Concept

Quantisation — where it appears

The restriction of a quantity to a discrete set of values, imposed by a boundary condition rather than by any limit on measurement. The same condition that gives a string its harmonics gives an atom its levels, and in neither case is the discreteness present in the differential equation.

Named by 22 essays across 6 fields — each of them below, with the objects they name alongside it.

Harmonics on a fixed string. Standing-wave patterns on a string clamped at both ends, at n = 1, 2, 3, 4. Only whole numbers of half-wavelengths fit, which is why the allowed frequencies are discrete.

Only some notes fit, and that is where discreteness comes from

A string clamped at both ends can vibrate at some frequencies and not others. A continuous object producing a whole-number list is the oldest quantisation in physics.

waves · Standing waves

The blackbody spectrum, against what classical physics predicted. Spectral exitance against wavelength for a blackbody at 3000, 4000, 5000 kelvin, in kilowatts per square metre per nanometre. Each curve peaks at the wavelength Wien's displacement law gives — 966 nm at 3000 K, 724 nm at 4000 K, 580 nm at 5000 K — and falls to nothing at short wavelengths.

The curve that would not come down

Classical physics predicted that a warm object radiates infinite power at short wavelengths. Every step of the derivation was correct, the prediction was absurd, and closing the gap required assuming that energy comes in lumps.

quantum · Blackbody

Photocurrent against applied voltage, at two intensities. Photocurrent against retarding voltage for caesium lit at 12×10¹⁴ hertz, at relative intensities of 1 and 2. Both curves reach zero at the same stopping voltage of 2.82 volts, because the brighter light delivers more photons and not more energetic ones. The saturation currents are in the ratio of the intensities. The slope between the stopping voltage and zero assumes the emitted electrons' energies are spread uniformly below the maximum, which they are not; the crossing point does not depend on that assumption.

Light arrives in lumps, and brightness only changes how many

Shine dim blue light on a metal and electrons come out. Shine intense red light and none do, however long the wait. The frequency decides whether anything happens; the intensity decides only how much.

quantum · Photon

The states a box allows, drawn on their energies. A particle confined between two walls one unit apart. States 1, 2, 3 are drawn, each riding on a line at its own energy — 1E₁, 4E₁, 9E₁ — because the energies go as n². Each wavefunction has n − 1 places where it crosses zero inside the box: 0 for n = 1, 1 for n = 2, 2 for n = 3. Nothing about the particle's mass or the depth of the well appears in the shapes; only the count of half-wavelengths that fit does.

The box that allows only some energies

Confine a wave between two walls and only the shapes that fit survive. That is a fact about strings, organ pipes and drumheads, and applying it to a matter wave produces quantisation with no new assumption at all.

quantum · Standing waves

Hydrogen's emission lines, where they are actually seen. Every transition down to level 1, 2, 3 in hydrogen, drawn at the wavelength it emits, on a logarithmic axis in nanometres. The Lyman series begins at 121.5 nm and crowds toward its limit at 91.1 nm; The Balmer series begins at 656.1 nm and crowds toward its limit at 364.5 nm; The Paschen series begins at 1874.6 nm and crowds toward its limit at 820.1 nm. Only the Balmer series has lines in the visible band, which is why it was the one found first.

The spectrum is a subtraction, not a list of values

An atom emits a handful of sharp wavelengths and nothing in between. They are not the atom's energies — they are the differences between them, which is why the lines come in families that crowd onto a limit.

quantum · Atomic spectra

Where the electron actually is, by radius. The radial probability density of the hydrogen 1s, 2s, 2p states — the chance of finding the electron in a thin shell at each radius, in units of the Bohr radius. 1s is most likely at 1.00 Bohr radii and averages 1.50; 2s is most likely at 5.24 Bohr radii and averages 6.00; 2p is most likely at 4.00 Bohr radii and averages 5.00. Each curve integrates to one, and each has n − l − 1 radial nodes where the electron is never found.

