Concept

Resolving power — where it appears

How finely an instrument distinguishes two things, given as the smallest separation or the largest ratio it can tell apart. For a grating it is the order times the number of illuminated rulings; for a lens it is the wavelength divided by twice the numerical aperture.

Named by 9 essays across 4 fields — each of them below, with the objects they name alongside it.

One level, split by the speed of the electron in it. Hydrogen's n = 2 level on the left at the scale of the whole spectrum, and the same level on the right at a scale ten thousand times finer. The gross structure puts it 3.4014 electronvolts below the ionisation limit; the relativistic and spin–orbit corrections then split it into a lower pair, j = ½, and an upper, j = 3/2, separated by 45.3 microelectronvolts. That gap is 1.331e-5 of the level's own binding energy, which is exactly α²/4 — so the size of the splitting is a measurement of how fast the electron is going, α being its speed in units of c on the innermost orbit. The same physics in sodium is larger by four orders of magnitude: its two D lines at 588.995 and 589.5924 nanometres differ by 2.133 millielectronvolts, which is 1.01e-3 of the transition energy, because the outer electron of sodium penetrates to where the nuclear charge is far from screened and the correction goes as the fourth power of the charge it sees.

The line that is really two

Sodium's yellow line is two lines six-tenths of a nanometre apart, and the gap is not a property of the light. It is a splitting of the atom's own level, caused by the electron's magnetic moment sitting in the field it sees because it is moving — and its size, relative to the level it splits, is exactly α²/4.

quantum · Atomic spectra
What arrives in the back focal plane. A grating of pitch 1.2 µm illuminated at 550 nm, and the spectrum that appears in the objective's back focal plane. Each spatial frequency in the object leaves at its own angle, sinθ = mλ/d, and the bar heights are the Fourier coefficients of the object's transmittance. The aperture admits everything inside sinθ = 0.65, which here is orders -1, 0, 1 — 2 of them carrying information about the pitch. Orders outside it are drawn faint and are simply lost: they never reach the image plane, and no amount of magnification afterwards recovers them. This is where a microscope's resolution is decided — not at the image, not by the eyepiece, but by which of these bars the front of the objective is wide enough to catch.

The image that is a diffraction pattern twice

A lens does not project an object onto a screen. It takes the object's spatial frequencies apart, spreading them across its own back focal plane at an angle each, and then puts them back together — so an image is the object's spectrum, filtered by whatever the aperture admits, transformed back. With only the zeroth order through, the image is a uniform grey with no information in it at all.

optics · Imaging
The spectrum, and what the interferometer records instead. On the left, a source spectrum: 1 line near 2000 reciprocal centimetres. On the right, what a detector behind a two-beam interferometer reads as the path difference is scanned — the interferogram. It is the cosine transform of the spectrum, so the two panels carry exactly the same information and neither is more fundamental. The fast oscillation is the mean wavenumber; the envelope that decays over about 0.133 centimetres is the reciprocal of the linewidth, which is the coherence length; and where two lines are present, the beat between them is the splitting. Nothing disperses anything anywhere in the instrument.

The fringe and the spectrum are one measurement

An interferometer with no prism and no grating in it measures a spectrum, because what it records as the path difference is scanned is the Fourier transform of the source's spectrum. Coherence length and linewidth are the same fact stated twice, and the resolution is bought in centimetres of travel.

optics · Coherence
What a row of sources does that one cannot. The pattern of 8 identical sources in a row, spaced 0.5 wavelengths apart, all driven in phase. Each source alone radiates the same in every direction drawn here; together they radiate almost entirely along one. The sum being performed is the sum over path differences across the row, which is the sum a diffraction grating performs over its slits — the same function with the same first null, at sin θ = 1/Nd, measured here off the curve. What has been exploited is retardation: the contributions arrive at different times, and the pattern is a map of where they arrive in step.

When the source is not heard all at once

The dipole approximation is not a statement that a source is small. It is a statement that every part of it is heard at the same retarded time, and dropping that assumption turns one source into a sum over a source. The sum is the same one a diffraction grating performs over its slits, with the same first null and the same extra orders — so a phased array and a grating are one piece of arithmetic met twice.

electromagnetism · Retardation
Two intersections, and the rule that picks one. The phase-matching construction for light arriving at 40° from a medium of index 1 into one of index -1. The circles are each medium's own relation between wavevector and frequency; the vertical line is the tangential wavenumber, which the boundary conserves. The line crosses the second circle twice, and the construction alone does not say which point is the answer — the rule that does is that energy must travel away from the interface. For a positive index the energy runs along the wavevector and the upper point is taken. For a negative one the energy runs against it, so the lower point is taken, the wavevector points back toward the boundary, and the ray leaves at -40.0° — on the same side of the normal as it arrived. Nothing in the drawing has changed except which intersection is circled.

