Illustrated Physics
physics, drawn
Concept

Hyperfine structure — where it appears

The splitting of an atom's energy levels by the interaction between the electrons and the magnetic moment of the nucleus, typically a millionth of the level spacing. It defines the second, through caesium, and the 21 cm line of hydrogen.

Named by 2 essays across one field — each of them below, with the objects they name alongside it.

Why a flip of the spin takes eleven million years. Spontaneous emission rates against frequency on logarithmic axes. The two lines are the rates an electric dipole of e a₀ and a magnetic dipole of one Bohr magneton would give, both rising as the cube of the frequency; they differ by α²/4, 1.3 × 10⁻⁵, the square of the ratio of the two moments. Measured lines sit near them: Lyman α at 6.3 × 10⁸ s⁻¹, Hα and sodium's D line near 10⁸, and hydrogen's 21 cm line at 2.87 × 10⁻¹⁵ s⁻¹ — a lifetime of 11.0 million years. Its slowness is two factors multiplied: a magnetic moment rather than an electric one, and a frequency nearly a million times lower, cubed.

The line that takes eleven million years

A hydrogen atom in its ground state can flip its electron's spin relative to the proton's and emit a photon of 21 centimetres. Left alone, one atom takes eleven million years to do it. The Galaxy is nonetheless bright at that wavelength, because there is so much hydrogen, and because the flip is so slow that the line's brightness counts atoms without caring how hot they are.

quantum · Atomic spectra The hyperfine structure, read off a room-temperature cell. The difference between the probe's absorption with the pump off and on, which removes the Doppler hump and leaves only the Doppler-free features, against detuning. The three transitions, labelled by the excited level F′, sit at −423.6, −266.65 and 0 MHz, and the three crossovers midway between them at −345.1, −211.8, −133.3 MHz. In this model, which empties the ground level only by exciting it, the crossover between F′ = 2 and 3 is the second strongest feature and the weak transitions to F′ = 1 and 2 are small. In real rubidium spectra the crossovers are often the strongest of all, because excited atoms can fall to the other ground level and be lost to the transition altogether — optical pumping, which the model leaves out and which deepens every hole the pump burns. The positions do not depend on any of that: the separations between the features are the hyperfine splittings of rubidium's excited state, read to a fraction of a megahertz in a glass cell on a bench.

The lines a warm vapour hides

Shine a tunable laser through a cell of rubidium vapour and the absorption is one smooth hump half a gigahertz wide, though the atoms' own lines are eighty times narrower and three of them lie inside it. The atoms are moving, each sees the light Doppler-shifted by its own speed, and their lines are smeared together. Send a second, stronger beam back the other way and narrow dips appear in the hump at exactly the frequencies of the hidden lines — because only atoms standing still can be talked to by both beams at once. The vapour stays at room temperature and the motion is not removed; it is selected against.

quantum · Atomic spectra

Named alongside it

The objects these essays reach for when they reach for this one.

Column densityDoppler broadeningFine structure constantLaserMagnetic dipole transitionNatural linewidthSaturationSpectral lineSpectroscopySpin temperatureSpontaneous emissionStatistical weight

All concepts