Illustrated Physics
physics, drawn
Concept

Pauli exclusion — where it appears

The requirement that a state of identical fermions change sign when two labels are swapped, which forbids two of them from occupying the same state. Its consequences are not small: it gives matter its volume, fixes the order the shells fill, and holds up a white dwarf against gravity with no temperature at all.

Named by 7 essays across 3 fields — each of them below, with the objects they name alongside it.

How fast a spinning electron would have to turn. The equatorial speed of a uniform sphere with the electron's mass and an angular momentum of ħ/2, against the radius it is given, both logarithmically. The expression is 5ħ/4mr and it passes the speed of light at 4.83e-13 m — half a picometre, which is four hundred times larger than a hydrogen nucleus. Giving it a smaller radius only makes the answer worse: at the experimental upper bound, 10⁻¹⁸ m the equator would move at 4.8e+5 times the speed of light; at the classical electron radius the equator would move at 1.7e+2 times the speed of light; at the reduced Compton wavelength the equator would move at 1.3e+0 times the speed of light. No radius the electron is permitted to have gets anywhere near a legal answer, and the experimental bound is off the scale by eight orders of magnitude. So the angular momentum is not the angular momentum of anything going round. It is a property the particle has, in the same way a charge is, and the only thing it shares with a spinning top is the algebra it obeys — which is, admittedly, the whole of what angular momentum means in physics.

The angular momentum that is not a rotation

An electron has angular momentum, and it is not going round anything. A sphere of its mass carrying that much angular momentum would need its equator moving at half a million times the speed of light at any size the electron is allowed to have. What survives of the analogy is the algebra — and the algebra turns out to require that turning the thing all the way round leaves it changed.

quantum · Spin The hole that holds exactly one particle. How likely a second particle is to be found a distance away from a first, relative to a gas with no correlation at all, for three cases that differ in nothing but the symmetry of the state under swapping the two labels. There is no interaction anywhere in this calculation: no Coulomb term, no potential, no force. Distinguishable particles give a flat line, which is what no interaction ought to give. Identical fermions dig a hole that reaches exactly zero at zero separation and fills back in over about a wavelength. Identical bosons do the opposite and pile up to twice the density. Integrating the fermion hole gives 0.9992 particles missing from around each one — exactly one, and the sum rule holds at any density, because raising the density narrows the hole in exact proportion. That is what makes the effect worth a name of its own. It is often called an exchange force and it is not a force: nothing carries momentum between the particles, and no term in the energy is proportional to a distance. It is a statement about which states exist. What follows from it is most of chemistry — the reason two atoms with filled shells repel, the reason a metal's electrons cost so much less Coulomb energy than a random arrangement would, and the reason matter takes up room.

The force with no force in it

Two identical fermions keep apart and two identical bosons crowd together, and neither is being pushed. The Hamiltonian contains no interaction at all: what produces the hole and the pile is which many-particle states exist, and the hole it digs around each electron holds exactly one particle at any density whatever.

quantum · Exclusion The interaction that orders a magnet is not the magnetic one. For six ordered magnets, two temperatures on a logarithmic scale: the energy of the magnetic interaction between two neighbouring moments, expressed as a temperature, and the temperature at which the material actually orders. iron orders at 1043 K against a dipolar scale of 0.201 K, a factor of 5182; cobalt orders at 1394 K against a dipolar scale of 0.117 K, a factor of 11961; nickel orders at 627 K against a dipolar scale of 0.015 K, a factor of 42312; gadolinium orders at 293 K against a dipolar scale of 0.790 K, a factor of 371; europium oxide orders at 69 K against a dipolar scale of 0.615 K, a factor of 112; lithium holmium fluoride orders at 1.53 K against a dipolar scale of 1.230 K, a factor of 1.24. The five ferromagnets order between a hundred and forty thousand times above the only interaction their moments have with each other, so whatever aligns them is not magnetism. The sixth is the control: lithium holmium fluoride is a magnet whose ordering really is dipolar, and its two temperatures agree.

