Concept

Attenuation — where it appears

The exponential weakening of a wave as a medium removes a fixed fraction of it per unit distance, whether by absorption or by scattering. The distance for a fall by a factor of e is the reciprocal of the number density times the cross-section, so it is the same arithmetic as a mean free path.

Named by 10 essays across 4 fields — each of them below, with the objects they name alongside it.

The same law, across twenty-eight decades. The mean free path 1/nσ against cross-section, for a target density of 6.83·10³⁰ targets per cubic metre — solid lead. It is a straight line of slope minus one, because there is only one thing in the law. At 10⁻²⁸ m² the path is 1.46 mm; at 10⁻⁴⁷ m² the path is 1.55 light-years. Nothing about the physics changes between those ends. Only the area does.

How far a neutrino gets

A mean free path is one over the number density times the cross-section, and nothing else. Change only the cross-section — by twenty-eight powers of ten — and the same arithmetic that gives a molecule seventy nanometres in air gives a neutrino a light-year of solid lead.

astrophysics · Kinetic theory
Three geometries, three exponents. Amplitude against distance for a wave spreading in one, two and three dimensions, on logarithmic axes, over 3 decades. The same power crosses every surface round the source, so the intensity falls as one over the area of that surface and the amplitude as one over its square root. The fitted slopes are 0.000 along a line, -0.500 over a cylinder, -1.000 over a sphere, each fitted by least squares to the drawn curve rather than written on it. A ripple on water is the middle case and a sound in a room is the last, which is why a ripple stays visible so much further than a shout carries.

How a wave thins out

A wave gets weaker with distance for two quite different reasons, and only one of them is a loss. Geometry alone fixes the first exactly — three exponents for three dimensions, with nothing about the medium in them — and whatever is left over is the medium eating the wave.

waves · Wave motion
An f² law that is right in shape and out by 30× in size. Two absorption curves for air against frequency, both logarithmic, in decibels per kilometre. The lower one is the classical Stokes–Kirchhoff result computed from air's viscosity and thermal conductivity alone, and it goes as f^2.000 — exactly two, because the loss per cycle is fixed and the number of cycles per metre is proportional to the frequency. The upper one is the measured atmospheric absorption at 20 °C and 50 per cent humidity, which fits f^1.42 and is 30 times larger at 1 kHz and 211 times at 125 Hz. The excess is not a correction to viscosity: it is nitrogen and oxygen storing energy in vibration and giving it back late, at a rate the water vapour sets, and it is the mechanism that actually removes the treble from a distant sound.

The distance that takes the treble out

Spreading treats every frequency alike; absorption does not. The loss per cycle is roughly fixed and the number of cycles per metre goes as the frequency, so absorption climbs as f² and a sound gets duller with distance as well as quieter — which is the whole account of why a nearby thunderclap cracks and a distant one rumbles.

waves · Attenuation
The year, arriving underground at four different times. Temperature against depth in soil of diffusivity 0.5 mm²/s, at four times of year, measured from the annual mean. The surface swings by ±12 K; the swing underground is smaller and later, and both are governed by one length, δ = √(2D/ω) = 2.24 m. The amplitude falls as e^(−z/δ) — the dashed envelope — and the phase lags by z/δ radians, so the curves lean over as they go down and cross the axis at different depths. At 7.0 m the lag is half a year: the ground there is at its coldest in August and its warmest in February, in antiphase with the sky, with a swing of 0.52 K left. That is a cellar, and it is also why a water main below about a metre and a half does not know that it froze last week.

The summer that reaches the cellar in December

Drive the diffusion equation at its boundary instead of releasing something into it and the solution is a decaying, lagging oscillation with a single length in it. That length governs both the shrinking and the delay, which is why the depth at which the ground is coldest in August is fixed by the same number as the depth at which the seasons stop being felt at all.

thermodynamics · Diffusion
Why only a sideways scattered wave takes anything away. The transmitted amplitude behind a thin scatterer, drawn as a phasor: the incident wave of unit length along the axis, plus a forward-scattered wave of length 0.12 at 0°, 60°, 90°, 150°. What a detector reads is the square of the total length. A scattered wave along the incident one lengthens or shortens the sum in proportion to itself; one at right angles changes the length only in second order, because a small perpendicular addition to a long vector barely alters its length. So a scatterer that removes energy from the beam at first order must scatter forward with a component perpendicular to the incident wave, and the size of that component is the whole extinction — which is the optical theorem.

Everything a scatterer removes, from one direction

How much light a particle takes out of a beam — by scattering it anywhere at all, and by absorbing it — is fixed entirely by what it does in the forward direction, where its scattered wave cannot be told apart from the incident one. The mechanism is interference, and it also gives the refractive index.

optics · Scattering
A bend of 5 mm, and where the field has to give up. The transverse profile of the guided mode, with the core shaded and the radius at which a bend of 5 millimetres would require the field to outrun the cladding marked. Inside the core the field is a cosine; outside it decays, and the decay is what keeps the mode together. Bending the guide imposes a rigid rotation, so the field a distance x from the axis must travel faster in proportion to x — and past 13.5 micrometres it would have to travel faster than the cladding permits. There the field can no longer be evanescent, and what is there radiates away. The amount there is 1.63e-2 of the peak, which is why the loss is negligible until the caustic moves in, and then is not.

