Illustrated Physics
physics, drawn
Concept

Spectroscopy — where it appears

The measurement of how matter absorbs, emits or scatters radiation as a function of frequency. Each line sits at an energy difference fixed by the structure that made it, so a spectrum identifies atoms, molecules and nuclei and measures their temperature, motion and surroundings from a distance.

Named by 2 essays across 2 fields — each of them below, with the objects they name alongside it.

A few cycles, and everything about them is two numbers. The strain radiated by a remnant of 62 solar masses spinning at 0.68 of its maximum, as it settles down, with the decaying envelope of its fundamental mode drawn over it. The fundamental rings at 274 hertz and decays in 3.7 milliseconds, which is 1.0 cycles — this is not a bell and it does not sustain. Every frequency and every decay time in the sum is fixed by the mass and the spin alone; nothing about what made the remnant survives into them. What does depend on the collision is how loudly each mode is excited, and the relative amplitudes here are the rough values a merger of two comparable masses produces rather than a prediction.

A few cycles that are only mass and spin

After the orbit is gone there is one object left, distorted, and it settles down by radiating at frequencies that belong to it rather than to the collision. For a black hole those frequencies are fixed by the mass and the spin and by nothing else — so the first mode measured is a measurement and every mode after it is a test, and the test is that four curves in one plane pass through one point.

astrophysics · Gravitational waves The area under the spacings is the bond. The gap between each vibrational level and the next, against level number, for a Morse well and a Lennard-Jones well with the same depth and the same curvature at the bottom, Λ = 100, in units of the well depth. The sum of the gaps from the lowest level up is the energy needed to break the bond from there. For the Morse well the gaps fall in a straight line to zero, and a straight line through the first 5 of them, extended to zero, encloses 0.9473 against the true 0.9473. For the Lennard-Jones well the gaps start almost the same and fall slightly faster at first — which is what the straight line sees — then trail off in a long tail of small gaps near the top; the same extrapolation from the first 5 encloses 0.7988 against the true 0.9474 — 15.7 per cent short, because the straight line cannot see the crowded levels its data never reached.

The spectrum that weighs a bond

A vibrational spectrum measured near the bottom of a molecule's well gives its curvature, and the curvature says nothing about how deep the well is. Measured further up, it says everything. The levels of a real bond crowd together towards the top, the gap between neighbours falls towards zero, and the sum of all the gaps is the energy it takes to break the bond. A straight line drawn through the gaps that have been measured, and extended to zero, was for decades how bond energies were found — and for a bond with the tail of two neutral atoms it comes out a sixth short.

mechanics · Harmonic approximation

Named alongside it

The objects these essays reach for when they reach for this one.

AnharmonicityBlack holeDampingDegeneracyDissociation energyGravitational wavesHarmonic approximationHorizonsKerr metricLennard jones potentialMeasurementMorse potential

All concepts