the local clock says. Nothing local can do that. The field is the far end of a circuit whose upper plate is a single conductor round the whole planet, and a conductor has one potential, so every patch of fair-weather sky is reading the sum of all the world's thunderstorms at once.

electromagnetism · Potential

Named alongside it

The objects these essays reach for when they reach for this one.

Polymer solutionViscoelasticityWeissenberg numberCapacitanceCoil stretch transitionConductivityConductorConstitutive lawCreeping flowDumbbell modelElectric potentialEquipotential

All concepts