Where the electron probably is

The Bohr atom put the electron on a circle of definite radius. What replaced it keeps the radius as the most likely place to find the electron and gives up the circle, the speed and the trajectory entirely.

quantum · Atomic structure

A beam through a chain of analysers. An unpolarised beam of intensity 1 entering 3 analysers oriented at 0°, 90°, 0°, selecting the + then + output each time. The intensities are 0.500 and 0.500 out of analyser 1; 0.250 and 0.250 out of analyser 2; 0.125 and 0.125 out of analyser 3. The last analyser is oriented the same way as the first, and it produces a "−" beam of 0.125 — a beam of exactly the kind the first analyser removed entirely. The middle analyser did not filter the beam; it replaced what the beam had an answer to.

The answer that was not there before

Send a beam through an analyser and it splits in two. Send one half through a second analyser turned sideways, then through a third pointing the way the first did, and the property the first analyser removed has come back.

quantum · Measurement

No two in the same state, and why matter has volume

Nothing in the energy levels of an atom says how many electrons may occupy each one. The answer is one per state, it is not derived from any force, and it is the reason a table holds a cup up.

quantum · Exclusion

One well, two wells, and the band they become. The energy levels of a chain of identical wells, for 1, 2, 3, 6, 12, 40 of them, with an on-site energy of -4 eV and a coupling of -0.9 eV between neighbours. One well has one level. Two split it into two, 1.80 eV apart. By 40 the levels have filled a band 3.59 eV wide, which is closing on the limit of four times the coupling, 3.60 eV — and no further widening happens however many more wells are added. The count of levels grows with the number of wells; the width of the band does not.

What happens when the wells get close

Two atoms brought together split one level into two. A thousand split it into a thousand, packed into a band whose width stops growing after the third. Whether that band is full or half full is the whole difference between a wire and a window.

quantum · Bands

Where the particle is likely to be found. A particle confined between two walls one unit apart. States 1, 4, 16 are drawn, each riding on a line at its own energy — 1E₁, 16E₁, 256E₁ — because the energies go as n². The curves are |ψ|², the probability of finding the particle at each position. The dashed line on each is the classical answer: a ball bouncing between the walls at constant speed is equally likely to be anywhere, and the quantum density oscillates about it and converges onto it as n rises.

Where the quantum picture hands back the old one

A confined particle's probability density oscillates violently at every quantum number, and never stops. What makes the classical answer come back is not that the oscillations die away — it is that nothing can resolve them.

quantum · Correspondence $Two transitions, one shape and one not. The condensate fraction of an ideal Bose gas, 1 − (T/Tc)^3/2, drawn against the superfluid fraction of liquid helium-4, which goes as roughly 1 − (T/Tλ)^5.6. Both reach one at absolute zero and zero at their transition, and in between they disagree everywhere. The ideal calculation says why a transition has to exist; it does not describe the one that does, because its atoms do not interact and helium's do.$

The liquid that will not slow down

Cool helium below 2.17 kelvin and it starts flowing through gaps no ordinary liquid could enter, climbs out of its own container, and circulates for as long as anyone has been willing to watch. The viscosity is not small. As far as any measurement can tell, it is zero.

quantum · Superfluidity

The staircase equipartition cannot climb. The heat capacity of hydrogen at constant volume, in units of R, against temperature on a logarithmic axis. The three translational directions contribute 3/2 at every temperature. The two rotations switch on near 85.4 K — the temperature at which kT matches the first rotational step — taking the total to 5/2, computed here by summing the rigid rotor's partition function over two hundred levels rather than by assuming the plateau. The vibration switches on near 6332 K, taking it to 7/2. At 50 K the value is 2.469; at 300 K the value is 2.502; at 5000 K the value is 3.376. Classical equipartition predicts 7/2 at every temperature, including at four kelvin, and the size of the steps is set by ħ — which is how a heat capacity measures a quantum constant.

