Concept

Two-level system — where it appears

A system with exactly two accessible states, and the simplest thing a quantum Hamiltonian can act on. It models a spin in a field, a qubit and a pair of coupled modes, and its energy is bounded above — which is what makes a negative temperature possible for it and impossible for anything that can move.

Named by 4 essays across 2 fields — each of them below, with the objects they name alongside it.

Two levels that refuse to cross. On the left, the energies of a two-state system as one state is swept past the other, for couplings of 0, 0.05, 0.15, 0.35 electronvolts. With no coupling at all the two levels cross, which is the dotted pair. With any coupling whatever they do not: the eigenvalues are plus and minus half the square root of the squared detuning plus four times the squared coupling, so the closest approach is exactly twice the coupling — measured off the drawn curves as 0.000, 0.100, 0.300, 0.700 eV against 2V, agreeing to 0.0e+0. Far from the crossing the curves rejoin the uncoupled lines, so the repulsion is local: it is largest where the two states are degenerate and dies away as the square of the coupling divided by the detuning. On the right is what makes this more than a picture of two hyperbolas — the character of the upper state, meaning how much of the first basis state is in it. It swaps completely across a region whose width is set by the coupling, so the level that arrives as one thing leaves as the other. That exchange of identity is why the phrase avoided crossing is misleading: nothing is avoided, the labels are.

The crossing that never happens

Two energy levels swept past one another do not cross. Any coupling between them, however small, opens a gap of exactly twice the coupling — and the two levels exchange their identities across it, so the state that arrives as one thing leaves as the other while the labels are what avoided anything.

quantum · Bands

The temperature that runs off the top of the scale. On the left, the entropy of a collection of two-level systems against how many of them are in the upper level. It rises, reaches 0.69314 per spin — which is ln 2, and is where half of them are up — and then falls, because a system with every spin up is as orderly as one with every spin down. On the right, the slope of that curve, which is one over the temperature. Below the maximum it is positive and ordinary: adding energy adds entropy, and the temperature is what everybody expects. At the maximum it is zero, which means the temperature is infinite. Past it the slope is negative — adding energy now removes entropy — and the temperature is negative. Such a system is not cold. It is hotter than any positive temperature whatever: put it in contact with anything at all and energy flows out of it, because that raises the total entropy. The quantity that orders systems by which way heat flows is not the temperature but its reciprocal, which runs smoothly from large and positive through zero to negative, and it is the temperature that has the discontinuity. None of this is possible unless the energy has a ceiling, which is why it happens in a spin system and not in anything that can move: a gas has no upper bound on its kinetic energy, so its entropy never turns over and its temperature is never negative.

Hotter than any temperature there is

A system whose energy has a ceiling can be pushed past the point where adding energy adds entropy. Its temperature is then negative — and negative temperatures are not cold. They sit above every positive temperature on the only scale that decides which way heat flows, and a working laser is at one.

thermodynamics · Third law $Ramsey fringes: two short pulses and a long wait. The fraction of atoms found in the upper state against the detuning of the drive from the atoms' frequency, in cycles per pulse length, for two π/2 pulses of length τ separated by a free time T = 10τ (solid), computed from the exact two-level evolution. Fringes of period 1/T ride under an envelope set by the short pulses (dotted, the response to one pulse of length 2τ). The central fringe is 0.0444 cycles per τ wide at half height, close to 1/2T. A single long pulse covering the same total time, 12τ (dashed), gives a peak 0.0666 wide: 1.50 times wider, and with no way of telling a large detuning from a small one by its side fringes alone.$

The wait that sets the precision

To measure an atom's frequency, the obvious method is to drive it and look for the response, and the sharpness of the answer is set by how long the drive lasts. Norman Ramsey found in 1949 that most of the drive is wasted. Two short pulses with a long wait between them do better than one long pulse, because during the wait the atom keeps its own time undisturbed, and any difference from the drive's time piles up as an angle the second pulse can read. Every primary clock in the world runs on that idea, and its precision is set by two numbers: how long the atoms can be left alone, and how many of them there are.

quantum · Measurement

A heat capacity that goes up and comes down. The heat capacity per system, in units of Boltzmann's constant, against temperature in units of the level spacing over k: for a system with two levels (red), Schottky's hump x²eˣ/(1 + eˣ)², x = Δ/kT, and for a harmonic oscillator with the same spacing (blue), which climbs to one k and stays there. Both are frozen out when kT is well below the gap. The oscillator then fills its unending stack of levels and reaches equipartition's value. The two-level system peaks at 0.439k when kT = 0.417Δ, and then, with both levels nearly equally occupied and nothing higher to go to, it stops absorbing heat: its capacity falls back towards zero as 1/T².

The heat capacity that goes up and comes down

Equipartition promises every way a system can move a fixed share of heat, and for a harmonic oscillator the promise is kept: once the temperature is high enough, it holds one k per oscillator and goes on holding it. A system with only two levels cannot keep it. It absorbs heat while its upper level is filling, then stops — the two levels equally full and nowhere higher to go — so its heat capacity rises to a peak and falls back to zero. The hump, named after Walter Schottky, is the signature of a degree of freedom with a ceiling, and the area under it counts how many states were there.

thermodynamics · Equipartition

Named alongside it

The objects these essays reach for when they reach for this one.

The Boltzmann factor Entropy Adiabatic theorem Atomic clock Avoided crossing Band gap Bloch sphere Bounded spectrum Coupling Debye model Diabatic Eigenvalue

All concepts