Concept

Polarisability — where it appears

How large a dipole moment an applied field induces in an object, per unit field. It decides the force a non-uniform field exerts — proportional to the polarisability times the gradient of the intensity — and its sign relative to the surrounding medium decides whether the object is pulled in or pushed out.

Named by 5 essays across 3 fields — each of them below, with the objects they name alongside it.

N when the phases are random, N² when they are not. Scattered intensity against the number of scatterers, both logarithmic, for two ways of adding the same amplitudes. The lower curve averages 400 draws of N unit amplitudes with independent random phases and grows as N^1.000; the upper one adds them in phase and grows as N². At 3000 scatterers the two differ by a factor of 2921. Nothing about the scatterers is different between the two — same number, same strength, same wavelength. Only the arrangement is, and it is worth three decades here.

Why a litre of water is not blue for the reason the sky is

The same molecules that make the sky blue also make the refractive index of air, and the two numbers agree because the sideways sum has random phases and the forward one does not. Condense those molecules into a liquid and the sideways sum collapses by a factor of sixteen — and what is left is thirty-four times smaller than the absorption that actually colours the water.

optics · Scattering
A force that points across the beam, not along it. The intensity of a beam focused to a waist of 0.5 µm, and the force it exerts on a 60 nm polystyrene sphere in water, across the beam. The force is not a pressure and does not point along the light: it is the pull on an induced dipole sitting in a non-uniform field, proportional to the gradient of the intensity rather than to the intensity, and it points up the gradient — towards the bright axis from either side. It vanishes exactly on the axis, which is what makes the axis a trap rather than a place. The well is 47 times kT deep at 100 milliwatts, which is why the particle stays: thermal motion explores it and does not escape it. The stiffness near the bottom is 3.070 piconewtons per micrometre, and a particle in a spring that stiff wanders 36 nanometres from centre.

The light that pulls rather than pushes

Radiation pressure is momentum arriving, and it points along the beam. A gradient of intensity does something else entirely — it polarises a particle and then pulls the induced dipole up the gradient — so a focused beam holds a particle at its waist against the push, and the force that does it is not a pressure at all.

astrophysics · Radiation pressure
Why only a sideways scattered wave takes anything away. The transmitted amplitude behind a thin scatterer, drawn as a phasor: the incident wave of unit length along the axis, plus a forward-scattered wave of length 0.12 at 0°, 60°, 90°, 150°. What a detector reads is the square of the total length. A scattered wave along the incident one lengthens or shortens the sum in proportion to itself; one at right angles changes the length only in second order, because a small perpendicular addition to a long vector barely alters its length. So a scatterer that removes energy from the beam at first order must scatter forward with a component perpendicular to the incident wave, and the size of that component is the whole extinction — which is the optical theorem.

Everything a scatterer removes, from one direction

How much light a particle takes out of a beam — by scattering it anywhere at all, and by absorbing it — is fixed entirely by what it does in the forward direction, where its scattered wave cannot be told apart from the incident one. The mechanism is interference, and it also gives the refractive index.

optics · Scattering
A living cell and a dead one, told apart by a frequency. The real part of the dielectrophoretic factor for a living cell and a dead one, ten micrometres across, in a liquid of conductivity 0.01 S/m, against frequency. The cell is a conducting interior inside a membrane five nanometres thick. The living cell's intact membrane blocks slow fields, so at low frequency it behaves as an insulator and is pushed out of strong field; above 42 kHz the membrane is short-circuited by its own capacitance and the conducting interior is felt, so the cell is pulled in; above 140 MHz the permittivities take over and it is pushed again. The dead cell's membrane leaks, its interior has lost ions, and it changes sign only at 8.8 MHz. In 2 bands — below 42 kHz and from 8.9 MHz to 140 MHz — the same field pushes the two in opposite directions.

The force whose sign a frequency chooses

A neutral particle in a non-uniform field is pulled towards strong field if it polarises more than the liquid around it and pushed away if it polarises less. With conduction in the picture, which of the two it does is decided by how fast the field alternates — and a living cell, a conductor wrapped in an insulator five nanometres thick, changes sign twice, where a dead one changes once. The same electrodes can then send the living cells one way and the dead ones the other.

electromagnetism · Dielectrics
London's attraction, and the distance where it gives out. The dispersion energy between two identical atoms times the sixth power of their separation, relative to London's constant, against the separation in units of c/ω₀ — the reduced wavelength of each atom's strongest transition — on logarithmic axes, from the Casimir–Polder integral with a one-resonance polarisability. Close in, the product is one: London's inverse sixth power. It has fallen to a half by 3.82 c/ω₀, and far out it falls as one over the distance, so the energy goes as the inverse seventh power, reaching 23.2 per cent of London's value at ten reduced wavelengths and 2.44 per cent at a hundred. For two helium atoms, whose strongest line is at 58 nm, c/ω₀ is about 9 nm; for two sodium atoms, 94 nm.

The attraction that weakens when light is too slow

Two neutral atoms attract because each one's fluctuating electrons polarise the other, and the two fluctuations fall into step. London's calculation of the force, as the inverse sixth power of the distance, assumes the field from one atom reaches the other instantly. It does not. Beyond a distance set by the wavelength of the atoms' own strongest transition — nine nanometres for helium, about a hundred for sodium — the field returns too late to find the fluctuation that made it. The attraction then falls one power faster. Casimir and Polder worked this out in 1948, and it was the starting point for the Casimir force between plates.

electromagnetism · Retardation

Named alongside it

The objects these essays reach for when they reach for this one.

AbsorptionBrownian motionDipoleFluctuationsRayleigh scatteringRefractive indexScatteringSuperpositionAttenuationCalibrationCasimir polderCoherence

All concepts