Illustrated Physics
physics, drawn
Concept

Debye model — where it appears

A solid's heat capacity computed by counting its sound waves as modes of a box and cutting the count off at the shortest wavelength the lattice allows. It gives the T³ law at low temperature and the classical value at high, and its only material input is one temperature fixed by the speed of sound.

Named by 2 essays across 2 fields — each of them below, with the objects they name alongside it.

Entropy that is still there at absolute zero, counted and measured. Four substances whose entropy does not go to zero when they are cooled as far as anybody can cool them, with the entropy counted from the arrangements they froze into beside the entropy measured by integrating their heat capacities. Ice is the famous one: every oxygen has four hydrogen bonds and the rule is that two hydrogens sit near it and two far, which leaves six of the sixteen placements legal, and Pauling's count of the whole crystal collapses to R ln(3/2) = 3.371 J per mole per kelvin against a measured 3.41 — an agreement to one per cent from an argument on one line. Carbon monoxide and nitrous oxide are the easy cases, molecules that can lie either way round in the lattice and have too little to gain by choosing. The worst of the four is off by 25 per cent, which is the honest state of this subject: the counts are crude, they ignore the correlations between neighbouring choices, and they still land within sight of a calorimeter. What the figure is really about is that the third law has an escape clause and the escape clause is measurable. A perfect crystal has one arrangement and zero entropy; a crystal that ran out of time while it had many has the logarithm of however many it stopped at, permanently.

The entropy that is still there at zero

The third law says a perfect crystal has no entropy at absolute zero. Ice has 3.41 joules per kelvin per mole left over, and the number can be recovered from one line of counting — two hydrogens near each oxygen and two far, six legal arrangements out of sixteen, R ln(3/2). The law has an escape clause and the escape clause is measurable.

thermodynamics · Third law How many modes a square has below a given wavenumber. The number of vibration modes of a square with wavenumber below k, counted exactly — every eigenvalue of this region is a closed form, so the staircase is the true count and not an estimate. There are 265 of them below k = 60. The smooth curves are what Weyl's law predicts. The upper one is the leading term alone, the area times k² over 4π, and it is too high by 21.5 modes at the right-hand edge; the lower one subtracts the perimeter term, the perimeter times k over 4π, and is out by 2.4. The content of the law is that the count depends on the region through its area and its perimeter and — to this order — through nothing else at all: not through its shape, not through where its corners are, not through whether it is convex. The staircase's steps are the individual modes, and they cluster where two different pairs of indices give the same wavenumber. That the count is smooth in the large while being a staircase in the small is what makes a mode count usable in thermodynamics, where it appears as a density of states and never as a list.

How many ways there are to vibrate

A drum has infinitely many modes, and below any given frequency it has a finite number of them. That number turns out to depend on the drum's area and the length of its rim and — to the accuracy anybody uses — on nothing else about its shape. Almost every result in thermal physics that involves waves is an application of that count.

waves · Standing waves

Named alongside it

The objects these essays reach for when they reach for this one.

Absolute entropyBlackbodyBoundary conditionDensity of statesEigenvalueEntropyErgodicityHeat capacityMicrostatesMode countingNormal modesResidual entropy

All concepts