Illustrated Physics
physics, drawn
Concept

Coordination number — where it appears

How many nearest neighbours an atom has, and at what distance. It is the first thing that distinguishes one structure from another, and it can be measured without a crystal at all from the oscillations above an absorption edge.

Named by 2 essays across 2 fields — each of them below, with the objects they name alongside it.

Where a heap stops flowing. The number of motions that cost nothing, against the mean number of contacts each grain has, for a patch of 37 grains. Every point is the rank of an actual rigidity matrix — one row per contact, one column per coordinate — subtracted from the number of coordinates, so it is a measurement of the network rather than a formula about it. The dashed line is Maxwell's count, two coordinates a grain minus half a contact each, which is what the counting alone predicts. The measured curve reaches its floor of three free motions — the rigid-body ones — at a coordination of 4.11, and Maxwell's line reaches zero at exactly four, which is twice the dimension of the plane. That is the isostatic point and the difference between the two numbers is the boundary of a finite patch, whose outer grains have fewer neighbours than they would in an infinite one. Above the threshold the two curves separate: the measured floor stays at three while the count keeps falling, and the gap is the redundancy — contacts whose forces no equilibrium equation can determine. Below it the pack has genuine mechanisms and will rearrange under any load at all. The transition is in the count and not in the material, which is why a fluid and a solid here are made of exactly the same grains.

The heap that becomes a solid

Sand poured into a jar flows; the same sand shaken down and pressed does not. Nothing about the grains has changed — not their size, their hardness, their friction or their density by more than a per cent — and the thing that changed is a count of contacts, which crosses a threshold set by the dimension of space and by nothing else.

fluids · Granular matter The ripple that sits on top of an absorption edge. The Cu K absorption of copper foil, 293 K through its edge and for seven hundred electronvolts above it, with the smooth atomic background it would have if the absorbing atom were alone drawn beneath it. The difference between the two is the fine structure: a modulation reaching 11 per cent, dying away as the photon energy rises, and entirely absent from a free atom. It is there because the ejected electron is a wave that the neighbouring atoms scatter back onto the atom that emitted it, so the absorption depends on whether the returning wave arrives in step with the outgoing one — which depends on the distance to the neighbour and on nothing else about the sample.

The ripple that counts the neighbours

An absorption edge is drawn as a step and it is a step with a ripple on it — a modulation of eleven per cent in copper, five in a zinc site buried in a protein. The ripple is the ejected electron's own wave, scattered back onto the atom that emitted it, so its period is a distance. It is the only way of measuring where an atom's neighbours are that does not need a crystal.

waves · Attenuation

Named alongside it

The objects these essays reach for when they reach for this one.

AbsorptionAttenuationBinding energyConstraint countingDebye waller factorDegrees of freedomForce-chainFourier transformGranular matterInterferenceIsostaticJamming

All concepts