Illustrated Physics
physics, drawn
Concept

Ionisation — where it appears

The removal of one or more electrons from an atom, changing what the nucleus is surrounded by rather than what it is. It shifts spectral lines, opens or closes decay channels, and in the extreme case turns a stable nuclide into a radioactive one — bare rhenium-187 decays in 33 years against 41.6 billion as an atom.

Named by 6 essays across 3 fields — each of them below, with the objects they name alongside it.

Hydrogen's emission lines, where they are actually seen. Every transition down to level 1, 2, 3 in hydrogen, drawn at the wavelength it emits, on a logarithmic axis in nanometres. The Lyman series begins at 121.5 nm and crowds toward its limit at 91.1 nm; The Balmer series begins at 656.1 nm and crowds toward its limit at 364.5 nm; The Paschen series begins at 1874.6 nm and crowds toward its limit at 820.1 nm. Only the Balmer series has lines in the visible band, which is why it was the one found first.

The spectrum is a subtraction, not a list of values

An atom emits a handful of sharp wavelengths and nothing in between. They are not the atom's energies — they are the differences between them, which is why the lines come in families that crowd onto a limit.

quantum · Atomic spectra The half-life that depends on the electrons. Half-lives of 3 nuclides as neutral atoms and as bare nuclei, measured at a heavy-ion storage ring where fully stripped ions can be kept circulating for months. The changes are not corrections. ¹⁸⁷Re goes from 41.6 billion years to 32.9 — a factor of 1.26 billion — because a beta decay whose available energy is only 2.5 keV cannot put an electron into the continuum but can put one into an empty K orbital, and stripping the atom opens that channel. ¹⁶³Dy is stable as an atom and decays in 47 days as a bare nucleus, for the same reason. The rate is a property of the nucleus and of what surrounds it, not of the nucleus alone.

The half-life that chemistry can change

A nucleus has no clock, the usual account goes, and nothing outside it touches the rate. That is very nearly true and it is not exactly true. Electron capture takes an electron from the nucleus's own position, so its rate is proportional to how many electrons are there — which is chemistry, worth a per cent. And a nucleus stripped of every electron can gain a decay channel it did not have: rhenium-187 goes from forty-two billion years to thirty-three.

quantum · Decay Hydrogen comes apart far below its binding temperature. The fraction of hydrogen that is ionised in equilibrium, against temperature on a logarithmic axis, for densities of hydrogen nuclei of 10²³, 10¹⁸, 10¹², 10⁶ per cubic metre, from Saha's equation. Hydrogen's binding energy, 13.6 eV, corresponds to 157,803 K. It is half ionised at 13,980 K at 10²³ per cubic metre, 7,235 K at 10¹⁸ per cubic metre, 4,519 K at 10¹² per cubic metre, 3,270 K at 10⁶ per cubic metre — at a temperature where kT is between an eleventh and a fiftieth of the energy needed to free the electron. The thinner the gas, the cooler the temperature at which it comes apart, because a free electron in a thin gas has vastly more room to be in than a bound one.

The electron that leaves because there is room

It takes 13.6 electronvolts to pull the electron off a hydrogen atom, the energy of a particle at a temperature of 158,000 kelvin. Hydrogen is half ionised at the surface of a star at 14,000 kelvin, in a thin nebula at 7,000, and in the early universe at under 4,000 — a fortieth of its binding energy. The electron leaves not because it has enough energy but because a free electron has so much more room to be in than a bound one, and at equilibrium room counts as much as energy. Saha's equation is that trade written down, and it turned out to be the key to what stars are made of.

thermodynamics · Chemical potential Hydrogen ionised by heat at one end and by crowding at the other. The ionised fraction of hydrogen against the density of nuclei, at 5,000 K, 10,000 K, 20,000 K, from Saha's equation with the binding energy lowered by the neighbouring charges (solid) and without the lowering (dashed). Thin gas is ionised by the room a free electron gains; compression takes the room away and the gas recombines, as the dashed curves continue to do for ever. The solid curves turn round: at 5,000 K the gas is least ionised, 2.5·10⁻⁴ per cent, near 10²⁶ per cubic metre; at 10,000 K the gas is least ionised, 0.41 per cent, near 10²⁷ per cubic metre; at 20,000 K the gas is least ionised, 12 per cent, near 10²⁸ per cubic metre, and by 6·10²⁸ per cubic metre — 0.10 g/cm³ — every curve is fully ionised, because the ground state no longer exists. That density does not depend on the temperature at all.