Half a kT for every way of moving

A heat capacity ought to be a count. Every quadratic term in a system's energy carries half a kT of it, so warming a gas is a matter of enumerating the ways its molecules can move — and the fact that the count comes out wrong for hydrogen is how a thermometer measured Planck's constant.

thermodynamics · Equipartition $6 modes of a drum, and their frequency ratios. Nodal-line diagrams for 6 modes of a circular membrane, each labelled with its frequency as a multiple of the lowest mode's. A mode (m, n) has m nodal diameters and n − 1 nodal circles, and the circles are drawn at the radii where the computed radial function J_m(j(m,n)·r/R) crosses zero — not at guessed fractions of the radius. The two tints are the two directions the head is moving in at that instant, and the lines between them are the parts of it that never move. The ratios are 1.000, 1.593, 2.136, 2.295, 2.653, 2.917: each one is a quotient of two zeros of Bessel functions, computed here from the power series and checked against their published values to 4.4e-7. Not one is a whole number, which is why a drum has no harmonic series and no pitch in the sense a string has one — and why these same ratios belong to every circular membrane ever stretched, whatever it is made of and however tightly it is pulled.$

The drum that has no harmonics

A string's allowed frequencies are 1, 2, 3, 4 times its lowest, because counting half-wavelengths is arithmetic. Clamp a membrane round a circle and the same reasoning returns 1.000, 1.593, 2.136, 2.295 instead — zeros of Bessel functions, not integers. And those numbers belong to the shape of the boundary alone, which raises a question nobody could answer until 1992.

waves · Standing waves

How fast a spinning electron would have to turn. The equatorial speed of a uniform sphere with the electron's mass and an angular momentum of ħ/2, against the radius it is given, both logarithmically. The expression is 5ħ/4mr and it passes the speed of light at 4.83e-13 m — half a picometre, which is four hundred times larger than a hydrogen nucleus. Giving it a smaller radius only makes the answer worse: at the experimental upper bound, 10⁻¹⁸ m the equator would move at 4.8e+5 times the speed of light; at the classical electron radius the equator would move at 1.7e+2 times the speed of light; at the reduced Compton wavelength the equator would move at 1.3e+0 times the speed of light. No radius the electron is permitted to have gets anywhere near a legal answer, and the experimental bound is off the scale by eight orders of magnitude. So the angular momentum is not the angular momentum of anything going round. It is a property the particle has, in the same way a charge is, and the only thing it shares with a spinning top is the algebra it obeys — which is, admittedly, the whole of what angular momentum means in physics.

The angular momentum that is not a rotation

An electron has angular momentum, and it is not going round anything. A sphere of its mass carrying that much angular momentum would need its equator moving at half a million times the speed of light at any size the electron is allowed to have. What survives of the analogy is the algebra — and the algebra turns out to require that turning the thing all the way round leaves it changed.

quantum · Spin

Circulation against how fast the bucket turns. The circulation round the rim of a bucket of radius 1 mm, against the angular velocity it is spun at. An ordinary liquid ends up rotating with the bucket, and its circulation is 2Ω times the area — the straight dashed line, continuous in Ω and with no special value anywhere on it. A superfluid's velocity is the gradient of a phase, so it can carry circulation only in whole units of h/m = 9.969e-8 m²/s. Below 0.256 radians per second it carries none at all: the bucket turns and the liquid does not, which is what Hess and Fairbank measured. Above it the circulation is a staircase of 13 steps, each exactly one quantum high and each 1.59e-2 radians per second wide. The staircase runs below the classical line by the ln(R/a) quanta the threshold costs, a fixed lag: at 102 radians per second the two agree to 0.24 per cent, which is why a rotating superfluid looks like a rotating liquid at any speed a bucket is normally spun at.

