Illustrated Physics
physics, drawn
Concept

Photoelectric effect — where it appears

The ejection of a bound electron by a single photon carrying more than its binding energy. Read as a function of photon energy it is a threshold, and in an attenuation curve that threshold is a step — a material becoming suddenly more opaque to a harder photon, which nothing smooth produces.

Named by 2 essays across 2 fields — each of them below, with the objects they name alongside it.

Three sources, and the number that separates them. The chance of detecting a second photon a delay τ after a first, divided by the chance if the two were independent, for three kinds of light. At long delay every curve is one, which is what independence means. At zero delay they are 2, 1 and 0, and those three numbers are three different physical situations. Thermal light is bunched: its intensity fluctuates, and a photon is more likely to be found where the intensity happened to be high, so it arrives with company for as long as the fluctuation lasts — 4 nanoseconds here. A laser is flat, because a coherent state has no intensity fluctuation to correlate with. And a single emitter is antibunched: it gives zero, exactly, because after emitting it is in its ground state and cannot emit again until it has been re-excited, which takes 12 nanoseconds. The zero is the important one. Every classical field, of every possible intensity distribution, has g²(0) at least one — the inequality follows from the fact that the mean square of a real positive quantity is at least the square of its mean. A measurement below one is not merely evidence for photons; it is a result no wave theory can produce.

The experiment a wave cannot pass

The photoelectric effect is offered everywhere as the proof that light is quantised, and it is not one — a classical wave falling on quantised matter reproduces every feature of it. The measurement that no wave can pass is a different one: send single photons at a beam splitter and count how often both detectors fire.

quantum · Photon An absorption that goes up when the photon gets harder. Mass attenuation coefficients for 4 materials against photon energy, both logarithmic, from tabulated measurements interpolated between. Away from a threshold every curve falls steeply — a harder photon is less easily absorbed, which is what makes X-rays penetrating. At a K edge the curve jumps upward: the photon has become able to eject an innermost electron, a whole new population becomes available, and the absorption multiplies by 4.4 for iodine at 33.17 keV and 4.0 for lead at 88 keV. That is a discontinuity in a material property as a function of frequency, and nothing in the classical description of absorption produces one. It exists because absorption at these energies is a transition of a bound electron rather than a loss in a medium.

The steps in an absorption curve

Every absorption law up to this point is smooth — a fixed loss per cycle, a relaxation, a power of frequency. Take the photon energy up to where it can eject an electron from an atom and the curve acquires steps, and they go the wrong way: the material becomes suddenly more opaque to a harder photon. Iodine absorbs four times as strongly at 33.4 keV as at 33.0, and that discontinuity is why it is injected into people.

waves · Attenuation

Named alongside it

The objects these essays reach for when they reach for this one.

AbsorptionAntibunchingAttenuationBeam splitterBinding energyCauchy schwarzCoincidenceCross-sectionEnergy levelsPhotonResolving powerScreening

All concepts