Concept

Fine structure constant — where it appears

The dimensionless number α ≈ 1/137 that measures the strength of the electromagnetic interaction between charged particles. In an atom it is the speed of the innermost electron in units of c, so fine-structure splittings are a fraction α² of the level spacing.

Named by 3 essays across 2 fields — each of them below, with the objects they name alongside it.

One level, split by the speed of the electron in it. Hydrogen's n = 2 level on the left at the scale of the whole spectrum, and the same level on the right at a scale ten thousand times finer. The gross structure puts it 3.4014 electronvolts below the ionisation limit; the relativistic and spin–orbit corrections then split it into a lower pair, j = ½, and an upper, j = 3/2, separated by 45.3 microelectronvolts. That gap is 1.331e-5 of the level's own binding energy, which is exactly α²/4 — so the size of the splitting is a measurement of how fast the electron is going, α being its speed in units of c on the innermost orbit. The same physics in sodium is larger by four orders of magnitude: its two D lines at 588.995 and 589.5924 nanometres differ by 2.133 millielectronvolts, which is 1.01e-3 of the transition energy, because the outer electron of sodium penetrates to where the nuclear charge is far from screened and the correction goes as the fourth power of the charge it sees.

The line that is really two

Sodium's yellow line is two lines six-tenths of a nanometre apart, and the gap is not a property of the light. It is a splitting of the atom's own level, caused by the electron's magnetic moment sitting in the field it sees because it is moving — and its size, relative to the level it splits, is exactly α²/4.

quantum · Atomic spectra

The field an atom calls strong

A magnetic field splits sodium's two yellow lines into ten, at spacings set by Landé's factors — until the field grows past the one the electron already feels from its own motion, when the ten reorganise into the three a theory without spin predicts. Nothing about the magnet decides which pattern appears. The atom does: the same 45 tesla is a strong field for hydrogen, a middling one for sodium and a weak one for caesium.

quantum · Atomic spectra $Both clocks move, and their ratio does not. Two years of a clock's fractional frequency against a distant clock (upper panel), and of the ratio of two unlike clocks kept side by side (lower panel). Above, both clocks slow as the Earth nears the Sun, with an amplitude of 1.65·10⁻¹⁰, and if the redshift is universal the two curves are one curve. Below, the ratio: the flat line is what universality predicts, and the sinusoid is what a clock responding to the potential 10⁻⁶ more strongly than the other would produce — an annual term of 1.65·10⁻¹⁶, a million times smaller than the shift both clocks share and within reach of clocks that compare to parts in 10¹⁷.$

The clocks that must all slow together

Every clock on the Earth runs slower in January than in July, by three parts in ten thousand million, because the orbit carries the planet deeper into the Sun's potential at perihelion. No clock on the Earth can see this, and that invisibility is the claim worth testing. If the redshift is a property of time rather than of clocks, two clocks built on different physics must slow by exactly the same fraction, and their ratio must not move with the seasons. A ratio that did move would mean the constants of nature depend on where they are measured.

astrophysics · Gravitational redshift

Named alongside it

The objects these essays reach for when they reach for this one.

Angular momentum Atomic spectra Degeneracy Energy levels Magnetic moment Selection rules Spectral line Spin Clocks Eccentricity Equivalence principle General relativity

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