Concept

Density of states — where it appears

How many quantum states a system has per unit energy or per unit frequency, obtained by differentiating the count of states below a level. It is the factor in front of every rate a golden-rule calculation produces, and the ω² in Planck's law and the T³ in a solid's heat capacity are both this quantity.

Named by 6 essays across 2 fields — each of them below, with the objects they name alongside it.

How much of copper's electron sea a temperature can reach. The probability that a state of a given energy is occupied, in copper, at 4 temperatures, with energy measured in units of the Fermi energy — 7.04 eV here. At absolute zero the curve is a step: every state below the ceiling is full and every state above it is empty. Raising the temperature rounds the step, and rounds it over a range of about kT, which is the whole point — at room temperature kT is 0.0259 eV against a ceiling of 7.04 eV, so the rounding is 1.6 per cent of the way down the sea and everything deeper is untouched. An electron in the deep is not held there by a force; it simply has nowhere to go, because every state it could be promoted to is occupied. at 0 K the step is spread over 0.00 per cent of E_F, at 300 K the step is spread over 1.61 per cent of E_F, at 3000 K the step is spread over 16.13 per cent of E_F, at 20000 K the step is spread over 107.52 per cent of E_F.

The pressure that is not a temperature

Copper's conduction electrons are at a temperature of eighty thousand kelvin, in a wire that is at room temperature. That is not a figure of speech, it is what the exclusion principle does to a mole of particles, and it explains the largest unexplained number in the theory of metals.

quantum · Exclusion
How many modes a square has below a given wavenumber. The number of vibration modes of a square with wavenumber below k, counted exactly — every eigenvalue of this region is a closed form, so the staircase is the true count and not an estimate. There are 265 of them below k = 60. The smooth curves are what Weyl's law predicts. The upper one is the leading term alone, the area times k² over 4π, and it is too high by 21.5 modes at the right-hand edge; the lower one subtracts the perimeter term, the perimeter times k over 4π, and is out by 2.4. The content of the law is that the count depends on the region through its area and its perimeter and — to this order — through nothing else at all: not through its shape, not through where its corners are, not through whether it is convex. The staircase's steps are the individual modes, and they cluster where two different pairs of indices give the same wavenumber. That the count is smooth in the large while being a staircase in the small is what makes a mode count usable in thermodynamics, where it appears as a density of states and never as a list.

How many ways there are to vibrate

A drum has infinitely many modes, and below any given frequency it has a finite number of them. That number turns out to depend on the drum's area and the length of its rim and — to the accuracy anybody uses — on nothing else about its shape. Almost every result in thermal physics that involves waves is an application of that count.

waves · Standing waves
A current that falls by a decade for every ångström. Tunnelling current against the width of a vacuum gap, on a logarithmic scale, for three work functions covering the range of clean metal surfaces. The curves are straight because the transmission is an exponential in the gap, and their slopes are 0.833, 0.944, 1.044 decades per ångström — fitted to the drawn curves and agreeing with 2κ/ln 10 to a part in a million. At 4.5 electronvolts a change of ten picometres, a tenth of an atomic radius, changes the current by 24 per cent. That is the sensitivity a scanning tunnelling microscope lives on, and it is why the instrument measures height by holding the current fixed and recording what the piezo had to do: the current is far too steep a function of height to be read as one.

The last atom does all the seeing

A tunnelling rate falls by a factor of eight for every tenth of a nanometre of extra barrier, which is normally quoted as the reason nothing ever tunnels anywhere. Read the other way it is a microscope: the second-nearest atom of a blunt metal tip carries a two-hundredth of the current the nearest one does, so a tip nobody sharpened resolves a single atom, and the resolution comes from an exponential rather than from any piece of engineering.

quantum · Tunnelling
The edge that is a straight line, not a step. The absorption of gallium arsenide near its own band gap of 1.424 electronvolts, on a logarithmic axis, at 4 temperatures. Below the gap the absorption does not stop; it falls exponentially, along a straight line whose slope is an energy, and the straightness holds over several decades. Raising the temperature makes the line shallower — the tail reaches further below the gap — and the slope runs from 5.6 millielectronvolts at 10 kelvin to 7.5 at 300, a factor of 1.33. The lines pivot about a point just above the gap rather than rotating about nothing, which is what makes the slope a single number worth quoting. The band gap's own shift with temperature has been removed here, so that the fan is the tail's doing and not the gap's.

Below the gap, where there is nothing to absorb

A semiconductor is supposed to be transparent below its band gap, and it is not. The absorption falls exponentially instead, over seven decades, along a straight line whose slope is an energy of a few millielectronvolts — and the description that produces that line has no states in the gap at all. What the slope measures is how much the gap itself is moving about.

waves · Attenuation
The peak that rises out of a cloud. A slice through the shadow a released cloud of a million atoms casts after it has expanded, the measurement by which condensates are seen, at 1.1, 0.8 and 0.5 times the transition temperature: the thermal atoms, whose spread of speeds sets the cloud's width, give a broad rounded profile; the condensed atoms, all in one state with only the small spread of momenta their trap allowed, give a narrow peak at the centre, drawn here with the shape repulsion between the atoms gives it. Above Tc there is only the broad cloud. At 0.8 Tc a sharp peak stands up from its middle, holding 47 per cent of the atoms; at 0.5 Tc the peak holds 87 per cent and the thermal wings have shrunk. The two-component shape — a narrow peak on a broad base — was the signature that announced the first gaseous condensates in 1995.

The condensate a trap makes

A gas of atoms held in a magnetic trap and cooled to a few hundred billionths of a degree does something no gas in a box does at any temperature it can reach: a large share of its atoms falls into the trap's single lowest state, and a sharp peak rises out of the cloud. The reason is counting. The trap's excited states can hold only so many atoms at a given temperature, and the number grows as the cube of the temperature — so below one temperature the atoms run out of room, and every atom that does not fit has only one place to go.

quantum · Superfluidity
A lifetime that oscillates with a distance. The rate at which an excited atom emits a photon, relative to its rate in empty space, against its distance from a perfect mirror in wavelengths, for its dipole pointing across the mirror and along it. On the mirror itself the rate doubles for the first and vanishes for the second. As the distance grows both swing about 1 with a period of half a wavelength and a shrinking size: at half a wavelength the along-mirror rate is 0.96, and at a wavelength 0.99. Nothing in the atom has changed; its excited electron and its transition are the same in every position. An emission rate is a property of an atom and of the room it is in.

The lifetime that depends on where the mirror is

A half-life is treated as the most private fact about an atom or a nucleus, and for a nucleus that is nearly true. An excited atom beside a mirror decays faster or slower depending on how many half-wavelengths away the mirror stands, and between two mirrors closer than half a wavelength it does not emit at all. The atom has not changed. A decay is a transition to a state with a photon in it, and the room decides whether that state exists.

quantum · Decay

Named alongside it

The objects these essays reach for when they reach for this one.

Heat capacityAbsorptionApproximationAttenuationBand gapBlackbodyBose einstein condensationBose einstein statisticsBoundary conditionCavity qedChemical potentialDebye model

All concepts