The whirlpool that comes in one size

Spin a bucket of ordinary liquid and it ends up turning with the bucket. Spin a bucket of superfluid helium slowly and it does not turn at all. Spin it faster and it does not turn either — until a threshold, at which a single line of circulation appears, carrying not some amount but exactly h/m. There is nothing in between, because the velocity is the gradient of a phase and a phase has to come back to itself.

fluids · Superfluidity

The rotation that mixes electricity into magnetism. The two Lorentz invariants of a field — E² − c²B² across and 2E·cB up — as the field is rotated by the duality transformation that takes E into cB and cB into −E. Every configuration moves on a circle, so the combination of the two invariants is preserved while neither is. A light wave sits at the origin and stays there, which is why a wave cannot be turned into anything else by this rotation; a static charge starts on the positive axis and is carried round to a pure magnetic field a quarter turn later. The source-free equations are unchanged by the whole family, so a universe with no charges in it has no way to say which field is which.

The symmetry one missing charge would complete

Maxwell's equations with no sources are unchanged by rotating the electric field into the magnetic one. With sources they are not, and the only thing missing is magnetic charge — which, if one existed anywhere, would force every electric charge in the universe to be a multiple of a fixed unit.

electromagnetism · Maxwell equations

The ring picks a whole number and pays for the difference. The kinetic energy of the screening current in a superconducting ring, against the flux applied from outside, in units of the flux quantum. Each parabola belongs to one winding number — the number of times the condensate's phase turns round the ring, which has to be an integer because the wavefunction has to come back to itself. The ring cannot hold an arbitrary flux, so it holds the nearest whole number of quanta and drives a current to make up the difference; the energy of that current goes as the square of the mismatch, which is what each parabola is. The lowest curve at each applied flux is the state the ring is in, and the winding number changes at exactly the half-integers — 0.50 and 1.50 and 2.50 here. So the measurable properties of the ring are periodic in the applied flux with a period of one quantum, which is 2.0678 × 10⁻¹⁵ webers and is about the flux the Earth's field puts through a square micrometre.

Two lengths, and which one is longer

A superconductor has a depth to which a field leaks in and a distance over which superconductivity itself can be built up. Which of the two is larger decides the sign of the energy of a boundary — and therefore whether the material keeps every field out or fills itself with a lattice of holes.

electromagnetism · Superconductivity

The area under the spacings is the bond. The gap between each vibrational level and the next, against level number, for a Morse well and a Lennard-Jones well with the same depth and the same curvature at the bottom, Λ = 100, in units of the well depth. The sum of the gaps from the lowest level up is the energy needed to break the bond from there. For the Morse well the gaps fall in a straight line to zero, and a straight line through the first 5 of them, extended to zero, encloses 0.9473 against the true 0.9473. For the Lennard-Jones well the gaps start almost the same and fall slightly faster at first — which is what the straight line sees — then trail off in a long tail of small gaps near the top; the same extrapolation from the first 5 encloses 0.7988 against the true 0.9474 — 15.7 per cent short, because the straight line cannot see the crowded levels its data never reached.

The spectrum that weighs a bond

A vibrational spectrum measured near the bottom of a molecule's well gives its curvature, and the curvature says nothing about how deep the well is. Measured further up, it says everything. The levels of a real bond crowd together towards the top, the gap between neighbours falls towards zero, and the sum of all the gaps is the energy it takes to break the bond. A straight line drawn through the gaps that have been measured, and extended to zero, was for decades how bond energies were found — and for a bond with the tail of two neutral atoms it comes out a sixth short.

mechanics · Harmonic approximation

A temperature the circuit refuses to go below. The escape temperature — the temperature that would give the measured escape rate if escape were purely thermal — against the actual temperature of the junction, for a 10 µA, 5 pF junction at biases of 0.985 and 0.99 of its critical current. Hot, the two are equal: the phase is kicked over the barrier by thermal noise. Cooled below the crossover, 39 mK at 0.985 and 36 mK at 0.99, the escape temperature stops falling and levels off at 42 mK and 44 mK: the rate no longer depends on the temperature at all. This levelling-off, measured by Michel Devoret, John Martinis and John Clarke in 1985 with the junction's electrical environment carefully characterised, was the evidence that a macroscopic electrical variable tunnels.

