Concept

X-rays — where it appears

Electromagnetic radiation of a few hundred to a few hundred thousand electronvolts, with wavelengths comparable to the spacing between atoms. That coincidence is why they diffract from crystals and why their absorption is a probe of an atom's innermost electrons.

Named by 5 essays across 4 fields — each of them below, with the objects they name alongside it.

An absorption that goes up when the photon gets harder. Mass attenuation coefficients for 4 materials against photon energy, both logarithmic, from tabulated measurements interpolated between. Away from a threshold every curve falls steeply — a harder photon is less easily absorbed, which is what makes X-rays penetrating. At a K edge the curve jumps upward: the photon has become able to eject an innermost electron, a whole new population becomes available, and the absorption multiplies by 4.4 for iodine at 33.17 keV and 4.0 for lead at 88 keV. That is a discontinuity in a material property as a function of frequency, and nothing in the classical description of absorption produces one. It exists because absorption at these energies is a transition of a bound electron rather than a loss in a medium.

The steps in an absorption curve

Every absorption law up to this point is smooth — a fixed loss per cycle, a relaxation, a power of frequency. Take the photon energy up to where it can eject an electron from an atom and the curve acquires steps, and they go the wrong way: the material becomes suddenly more opaque to a harder photon. Iodine absorbs four times as strongly at 33.4 keV as at 33.0, and that discontinuity is why it is injected into people.

waves · Attenuation

The ripple that sits on top of an absorption edge. The Cu K absorption of copper foil, 293 K through its edge and for seven hundred electronvolts above it, with the smooth atomic background it would have if the absorbing atom were alone drawn beneath it. The difference between the two is the fine structure: a modulation reaching 11 per cent, dying away as the photon energy rises, and entirely absent from a free atom. It is there because the ejected electron is a wave that the neighbouring atoms scatter back onto the atom that emitted it, so the absorption depends on whether the returning wave arrives in step with the outgoing one — which depends on the distance to the neighbour and on nothing else about the sample.

The ripple that counts the neighbours

An absorption edge is drawn as a step and it is a step with a ripple on it — a modulation of eleven per cent in copper, five in a zinc site buried in a protein. The ripple is the ejected electron's own wave, scattered back onto the atom that emitted it, so its period is a distance. It is the only way of measuring where an atom's neighbours are that does not need a crystal.

waves · Attenuation $A mirror for X-rays that works only at a glance. The fraction of 8 keV X-rays reflected by a smooth surface of gold and of silicon, against the grazing angle between the ray and the surface, in milliradians, with absorption included (solid) and without it (dashed). Below the critical angle √(2δ) — 10.02 mrad (0.57°) for gold, 3.88 mrad (0.22°) for silicon — the X-rays are totally reflected from outside the material, because its index is below the vacuum's; above it almost nothing is. Absorption rounds the edge and keeps the plateau a little below one. A mirror for X-rays is therefore a surface met at less than a degree, and it reflects well only while it is met that way.$

The index that falls below one

Glass bends light because light is slower in it. X-rays are not slower in glass, or in anything: every material's refractive index for them is slightly less than one, by a few parts in a million. Everything about X-ray optics follows from that small number with the wrong sign. A lens that focuses them must be thinner in the middle than at the edges, and so weak that dozens are stacked in a row. A mirror reflects them only if they arrive at a glancing angle of less than a degree — totally, from the outside, the reverse of the way a diamond traps light — which is why the mirrors of an X-ray telescope are long, nested barrels rather than dishes.

optics · Refraction

Two factors of γ between a magnet and an X-ray. An electron of 6 GeV (γ = 11742) crossing an undulator, a row of magnets alternating every λᵤ = 3 cm. Top: the laboratory, where the electron wiggles once per period. Middle: the electron's own frame, where the row is contracted by γ to 2.55 μm and rushes past at nearly the speed of light; to the electron it is a wave of that wavelength, and the electron radiates at it, in the infrared. Bottom: that light, emitted forward and seen back in the laboratory, is Doppler-shortened by a further factor of about 2γ, to λᵤ/2γ² = 1.088 Å; the wiggle's own slowing of the electron adds a factor (1 + K²/2), giving 1.632 Å for a deflection parameter K = 1 — hard X-rays from centimetre magnets. The drawing is schematic: the three periods differ by factors of about twelve thousand and a hundred million, and cannot be drawn to one scale.

The magnet period that comes out as an X-ray

A row of permanent magnets alternating every three centimetres, with a beam of six-gigaelectronvolt electrons sent down the middle, shines X-rays with a wavelength of an ångström and a half — two hundred million times shorter than the spacing of the magnets that made them. The factor is γ squared, and the two γ's come from two different frames. In the electron's frame the row of magnets is contracted by γ and rushes past it as a wave; the electron shakes in step and radiates; and that light, sent forward, comes back to the laboratory shortened by another factor of 2γ. Length contraction is half of every X-ray a modern synchrotron makes.

relativity · Length contraction

The square root of an X-ray's energy, one step per element. The square root of the energy of each element's Kα X-ray line, in units of the Rydberg energy, against its atomic number, for 24 elements from aluminium to lead (dots), with Moseley's law, √(3/4)·(Z − 1), drawn as a line. The points march up in equal steps, one per element, because each step adds one proton to the nucleus and one unit to the charge the falling electron feels. When Moseley first did this, in 1913–14, the line had gaps where no known element fell: the numbers marked, 43, 61, 72 and 75, were found later as technetium, promethium, hafnium and rhenium. At high atomic number the points rise above the line, by 6 per cent for lead, because the innermost electrons there move fast enough for relativity to deepen their binding.

The X-ray line that counts the protons

Strike a metal with fast electrons and it gives off X-rays at a few sharp energies characteristic of the metal. In 1913 Henry Moseley measured the strongest of them for element after element and found that the square root of its energy rose in equal steps, one step per element — as if something inside each atom were being counted. It was the charge on the nucleus. The periodic table had been ordered by weight; Moseley's line ordered it by protons, fixed the elements it was missing, and showed that an electron deep inside a heavy atom behaves like the electron in hydrogen, with the charge turned up.

quantum · Atomic spectra

Named alongside it

The objects these essays reach for when they reach for this one.

Absorption Attenuation Binding energy Screening Atomic number Bohr model Compound refractive lens Coordination number Critical angle Cross-section Debye waller factor Doppler effect

All concepts