Illustrated Physics
physics, drawn
Concept

Atomic spectra — where it appears

The set of wavelengths an element emits or absorbs, each one a difference between two of its energy levels rather than a level itself. Because differences are what is seen, a spectrum is a subtraction table, and reconstructing the levels from it is a puzzle rather than a reading.

Named by 4 essays across 2 fields — each of them below, with the objects they name alongside it.

Hydrogen's emission lines, where they are actually seen. Every transition down to level 1, 2, 3 in hydrogen, drawn at the wavelength it emits, on a logarithmic axis in nanometres. The Lyman series begins at 121.5 nm and crowds toward its limit at 91.1 nm; The Balmer series begins at 656.1 nm and crowds toward its limit at 364.5 nm; The Paschen series begins at 1874.6 nm and crowds toward its limit at 820.1 nm. Only the Balmer series has lines in the visible band, which is why it was the one found first.

The spectrum is a subtraction, not a list of values

An atom emits a handful of sharp wavelengths and nothing in between. They are not the atom's energies — they are the differences between them, which is why the lines come in families that crowd onto a limit.

quantum · Atomic spectra The rotation two boosts leave behind. The angle through which a frame's axes are turned after two boosts of equal size, against the angle between the two boosts, for 4 speeds. Two boosts in the same direction compose to a boost and nothing else, which is the zero at the left; two in different directions do not. What is left over is a rotation, and it is not small at large speeds: at β = 0.3 it peaks at 2.7° when the boosts are 91° apart, at β = 0.6 it peaks at 12.8° when the boosts are 96° apart, at β = 0.85 it peaks at 36.1° when the boosts are 108° apart, at β = 0.95 it peaks at 63.2° when the boosts are 122° apart. Each curve here is computed by multiplying the two boost matrices and pulling the rotation out of the product, not by evaluating a formula; the closed form for perpendicular boosts is used to check the extraction and appears nowhere in the drawing. The consequence is that the Lorentz boosts do not form a group by themselves — compose two and you leave the set — and that an object carried round a closed path in velocity space comes back turned.

The turn that two pushes leave behind

Two boosts in different directions do not compose to a boost. The product carries a rotation, so a frame carried once round a closed path comes back turned — and the size of that turn was the factor of two standing between the calculated and the measured splitting of a spectral line.

relativity · Velocity addition One level, split by the speed of the electron in it. Hydrogen's n = 2 level on the left at the scale of the whole spectrum, and the same level on the right at a scale ten thousand times finer. The gross structure puts it 3.4014 electronvolts below the ionisation limit; the relativistic and spin–orbit corrections then split it into a lower pair, j = ½, and an upper, j = 3/2, separated by 45.3 microelectronvolts. That gap is 1.331e-5 of the level's own binding energy, which is exactly α²/4 — so the size of the splitting is a measurement of how fast the electron is going, α being its speed in units of c on the innermost orbit. The same physics in sodium is larger by four orders of magnitude: its two D lines at 588.995 and 589.5924 nanometres differ by 2.133 millielectronvolts, which is 1.01e-3 of the transition energy, because the outer electron of sodium penetrates to where the nuclear charge is far from screened and the correction goes as the fourth power of the charge it sees.

The line that is really two

Sodium's yellow line is two lines six-tenths of a nanometre apart, and the gap is not a property of the light. It is a splitting of the atom's own level, caused by the electron's magnetic moment sitting in the field it sees because it is moving — and its size, relative to the level it splits, is exactly α²/4.

quantum · Atomic spectra The levels that refuse to cross. The six energies of sodium 3p against an applied field from zero to 4 crossover fields, 147 T, from diagonalising spin–orbit coupling and the field together. At zero field there are two levels, 515.5 GHz apart. The two states with the largest |mⱼ| are straight lines at every field, because nothing else shares their mⱼ. The other four bend. The two states with mⱼ = −½ approach within 486.0 GHz near 12.3 T and then separate again — √2 ζ exactly, since the coupling between them sets how close they may come — while the mⱼ = −3/2 state falls straight through the lower mⱼ = +½ state at 16.6 T as if it were not there. States that the field cannot mix cross freely; states it can mix exchange character instead, and that exchange is the passage from one pattern to the other.

The field an atom calls strong

A magnetic field splits sodium's two yellow lines into ten, at spacings set by Landé's factors — until the field grows past the one the electron already feels from its own motion, when the ten reorganise into the three a theory without spin predicts. Nothing about the magnet decides which pattern appears. The atom does: the same 45 tesla is a strong field for hydrogen, a middling one for sodium and a weak one for caesium.

quantum · Atomic spectra

Named alongside it

The objects these essays reach for when they reach for this one.

Energy levelsSelection rulesSpinAngular momentumDegeneracyFine structure constantMagnetic momentSpectral lineIonisationThe Lorentz transformationNon commutativityPhoton

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