Illustrated Physics
physics, drawn
Concept

Probability density — where it appears

The function whose integral over a region gives the chance of finding something there, a property of a population rather than of any member. Its value at a point is not a probability and has units of one over a volume, which is why only integrals of it mean anything.

Named by 10 essays across one field — each of them below, with the objects they name alongside it.

The states a box allows, drawn on their energies. A particle confined between two walls one unit apart. States 1, 2, 3 are drawn, each riding on a line at its own energy — 1E₁, 4E₁, 9E₁ — because the energies go as n². Each wavefunction has n − 1 places where it crosses zero inside the box: 0 for n = 1, 1 for n = 2, 2 for n = 3. Nothing about the particle's mass or the depth of the well appears in the shapes; only the count of half-wavelengths that fit does.

The box that allows only some energies

Confine a wave between two walls and only the shapes that fit survive. That is a fact about strings, organ pipes and drumheads, and applying it to a matter wave produces quantisation with no new assumption at all.

quantum · Standing waves Where the electron actually is, by radius. The radial probability density of the hydrogen 1s, 2s, 2p states — the chance of finding the electron in a thin shell at each radius, in units of the Bohr radius. 1s is most likely at 1.00 Bohr radii and averages 1.50; 2s is most likely at 5.24 Bohr radii and averages 6.00; 2p is most likely at 4.00 Bohr radii and averages 5.00. Each curve integrates to one, and each has n − l − 1 radial nodes where the electron is never found.

Where the electron probably is

The Bohr atom put the electron on a circle of definite radius. What replaced it keeps the radius as the most likely place to find the electron and gives up the circle, the speed and the trajectory entirely.

quantum · Atomic structure A wavefunction crossing a barrier it has not the energy for. An electron of 2 electronvolts meeting a 3 electronvolt barrier 0.3 nanometres wide, with the four matching conditions solved rather than sketched. Left of the barrier the incident and reflected waves add to a standing pattern; inside it the amplitude decays exponentially; to the right a travelling wave continues with amplitude 0.3912 of the incident one, so 15.3 per cent of the electrons get through. Classically none of them do.

The wall that is not quite a wall

A particle without enough energy to climb a barrier sometimes appears on the other side of it. The probability falls exponentially with the barrier's width, which is why the effect is invisible at ordinary scales and why it can be turned into a microscope.

quantum · Tunnelling The interference pattern arriving one particle at a time. The same double slit — 100 micrometres apart, slits 40 micrometres wide, lit at 633 nm, screen 1 metre away — recorded after 20, 200, 1000 arrivals, with the intensity that governs them plotted underneath. Each arrival is a single dot in one place, drawn at a position sampled from that intensity. After 20 there is no pattern to see; after 1000 the fringes are unmistakable, with the dark ones exactly 6.33 millimetres apart — the wavelength times the screen distance over the separation. The bright ones are not evenly spaced, because the single-slit envelope pulls each maximum toward the centre; its first zero is at 15.8 millimetres and is set by the width of one slit alone.

One arrival at a time, and the pattern still appears

Send particles through a double slit slowly enough that only one is ever in the apparatus, and each arrives as a single dot in one place. Wait, and the dots assemble into fringes that no dot knew about.

quantum · Matter waves A beam through a chain of analysers. An unpolarised beam of intensity 1 entering 3 analysers oriented at 0°, 90°, 0°, selecting the + then + output each time. The intensities are 0.500 and 0.500 out of analyser 1; 0.250 and 0.250 out of analyser 2; 0.125 and 0.125 out of analyser 3. The last analyser is oriented the same way as the first, and it produces a "−" beam of 0.125 — a beam of exactly the kind the first analyser removed entirely. The middle analyser did not filter the beam; it replaced what the beam had an answer to.

The answer that was not there before

Send a beam through an analyser and it splits in two. Send one half through a second analyser turned sideways, then through a third pointing the way the first did, and the property the first analyser removed has come back.

quantum · Measurement Decay, and the ensemble it is a property of. 400 nuclei followed for 4 half-lives. The smooth curve is the exponential; the stepped traces are 3 independent runs in which every nucleus was given its own decay time and told nothing about the others. The number surviving halves at each dashed line — 200, 100, 50, 25 — and it halves again over the next interval regardless of how long the sample has already been sitting there, which is the property no ordinary clock has. The traces wander further from the curve as the numbers get small: at the end only about 25 are left and the scatter is a visible fraction of that.

