Concept

Rayleigh scattering — where it appears

Scattering by particles much smaller than the wavelength, going as the inverse fourth power of it, and the reason the sky is blue. The same fourth power reddens a sunset, since what is scattered out of a long path is what is missing from the light that arrives.

Named by 6 essays across 2 fields — each of them below, with the objects they name alongside it.

How much each colour is scattered. Scattering strength against wavelength, as the inverse fourth power, normalised to one at 550 nanometres. Light at 450 nanometres is scattered 4.35 times as strongly as light at 650 nanometres — which is the whole reason the sky is the colour it is.

Why the sky is blue and the sunset is not, from one exponent

Scattering goes as the inverse fourth power of wavelength, and that single number produces a blue sky and a red sun without any second explanation. The two facts look opposite and are the same arithmetic.

optics · Scattering
Where the sky's blue goes. How many times more strongly a sphere scatters 450 nm light than 650 nm light, against its radius, with the radius on a logarithmic axis running from a couple of nanometres to twenty micrometres. On the left the ratio sits at 4.35, which is the fourth power of the wavelength ratio and the whole reason the daytime sky is blue. It does not stay there. By a radius of 245 nm the preference has halved, and by a micrometre it has essentially gone: a particle comparable with the wavelength scatters every visible colour within a few per cent of equally, which is why a cloud is white, why fog is white, why milk is white and why the exhaust of a cold diesel is white while the smoke of a cigarette — whose particles are ten times smaller — is blue. Nothing about the material changed between one end of this axis and the other; only the size did.

When the particle is the size of the wave

The sky is blue because small things scatter short wavelengths far more strongly. A cloud is made of the same water and scatters every colour alike. Nothing about the material changed — only the size, and one dimensionless number crossing one.

optics · Scattering
The blow-out band has two edges, not one. The ratio of radiation force to gravity against grain radius, with the radiation-pressure efficiency included: a grain much smaller than the wavelength of the light barely interacts with it — the efficiency falls as the fourth power of the size, which is Rayleigh's law — so the ratio stops rising and turns over. The dashed line is the same ratio with the efficiency taken as one, which is the usual drawing and is right only to the right of the turnover at 115 nm. The consequence is that a grain can be too small to be blown out as well as too large. Taking the threshold at a half — the value at which a grain released from a circular orbit is unbound — the band runs from 48.2 nm to 574 nm, and the largest ratio any grain of this material reaches is 1.87. Everything outside that band stays, and what stays does not stay put: it spirals.

The size the light cannot blow away

Radiation pressure and gravity both fall as the inverse square of distance, so their ratio is a property of the grain and not of where it is. What follows is a band of sizes that get blown out — with a lower edge as well as an upper one — and a drag, on everything else, that is the same pressure read one order further in v/c.

astrophysics · Radiation pressure
N when the phases are random, N² when they are not. Scattered intensity against the number of scatterers, both logarithmic, for two ways of adding the same amplitudes. The lower curve averages 400 draws of N unit amplitudes with independent random phases and grows as N^1.000; the upper one adds them in phase and grows as N². At 3000 scatterers the two differ by a factor of 2921. Nothing about the scatterers is different between the two — same number, same strength, same wavelength. Only the arrangement is, and it is worth three decades here.

Why a litre of water is not blue for the reason the sky is

The same molecules that make the sky blue also make the refractive index of air, and the two numbers agree because the sideways sum has random phases and the forward one does not. Condense those molecules into a liquid and the sideways sum collapses by a factor of sixteen — and what is left is thirty-four times smaller than the absorption that actually colours the water.

optics · Scattering
A force that points across the beam, not along it. The intensity of a beam focused to a waist of 0.5 µm, and the force it exerts on a 60 nm polystyrene sphere in water, across the beam. The force is not a pressure and does not point along the light: it is the pull on an induced dipole sitting in a non-uniform field, proportional to the gradient of the intensity rather than to the intensity, and it points up the gradient — towards the bright axis from either side. It vanishes exactly on the axis, which is what makes the axis a trap rather than a place. The well is 47 times kT deep at 100 milliwatts, which is why the particle stays: thermal motion explores it and does not escape it. The stiffness near the bottom is 3.070 piconewtons per micrometre, and a particle in a spring that stiff wanders 36 nanometres from centre.

The light that pulls rather than pushes

Radiation pressure is momentum arriving, and it points along the beam. A gradient of intensity does something else entirely — it polarises a particle and then pulls the induced dipole up the gradient — so a focused beam holds a particle at its waist against the push, and the force that does it is not a pressure at all.

astrophysics · Radiation pressure
The pattern the whole sky is written in. The sky as a disc — zenith at the centre, horizon at the rim, equal angles at equal distances — with the sun 30° above the horizon. Each short line is the direction the electric field vibrates in at that point, and its length and darkness are how polarised the light there is. The directions are perpendicular to the plane containing the sun, the observer and the point, which puts them tangent to circles centred on the sun. The heavy arc is the locus 90° from the sun, where the polarisation is strongest — 74 per cent here — and it is a great circle rather than a patch: a band across the sky, not a region near the horizon. This is what a polarising filter on a camera acts on, and it is why turning one darkens a band of sky and leaves the rest almost untouched, and why the effect is strongest when the sun is off to one side and absent when it is behind the photographer.

The pattern the sky is written in

Scattered sunlight is polarised, so the whole sky carries a direction of vibration at every point — arranged in circles about the sun, strongest on the great circle ninety degrees away from it, and vanishing at points that were found by looking before anyone could explain them. Bees navigate by it and a camera filter reads one band of it.

optics · Polarisation

Named alongside it

The objects these essays reach for when they reach for this one.

PolarisationScatteringDipole radiationMultiple scatteringPolarisabilityRadiation pressureRefractive indexAberrationAbsorptionAsymmetry parameterAtmosphereBrownian motion

All concepts