The circuit that goes through a wall

Tunnelling is usually told about electrons and alpha particles — single, small, quantum things passing through barriers they cannot climb. In 1985 it was seen in an electrical circuit: the phase difference across a Josephson junction, a coordinate shared by all the electrons in two pieces of superconducting metal, trapped in a well and escaping from it through the barrier rather than over it. The evidence was a temperature below which the circuit's escape rate stopped caring how cold it was. The same circuit showed discrete energy levels, and its descendants are the qubits of superconducting quantum computers.

quantum · Tunnelling

A sharp angle costs a spread of turning. Left: the probability of finding a rotor at each angle, for three states. Right: the probability of each value of its angular momentum, in units of ħ, for the same states. A state bunched to a circular spread of 0.025 has an angular-momentum spread of 2.21ħ; a state bunched to a circular spread of 0.302 has an angular-momentum spread of 0.59ħ; a state with no preferred angle has an angular-momentum spread of 0.00ħ. The angular momentum can only take whole-number values, so its probabilities are bars; the angle is continuous. The state with no preferred angle has exactly one value of angular momentum, and its angle is spread evenly round the circle — where the naive rule would say that its angle's spread times ħ/2 should be infinite, it is π/√3.

The angle the uncertainty principle cannot be written for

Position and momentum trade exactly: squeeze one and the other spreads, with a product never below ħ/2. Angle and angular momentum look like the same pair and are not. A rotor in a state of definite angular momentum has zero spread in angular momentum and a finite spread in angle, π/√3, and their product is zero. Nothing is wrong with the rotor. The relation was written with a commutator that does not hold, because an angle lives on a circle and a line has no ends to wrap round. The relation that does hold measures the angle's spread by how far its average position on the circle falls short of the rim.

quantum · Uncertainty

The electrons that pay in fixed amounts

Fire electrons through mercury vapour and raise the voltage that drives them, and the current they carry should simply rise. In 1914 James Franck and Gustav Hertz found it rising, then collapsing, then rising again, over and over, every 4.9 volts. Below that energy an electron bounces off a mercury atom and keeps almost everything; above it, it can hand the atom exactly 4.9 electronvolts and no other amount. The atom will accept energy only in the size of the gap between its levels — shown here by collisions rather than by light, and misread by its discoverers as something else entirely.

quantum · Atomic structure

The diamonds where the island's charge is fixed. The stability diagram of a single-electron island with identical junctions: bias voltage (units of e/CΣ) against the charge the gate induces (units of e). Inside each shaded diamond, labelled with the number of extra electrons the island holds, every possible tunnelling step costs energy and no current flows; outside, at least one step pays for itself and electrons pass one at a time. The diamonds repeat every time the gate charge rises by one electron, and touch at gate charges of e/2, 3e/2, … where two charge states cost the same and the island conducts at any bias. Their height is e/CΣ in each direction. Probing the model at three points outside the diamonds gives currents of 0.60, 0.25, 0.53; inside them, nothing.

The island that takes electrons one at a time

A capacitor holds charge in proportion to its voltage, and the proportion is a property of its shape — on any piece of metal large enough to see. Make the metal small enough and cold enough, and joined to the world only by tunnel junctions, and the proportion breaks into steps: one electron's charge costs more energy than the heat or the battery can supply, so no current flows at all until it can, and then the electrons cross one by one. A charge of a single electron becomes something a voltmeter can see.

electromagnetism · Conductors

Named alongside it

The objects these essays reach for when they reach for this one.

Energy levels Normal modes Zero-point energy Probability density Superposition Wavefunction Wavelength Angular momentum Boundary conditions Spectrum Spin Standing wave

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