Concept

Multiple scattering — where it appears

Light that has been scattered more than once before arriving, and has therefore lost the geometry that a single scattering would have imprinted on it. It is what keeps a real sky's polarisation below a hundred per cent, what makes a hazy sky white, and what makes the neutral points a measurement of turbidity.

Named by 4 essays across one field — each of them below, with the objects they name alongside it.

Where the sky's blue goes. How many times more strongly a sphere scatters 450 nm light than 650 nm light, against its radius, with the radius on a logarithmic axis running from a couple of nanometres to twenty micrometres. On the left the ratio sits at 4.35, which is the fourth power of the wavelength ratio and the whole reason the daytime sky is blue. It does not stay there. By a radius of 245 nm the preference has halved, and by a micrometre it has essentially gone: a particle comparable with the wavelength scatters every visible colour within a few per cent of equally, which is why a cloud is white, why fog is white, why milk is white and why the exhaust of a cold diesel is white while the smoke of a cigarette — whose particles are ten times smaller — is blue. Nothing about the material changed between one end of this axis and the other; only the size did.

When the particle is the size of the wave

The sky is blue because small things scatter short wavelengths far more strongly. A cloud is made of the same water and scatters every colour alike. Nothing about the material changed — only the size, and one dimensionless number crossing one.

optics · Scattering
The pattern the whole sky is written in. The sky as a disc — zenith at the centre, horizon at the rim, equal angles at equal distances — with the sun 30° above the horizon. Each short line is the direction the electric field vibrates in at that point, and its length and darkness are how polarised the light there is. The directions are perpendicular to the plane containing the sun, the observer and the point, which puts them tangent to circles centred on the sun. The heavy arc is the locus 90° from the sun, where the polarisation is strongest — 74 per cent here — and it is a great circle rather than a patch: a band across the sky, not a region near the horizon. This is what a polarising filter on a camera acts on, and it is why turning one darkens a band of sky and leaves the rest almost untouched, and why the effect is strongest when the sun is off to one side and absent when it is behind the photographer.

The pattern the sky is written in

Scattered sunlight is polarised, so the whole sky carries a direction of vibration at every point — arranged in circles about the sun, strongest on the great circle ninety degrees away from it, and vanishing at points that were found by looking before anyone could explain them. Bees navigate by it and a camera filter reads one band of it.

optics · Polarisation
Light that walks through a cloud. Seven photons entering a slab 8 scattering mean free paths thick from above, straight down, and followed until they leave, with every scattering equally likely to send them in any direction; their paths are projected onto the page. Of 20000 photons followed the same way, 82.5 per cent come back out of the top and 17.5 per cent out of the bottom. Diffusion theory predicts 18.2 per cent through the bottom. Only 10 photons cross without scattering at all, where e⁻⁸ predicts 6.7 — within the counting error of so few: nearly all of what is transmitted has walked, and the direction it arrived from is forgotten on the way.

The cloud light has to walk through

A beam crossing thirty scattering lengths of anything should keep e⁻³⁰ of itself — a ten-millionth of a millionth. A cloud thirty scattering lengths thick lets through nearly a third of the sunlight falling on it. The light has not crossed; it has walked, one scattering at a time, and a walk through a slab obeys a law with the shape of Ohm's rather than of an exponential.

optics · Scattering
With interference kept, transmission falls exponentially; without it, only as one over the thickness. Light through stacks of randomly thick transparent layers, alternating indices 1 and 2.6, with thicknesses scattered by ±50 per cent about a quarter wave, on a logarithmic scale against the number of layers. The falling line is the transmission with the waves' interference kept, computed exactly by multiplying transfer matrices and averaged as the logarithm over 40 random stacks and five wavelengths. It falls in a straight line: the transmission drops by a factor of e every 17 layers, however thick the stack, which is exponential decay — localisation. The upper curve is the same stacks with every surface's reflection and transmission added as intensities, so that no interference survives. It falls only as one over the thickness, checked to grow in exact proportion, which is the diffusion of light through a cloud: at 400 layers it still transmits 1.0 per cent where the coherent stack typically transmits 4.5·10⁻¹¹.

The walk that interference can stop

Light scattered many times walks through a cloud, and a walk always gets through eventually — a slab twice as thick lets through half as much. Keep the waves' interference instead of adding intensities, and in one dimension the same disorder does something a walk cannot: it stops the light exponentially, traps it in modes with nothing special about where they sit, and turns transmission from a number into a spread over powers of ten. Whether the same can happen to light in three dimensions has been claimed, retracted and argued for thirty years.

optics · Scattering

Named alongside it

The objects these essays reach for when they reach for this one.

Asymmetry parameterCoherent backscatteringDiffusionDipole radiationPolarisationRandom walkRayleigh scatteringAlbedoAnderson localisationAtmosphereDegree of polarisationDepolarisation

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