The pressure that ionises

Squeeze a hot gas of hydrogen and Saha's equation says it recombines: a free electron has less room to be in, and room was what paid for its freedom. Squeeze it far enough and it comes apart again, completely, at any temperature — not because the room has grown but because the atom has nowhere left to be. Crowded to within a few atomic radii of each other, hydrogen atoms have no bound state, and their electrons, freed by pressure alone, form a metal. Deep inside Jupiter most of the planet's hydrogen is in that state.

thermodynamics · Chemical potential The voltage a gas gap can hold, on one curve. The breakdown voltage of a gap in air between flat electrodes against the product of pressure and gap width, on logarithmic scales — Paschen's law, in which pressure and gap enter only as their product because both count how many collisions an electron makes on the way across. Townsend's model, with γ = 0.01 electrons freed per ion at the cathode, has its minimum of 305 V at 1.12 Pa·m — a gap of 11 μm at atmospheric pressure, or 112 Pa across a centimetre. Measured minima in air are about 330 V. To the left the gap is too short, or the gas too thin, for an electron to make enough collisions, and the voltage climbs steeply; below about 0.41 Pa·m there is no gas breakdown at any voltage. To the right, collisions are so frequent that an electron gains too little energy between them, and the voltage rises nearly in proportion to pd. Dashed, the empirical law for air at larger pd: 31.4 kV for a centimetre at one atmosphere, against the model's 35.5.

The spark that needs room to start

Air is an excellent insulator until it is not, and the usual statement of when — three megavolts a metre — is true only for gaps of about a centimetre. A gap breaks down when one electron's avalanche of ionisation sends back enough ions to the cathode to free one more electron, and that condition depends on the pressure and the gap only through their product. The result is a curve with a floor: about 330 volts in air, below which no gap of any width will spark, and above which both a thinner gas and a denser one insulate better.

electromagnetism · Dielectrics The field round a thin wire. The electric field against distance from the axis, on a logarithmic axis, for a wire inside a coaxial cylinder of radius 10 cm at 60 kV, for wire radii of 0.2, 1 and 5 mm; the dashed line is 30 kV/cm, the field at which air breaks down across a gap of a few centimetres, and each curve starts at its wire's surface. The field falls as 1/ρ, so it is concentrated at a thin wire: 483 kV/cm at the surface of the 0.2 mm wire, 130 at the 1 mm wire and 40.1 at the 5 mm one. The field exceeds 30 kV/cm only within 3.2 mm of the axis for the thinnest wire, 4.3 mm for the middle one and 6.7 mm for the thickest; across the remaining nine centimetres the air is far below breakdown, so ionisation can start at the wire and has nowhere to go.

The glow a thin wire wears before it sparks

Raise the voltage on a thin wire inside a metal tube and, long before anything sparks across, the wire starts to glow faintly violet and to hiss. The air right next to it is ionising, and the air a millimetre further out is not. The field round a wire falls away so fast that an avalanche of ionisation can start at the surface and find nowhere to go. That partial breakdown, corona, costs power lines energy in the rain, sets the size of the wires they are made from, cleans the smoke from chimneys and counts particles in detectors — and the field it needs is not a property of air but of the wire's radius.

electromagnetism · Dielectrics

Named alongside it

The objects these essays reach for when they reach for this one.

Chemical potentialDielectric breakdownElectric fieldSaha equationScreeningTownsend avalancheAtomic spectraAtomic structureBeta decayThe Boltzmann factorCoaxial lineCorona discharge

All concepts