Concept

Bohr model — where it appears

Bohr's 1913 picture of an electron in a hydrogen-like atom confined to orbits of fixed angular momentum, giving energy levels of −13.6 eV × Z²/n². It is not how atoms really work, but it gets hydrogen's levels and the scaling of inner-shell X-ray energies with nuclear charge right.

Named by 2 essays across one field — each of them below, with the objects they name alongside it.

An atom made of powers of n. Five properties of a hydrogen atom in a level of principal quantum number n, each divided by its value in the ground state, against n from 1 to 300 on logarithmic axes. The radius of a circular orbit rises as n², to 0.53 µm at n = 100; the orbital period as n³, to 1.5 × 10⁻¹⁰ s; the radiative lifetime of the circular state, from the Larmor loss on its orbit, as n⁵ — slope 5.000 — to 0.9 s. The binding energy falls as n⁻², to 1.36 meV, and the electric field that pulls the electron away falls as n⁻⁴, to 3.2 V/cm. Across n = 1 to 300 the lifetime changes by 2 × 10¹² and the ionising field by 8 × 10⁹.

The atom the size of a bacterium

Excite hydrogen's electron to the hundredth level and the atom is a micrometre across, bound by a thousandth of an electronvolt, pulled apart by the field of a torch battery, and — in its most circular state — able to live for nearly a second. Every one of those numbers is a power of n, and together they make the most exaggerated atom there is into one of the most useful.

quantum · Atomic spectra

The square root of an X-ray's energy, one step per element. The square root of the energy of each element's Kα X-ray line, in units of the Rydberg energy, against its atomic number, for 24 elements from aluminium to lead (dots), with Moseley's law, √(3/4)·(Z − 1), drawn as a line. The points march up in equal steps, one per element, because each step adds one proton to the nucleus and one unit to the charge the falling electron feels. When Moseley first did this, in 1913–14, the line had gaps where no known element fell: the numbers marked, 43, 61, 72 and 75, were found later as technetium, promethium, hafnium and rhenium. At high atomic number the points rise above the line, by 6 per cent for lead, because the innermost electrons there move fast enough for relativity to deepen their binding.

The X-ray line that counts the protons

Strike a metal with fast electrons and it gives off X-rays at a few sharp energies characteristic of the metal. In 1913 Henry Moseley measured the strongest of them for element after element and found that the square root of its energy rose in equal steps, one step per element — as if something inside each atom were being counted. It was the charge on the nucleus. The periodic table had been ordered by weight; Moseley's line ordered it by protons, fixed the elements it was missing, and showed that an electron deep inside a heavy atom behaves like the electron in hydrogen, with the charge turned up.

quantum · Atomic spectra

Named alongside it

The objects these essays reach for when they reach for this one.

Atomic number Blackbody radiation Correspondence principle Field ionisation Larmor formula Moseleys law Periodic table Rydberg atom Scaling law Screening Spontaneous emission X ray fluorescence

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