Illustrated Physics
physics, drawn
Concept

Doppler broadening — where it appears

The widening of a spectral line because atoms moving toward and away from an observer emit at Doppler-shifted frequencies. The line is Gaussian, its width growing as the square root of temperature over mass. It measures the temperature of stars and gases and hides narrower natural line shapes.

Named by 2 essays across 2 fields — each of them below, with the objects they name alongside it.

The hyperfine structure, read off a room-temperature cell. The difference between the probe's absorption with the pump off and on, which removes the Doppler hump and leaves only the Doppler-free features, against detuning. The three transitions, labelled by the excited level F′, sit at −423.6, −266.65 and 0 MHz, and the three crossovers midway between them at −345.1, −211.8, −133.3 MHz. In this model, which empties the ground level only by exciting it, the crossover between F′ = 2 and 3 is the second strongest feature and the weak transitions to F′ = 1 and 2 are small. In real rubidium spectra the crossovers are often the strongest of all, because excited atoms can fall to the other ground level and be lost to the transition altogether — optical pumping, which the model leaves out and which deepens every hole the pump burns. The positions do not depend on any of that: the separations between the features are the hyperfine splittings of rubidium's excited state, read to a fraction of a megahertz in a glass cell on a bench.

The lines a warm vapour hides

Shine a tunable laser through a cell of rubidium vapour and the absorption is one smooth hump half a gigahertz wide, though the atoms' own lines are eighty times narrower and three of them lie inside it. The atoms are moving, each sees the light Doppler-shifted by its own speed, and their lines are smeared together. Send a second, stronger beam back the other way and narrow dips appear in the hump at exactly the frequencies of the hidden lines — because only atoms standing still can be talked to by both beams at once. The vapour stays at room temperature and the motion is not removed; it is selected against.

quantum · Atomic spectra Fringes that bend into hooks beside a line. The interference fringes seen in a spectrograph behind an interferometer with 10 cm of sodium vapour at 10¹⁴ atoms per cubic centimetre in one arm and a glass plate in the other, against wavelength across the D₂ line (horizontal) and position along the slit (vertical, in fringe spacings). Far from the line the plate tilts every fringe evenly. Near the line the vapour's dispersion sweeps each fringe up on one side and down on the other, and every fringe turns back on itself in a hook: the turning points sit −100 and 100 picometres from the line centre, the same for every fringe. The line itself, a few picometres wide, is a dark gap between them; the hooks lie far outside it, in vapour that is transparent.

The hooks that weigh an absorption line

A strong absorption line is black at its centre, and how black it is says almost nothing about how many atoms made it — double them and the line hardly darkens. The atoms are still there, and they still bend light: on either side of the line, where the vapour is transparent, its refractive index rises and falls by an amount proportional to their number. In 1912 Dmitry Rozhdestvensky found a way to read that index straight off a photograph. Interference fringes passed through a spectrograph curl into hooks beside the line, and the distance between the hooks, squared, counts the atoms — whatever the line's shape and however saturated its core.

optics · Dispersion

Named alongside it

The objects these essays reach for when they reach for this one.

AbsorptionAnomalous dispersionDispersionHyperfine structureInterferometryLaserNatural linewidthOscillator strengthRefractive indexSaturationSpectral lineSpectroscopy

All concepts