The mode that will not turn a corner

Bend a waveguide and the field has to go round with it, which means the part furthest from the centre has to travel faster. Past a certain distance it would have to travel faster than the surrounding medium allows, and everything out there radiates away — which is why bend loss is exponential in the radius and arrives all at once.

waves · Guided waves
A beam of sound has a weight. The force a fully absorbed acoustic beam exerts, against its power, for 3 media. It is the power divided by the speed of sound and nothing else — a watt in water gives 675 micronewtons, which is the weight of 68 milligrams, and a watt in air gives 2.9 millinewtons because the sound is slower there. This is not an analogy with light: it is the same statement, that a wave carrying energy carries momentum, with a much smaller speed in the denominator. The consequence is that acoustic power is measured by weighing. A radiation-force balance — an absorbing target on a laboratory balance, with the transducer beneath it — is the primary standard for ultrasonic output, and every therapeutic and diagnostic transducer is calibrated against one.

Where the loudness goes

An absorption coefficient removes energy from a wave, and energy removed has to appear somewhere. It appears twice, from the same coefficient: as heat, and as momentum. So a beam of sound has a weight — a watt absorbed in water weighs sixty-eight milligrams — and acoustic power is measured by putting an absorber on a balance. The ratio of the force to the heating contains no intensity at all.

waves · Attenuation
An absorption that goes up when the photon gets harder. Mass attenuation coefficients for 4 materials against photon energy, both logarithmic, from tabulated measurements interpolated between. Away from a threshold every curve falls steeply — a harder photon is less easily absorbed, which is what makes X-rays penetrating. At a K edge the curve jumps upward: the photon has become able to eject an innermost electron, a whole new population becomes available, and the absorption multiplies by 4.4 for iodine at 33.17 keV and 4.0 for lead at 88 keV. That is a discontinuity in a material property as a function of frequency, and nothing in the classical description of absorption produces one. It exists because absorption at these energies is a transition of a bound electron rather than a loss in a medium.

The steps in an absorption curve

Every absorption law up to this point is smooth — a fixed loss per cycle, a relaxation, a power of frequency. Take the photon energy up to where it can eject an electron from an atom and the curve acquires steps, and they go the wrong way: the material becomes suddenly more opaque to a harder photon. Iodine absorbs four times as strongly at 33.4 keV as at 33.0, and that discontinuity is why it is injected into people.

waves · Attenuation
The ripple that sits on top of an absorption edge. The Cu K absorption of copper foil, 293 K through its edge and for seven hundred electronvolts above it, with the smooth atomic background it would have if the absorbing atom were alone drawn beneath it. The difference between the two is the fine structure: a modulation reaching 11 per cent, dying away as the photon energy rises, and entirely absent from a free atom. It is there because the ejected electron is a wave that the neighbouring atoms scatter back onto the atom that emitted it, so the absorption depends on whether the returning wave arrives in step with the outgoing one — which depends on the distance to the neighbour and on nothing else about the sample.

The ripple that counts the neighbours

An absorption edge is drawn as a step and it is a step with a ripple on it — a modulation of eleven per cent in copper, five in a zinc site buried in a protein. The ripple is the ejected electron's own wave, scattered back onto the atom that emitted it, so its period is a distance. It is the only way of measuring where an atom's neighbours are that does not need a crystal.

waves · Attenuation
The edge that is a straight line, not a step. The absorption of gallium arsenide near its own band gap of 1.424 electronvolts, on a logarithmic axis, at 4 temperatures. Below the gap the absorption does not stop; it falls exponentially, along a straight line whose slope is an energy, and the straightness holds over several decades. Raising the temperature makes the line shallower — the tail reaches further below the gap — and the slope runs from 5.6 millielectronvolts at 10 kelvin to 7.5 at 300, a factor of 1.33. The lines pivot about a point just above the gap rather than rotating about nothing, which is what makes the slope a single number worth quoting. The band gap's own shift with temperature has been removed here, so that the fan is the tail's doing and not the gap's.

Below the gap, where there is nothing to absorb

A semiconductor is supposed to be transparent below its band gap, and it is not. The absorption falls exponentially instead, over seven decades, along a straight line whose slope is an energy of a few millielectronvolts — and the description that produces that line has no states in the gap at all. What the slope measures is how much the gap itself is moving about.

waves · Attenuation

Named alongside it

The objects these essays reach for when they reach for this one.

AbsorptionCross-sectionIntensityTransportBinding energyDissipationInterferenceMean free pathSpectrumThermal energyThresholdViscosity

All concepts