The ray on the wrong side of the normal

The phase-matching construction draws a circle and a line, and the line crosses the circle twice. Every earlier construction silently took the upper intersection. Which one is physical is decided by where the energy goes rather than by where the wavevector points, and in a medium whose group velocity opposes its phase velocity the answer is the other one — so the refracted ray leaves on the same side of the normal it arrived on, a flat slab focuses, and a lens can beat the diffraction limit until loss stops it.

optics · Refraction
An absorption that goes up when the photon gets harder. Mass attenuation coefficients for 4 materials against photon energy, both logarithmic, from tabulated measurements interpolated between. Away from a threshold every curve falls steeply — a harder photon is less easily absorbed, which is what makes X-rays penetrating. At a K edge the curve jumps upward: the photon has become able to eject an innermost electron, a whole new population becomes available, and the absorption multiplies by 4.4 for iodine at 33.17 keV and 4.0 for lead at 88 keV. That is a discontinuity in a material property as a function of frequency, and nothing in the classical description of absorption produces one. It exists because absorption at these energies is a transition of a bound electron rather than a loss in a medium.

The steps in an absorption curve

Every absorption law up to this point is smooth — a fixed loss per cycle, a relaxation, a power of frequency. Take the photon energy up to where it can eject an electron from an atom and the curve acquires steps, and they go the wrong way: the material becomes suddenly more opaque to a harder photon. Iodine absorbs four times as strongly at 33.4 keV as at 33.0, and that discontinuity is why it is injected into people.

waves · Attenuation
One slit, four distances, one multiplication. The intensity across the beam behind a slit 5 wavelengths wide, at distances of 0.5, 5, 25, 100 wavelengths, each computed by multiplying the slit's plane-wave spectrum by the phase each wave accumulates and transforming back — no approximation about angles. Close to the slit the pattern is the slit's own shape with ripples at its edges; further out the ripples move inwards and the beam develops a bright centre; far away it spreads into the diffraction pattern. The travelling part of the field keeps its power to 10⁻¹⁰, running it back 100 wavelengths recovers it to 5 × 10⁻¹⁴, and at 100 wavelengths the result matches a direct Fresnel integral to 2.75 per cent rms. Near field and far field are not two theories; they are one multiplication at different distances.

The fan of plane waves inside every beam

Huygens added up wavelets from every point of a front. The same content can be written as a sum over plane waves travelling in every direction, and then propagation stops being an integral and becomes a multiplication: each plane wave picks up a phase in proportion to the distance. One square root in that phase holds all of diffraction, near field and far field alike — and when the square root turns imaginary, it holds the reason no instrument a wavelength away can see detail finer than half a wavelength.

waves · Huygens
A field that oscillates faster than any of its components. The oscillation of (cos x + i·2·sin x) to the power 10 over half a period, with its changing size divided out so that only the turning of its phase shows, beside the fastest wave it contains, cos 10x (dashed). Multiplied out, the function is a sum of waves e^(inx) with n running from −10 to 10 and no further. Yet in the shaded window, |x| < 0.62, it oscillates faster than cos 10x — near the origin like cos 20x, 2 times faster — completing 3.0 cycles there where its fastest component completes 2.0. Outside the window it slows down, and the next figure shows what happens to its size there.

The wiggle faster than any wave in it

Light passing through a lens carries no detail finer than half a wavelength, because no travelling wave in it varies faster than that. It would seem to follow that the light itself cannot vary faster anywhere. It can. A sum of slow waves can be arranged to wiggle faster than any of them over a stretch of any length chosen — and to focus to a spot as narrow as wanted — provided the stretch sits between side lobes that grow exponentially with every extra wiggle.

waves · Huygens
Light added to its own reflection. Green light of 550 nm in an emulsion of refractive index 1.5, falling on a metal mirror at the left and adding to its reflection, which comes back inverted. Thin lines: the total electric field across the first 750 nm at three moments; heavy line: its envelope, 2|sin kz|; dashed: the envelope of the magnetic field, 2|cos kz|. The sum does not travel. Its electric field is zero at the mirror at every instant and again every 183 nm, half a wavelength in the emulsion, with maxima between; the magnetic field is largest exactly where the electric field vanishes. A light-sensitive layer anywhere in that space is exposed in sheets parallel to the mirror, and which field it responds to decides whether the first sheet lies at the mirror or a quarter-wavelength above it.

The photograph that keeps the spectrum

Light falling on a mirror adds to its own reflection, and the sum does not travel: it stands, with sheets of darkness every half-wavelength. Otto Wiener photographed those sheets in 1890 and found the film clear where it touched the mirror, which settled which of light's two fields acts on matter. A year later Gabriel Lippmann recorded the sheets through the depth of an emulsion and developed them into stacked layers that, lit with white light, send back exactly the colours that wrote them. His photographs store the spectrum itself, so they can tell apart two yellows that every colour film and every eye records as one.

waves · Superposition

Named alongside it

The objects these essays reach for when they reach for this one.

Fourier transformInterferenceDiffractionEvanescent waveSpectrumApertureBandwidthCoherenceEnergy levelsPhase matchingRefractive indexScreening

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