Illustrated Physics
physics, drawn
Concept

Binding energy — where it appears

The energy that must be supplied to take a bound system apart, and therefore the amount by which the whole weighs less than its parts. Helium-4 is 28.3 MeV lighter than two protons and two neutrons, which is seven parts in a thousand of its own mass.

Named by 6 essays across 4 fields — each of them below, with the objects they name alongside it.

The curve that makes both fusion and fission release energy. Binding energy per nucleon against mass number: how much energy would have to be supplied, per particle, to take a nucleus apart into free protons and neutrons. The curve is the semi-empirical mass formula, evaluated at whichever proton number binds most tightly for each mass number rather than at a guessed one; the points are measured values. It rises steeply at the light end, peaks at mass number 58, and falls slowly thereafter. Everything about nuclear energy follows from that shape and from nothing else. Two light nuclei joined move up the curve and release the difference; one heavy nucleus split moves up it too, from the other side. Both directions are downhill in energy because the peak is in the middle, and the peak is in the middle because two effects fight — the surface term, which penalises small nuclei for having most of their nucleons on the outside, and the Coulomb term, which penalises large ones because every proton repels every other. The energy released is the height climbed times the number of nucleons carried, and it is a million times a chemical bond for the same reason the vertical axis is in millions of electronvolts rather than in single ones.

The mass that is missing

A helium nucleus weighs less than the two protons and two neutrons it is made of. The shortfall is not an error in the weighing; it is the binding energy, converted at the going rate. One curve of that shortfall against size explains why both fusion and fission release energy.

relativity · Mass-energy The mass of two things that have none. The invariant mass of a pair of photons of equal energy, in units of E/c², against the angle between them. It is computed from the total energy and the vector sum of the two momenta, and agrees with 2E·sin(θ/2) to 1.0e-14. at 0° the pair weighs 0.000 E/c²; at 30° the pair weighs 0.518 E/c²; at 60° the pair weighs 1.000 E/c²; at 90° the pair weighs 1.414 E/c²; at 120° the pair weighs 1.732 E/c²; at 180° the pair weighs 2.000 E/c². Two photons flying in the same direction have no mass between them at all, because their momenta add to exactly the energy over c; anything else and they do. Nothing has been added: the constituents are massless at every angle, and the mass of the system is a property of the arrangement. At 180° the pair weighs 2E/c², which is every joule it contains — the case of a sealed box of light, where the two beams cancel in momentum and the whole energy shows up on the scales.

The box of light that weighs something

Two photons flying apart have a mass between them, though neither has one. Seal them in a mirrored box and the box is heavier than it was empty, by exactly the energy inside divided by c². Mass is not a property of stuff and it does not add up — it is a property of a system, and 99 per cent of the mass of everything anybody has ever weighed is of this kind.

relativity · Mass-energy Why it stops falling in. The energy of an electron confined to a region of radius r around a nucleus, as the sum of two terms with different powers: a confinement energy ħ²/2mr² that rises without limit as the region shrinks, and a Coulomb attraction −Ze²/4πε₀r that falls. At Z = 1 the sum is least at 52.92 pm, where it is -13.61 eV. Both numbers are found by searching the drawn curve and both agree with the Bohr radius over Z and minus Z² Rydbergs to a part in a million. Nothing was quantised to get them. The only quantum input is that confining an electron to a region costs kinetic energy, which is the uncertainty relation and nothing more.

Why an atom is the size it is

A tenth of a nanometre is not a measured constant of nature but the outcome of a competition: confining an electron costs kinetic energy, and the nucleus pays for confinement with attraction. Minimising the sum gives the number, and changing the masses moves it by four orders of magnitude.

quantum · Atomic structure An absorption that goes up when the photon gets harder. Mass attenuation coefficients for 4 materials against photon energy, both logarithmic, from tabulated measurements interpolated between. Away from a threshold every curve falls steeply — a harder photon is less easily absorbed, which is what makes X-rays penetrating. At a K edge the curve jumps upward: the photon has become able to eject an innermost electron, a whole new population becomes available, and the absorption multiplies by 4.4 for iodine at 33.17 keV and 4.0 for lead at 88 keV. That is a discontinuity in a material property as a function of frequency, and nothing in the classical description of absorption produces one. It exists because absorption at these energies is a transition of a bound electron rather than a loss in a medium.

The steps in an absorption curve

Every absorption law up to this point is smooth — a fixed loss per cycle, a relaxation, a power of frequency. Take the photon energy up to where it can eject an electron from an atom and the curve acquires steps, and they go the wrong way: the material becomes suddenly more opaque to a harder photon. Iodine absorbs four times as strongly at 33.4 keV as at 33.0, and that discontinuity is why it is injected into people.

waves · Attenuation The month a binding energy would bend. The Moon's orbit seen with the Sun held off to the right, drawn as it would be if the Earth's binding energy fell towards the Sun more weakly than the rest of it. The Earth is bound by 4.5 × 10⁻¹⁰ of its mass-energy and the Moon by 1.9 × 10⁻¹¹, so with the Sun pulling at 5.93 mm/s² the Moon is pushed sunward relative to the Earth by 2.6 × 10⁻¹² m/s² for every unit of η. That push turns once a synodic month relative to the orbit, 29.53 days, and Hill's equations about a circular orbit — integrated from the forced solution and held on it to 4 × 10⁻¹¹ over twelve months — give a radial displacement of 8.0 m times η times the cosine of the lunar phase: outward at new moon, inward at full. The complete lunar theory, with the Sun's tide on the orbit included, gives 13.1 m. The displacement is drawn about 7 × 10⁶ times larger than it would be at η = 1.

The binding energy that has to fall too

Every laboratory test of the equivalence principle compares bodies whose own gravity is a part in 10²⁵ of their mass, so none of them can ask whether gravitational binding energy falls like everything else. The Earth is bound by five parts in ten billion and the Moon by twenty times less, and if that difference fell differently the Moon's orbit would lean towards the Sun once a month — by a distance lasers have been measuring since 1969.

astrophysics · Equivalence principle The ripple that sits on top of an absorption edge. The Cu K absorption of copper foil, 293 K through its edge and for seven hundred electronvolts above it, with the smooth atomic background it would have if the absorbing atom were alone drawn beneath it. The difference between the two is the fine structure: a modulation reaching 11 per cent, dying away as the photon energy rises, and entirely absent from a free atom. It is there because the ejected electron is a wave that the neighbouring atoms scatter back onto the atom that emitted it, so the absorption depends on whether the returning wave arrives in step with the outgoing one — which depends on the distance to the neighbour and on nothing else about the sample.

The ripple that counts the neighbours

An absorption edge is drawn as a step and it is a step with a ripple on it — a modulation of eleven per cent in copper, five in a zinc site buried in a protein. The ripple is the ejected electron's own wave, scattered back onto the atom that emitted it, so its period is a distance. It is the only way of measuring where an atom's neighbours are that does not need a crystal.

waves · Attenuation

Named alongside it

The objects these essays reach for when they reach for this one.

AbsorptionAttenuationEquivalence principleScreeningX-raysActivation barrierAtomic structureBohr radiusConservationConservation of energyCoordination numberCoulomb force

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