A nucleus with no clock

A half-life is a precise number and no individual nucleus has one. Each has the same chance of decaying in the next second as it had on the day it formed, and the exponential curve is a property of the population rather than of any member of it.

quantum · Decay Where the particle is likely to be found. A particle confined between two walls one unit apart. States 1, 4, 16 are drawn, each riding on a line at its own energy — 1E₁, 16E₁, 256E₁ — because the energies go as n². The curves are |ψ|², the probability of finding the particle at each position. The dashed line on each is the classical answer: a ball bouncing between the walls at constant speed is equally likely to be anywhere, and the quantum density oscillates about it and converges onto it as n rises.

Where the quantum picture hands back the old one

A confined particle's probability density oscillates violently at every quantum number, and never stops. What makes the classical answer come back is not that the oscillations die away — it is that nothing can resolve them.

quantum · Correspondence The correlation, and the best a shared list of answers can do. The coincidence correlation between two polarisation analysers against the angle between them, over two full turns of the correlation — a polariser turned through 180° is the same polariser, so the picture repeats. The singlet gives −cos 2Δ, drawn through −1.00 at 0°, 1.00 at 90°, −1.00 at 180°, 1.00 at 270°. Beside it is the best correlation any shared list of pre-agreed answers can produce: straight lines between the same four extremes, with corners where the cosine is smooth. The two agree exactly at the multiples of 45° and nowhere else, and they are furthest apart — by 0.2105 — at 19.77° and 70.23°, which is ½ arcsin(2/π) from either end of the quarter turn. The difference is not a matter of degree: it is a curve against a shape with a corner in it, and no list can be bent into the curve.

The correlation no instructions can produce

A pair of gloves in two boxes agrees perfectly and needs no physics, because the answers were settled at packing. What no packing can imitate is the shape that appears as the two analysers are turned relative to each other, and the shape is a number — 2.828 where every list of pre-agreed answers is stuck at 2.

quantum · Entanglement A line is what two bodies give. The electron energy spectrum of tritium, against the vertical line a two-body decay would produce. A nucleus emitting one particle has no choice about how to share the energy: momentum conservation fixes it, and every electron comes out at the same energy. The observed spectrum is a continuum running from zero to the full available energy, with a mean at 0.31 of the endpoint. The shape is a count of the ways the energy can be divided between an electron and something else, and the something else was proposed for no other reason than that the shape requires one.

The energy that did not all arrive

A nucleus emitting one particle has no choice about the energy it comes out with — momentum conservation fixes it, and the spectrum is a line. Beta decay gives a continuum instead, from zero to the full available energy, and the shape of that continuum is a count of the ways the energy can be shared. Counting it required a third body nobody had seen, and the way the count approaches its endpoint is still the best place to weigh one.

quantum · Decay The half-life that depends on the electrons. Half-lives of 3 nuclides as neutral atoms and as bare nuclei, measured at a heavy-ion storage ring where fully stripped ions can be kept circulating for months. The changes are not corrections. ¹⁸⁷Re goes from 41.6 billion years to 32.9 — a factor of 1.26 billion — because a beta decay whose available energy is only 2.5 keV cannot put an electron into the continuum but can put one into an empty K orbital, and stripping the atom opens that channel. ¹⁶³Dy is stable as an atom and decays in 47 days as a bare nucleus, for the same reason. The rate is a property of the nucleus and of what surrounds it, and the rung below this one says otherwise.

The half-life that chemistry can change

The first rung of this ladder said a nucleus has no clock and that nothing outside it touches the rate. That is very nearly true and it is not exactly true. Electron capture takes an electron from the nucleus's own position, so its rate is proportional to how many electrons are there — which is chemistry, worth a per cent. And a nucleus stripped of every electron can gain a decay channel it did not have: rhenium-187 goes from forty-two billion years to thirty-three.

quantum · Decay

Named alongside it

The objects these essays reach for when they reach for this one.

WavefunctionQuantisationDecoherenceMatter waveSuperpositionAtomic structureBeta decayBoundary conditionsDecayExponential sensitivityHalf-lifeInterference

All concepts