What holds a magnet together is not magnetism

Two neighbouring moments in iron interact magnetically with an energy worth a fifth of a kelvin, and iron keeps its order to 1,043 kelvin. Whatever aligns them is five thousand times stronger than the only force they exert on one another — and it is electrostatic, with the exclusion principle deciding which of two spatial arrangements two electrons may use.

electromagnetism · Magnetisation The triangle of collisions that survive. Every collision of a particle ε above a filled Fermi sea with a partner from the sea, at zero temperature: the partner's energy across, one product's energy up, both from the Fermi level, the other product's fixed by energy conservation. Without exclusion every point in the plotted square would be an allowed collision. With it, the partner must come from below the Fermi level, and both products must land above it: the partner no deeper than ε below, the first product above zero, the second product above zero too. What survives is the shaded triangle, whose area is half of ε squared, and the collision rate is proportional to it. Halve the particle's excess energy and the triangle shrinks to a quarter; at the Fermi level itself it vanishes, and a particle there cannot scatter at all.

The collisions the exclusion principle forbids

A copper wire holds one free electron per atom, packed a quarter of a nanometre apart and repelling one another with the full Coulomb force. It seems impossible that an electron could travel any distance through that crowd without colliding. It travels micrometres — thousands of atoms — before another electron deflects it. The collisions are not weak. They are forbidden: to collide, both electrons need empty states to move into, and in a sea filled to the brim almost none exist. The same rule makes cold helium-3 thicken as the square of how cold it gets.

quantum · Exclusion The proton fraction a cold star settles at. The fraction of nucleons that are protons in cold matter in beta equilibrium, where the neutron's chemical potential equals the proton's plus the electron's, against density on logarithmic axes, for free neutrons, protons and electrons with no nuclear forces. Below 1.22·10⁷ g/cm³ the electrons cannot pay the 1.29 MeV difference between a neutron and a proton and the matter is all protons. Above it the fraction collapses, to 0.014 per cent at its lowest near 7.9·10¹¹ g/cm³, and at nuclear density, 2.66·10¹⁴ g/cm³, it is 0.49 per cent. At higher densities it climbs slowly towards one ninth, 11 per cent, which it never reaches. The dashed part lies where real matter is made of nuclei rather than free nucleons.

The protons a star cannot afford

A free neutron decays in fifteen minutes into a proton, an electron and an antineutrino. Inside a neutron star it cannot, and the star is made of neutrons because of it. Beta decay is a reaction like any other, and at equilibrium the neutron's chemical potential must equal the proton's plus the electron's. In a crowded star an electron can only be added at the top of a sea tens of megaelectronvolts deep. So the matter settles where protons are rare: half a per cent of the nucleons at nuclear density, if nucleons were free, and never more than one in nine at any density.

thermodynamics · Chemical potential Which atoms in a Fermi sea are allowed to take a photon's kick. A slice through the occupied momentum states of a gas of identical fermions at zero temperature — a filled disc whose radius is the Fermi momentum — with each state marked by whether it can absorb a recoil of 0.8 of the Fermi momentum to the right, the kick a scattered photon gives. A state can scatter only if its kicked momentum lands outside the sea, in an empty state. The kicked sea is the second circle; the atoms in the overlap of the two (grey) land on occupied states and cannot scatter, and only those in the crescent (blue) can. In this slice 50 per cent of the states are allowed; over the whole sphere the allowed share is S(q) = 3q/4 − q³/16 = 0.568. A kick larger than the sea's diameter, twice the Fermi momentum, is never blocked, which is why the effect needs a sea whose Fermi momentum is comparable with the photon's.

The light a full sea will not scatter

An atom that scatters a photon recoils, and the recoil has to put it into a new state of motion. In a cold, dense gas of identical fermions most of the states it could recoil into are already taken, and the exclusion principle forbids the scattering outright. Nothing about the atom has changed — not its electrons, not its transition, not its cross-section — yet the gas becomes dimmer than the same number of atoms scattered one at a time. The effect was predicted in the 1990s and seen in 2021, and it turns transparency into a measurement of how full a quantum gas is.

quantum · Exclusion The cloud that stops shrinking. The rms size of a cloud of 10⁵ ideal atoms in a harmonic trap, in units of the Fermi radius, against temperature in units of the Fermi temperature, for fermions, for bosons and for a classical gas. The classical cloud shrinks as the square root of half the temperature ratio, all the way to nothing. The bosons follow it down to their condensation temperature, 0.52 of the Fermi temperature, and then collapse into the trap's ground state, whose rms size is 0.054 Fermi radii. The fermions part from the classical line near the Fermi temperature and level off at one over the square root of eight, 0.354 of the Fermi radius: at a quarter of the Fermi temperature they are 1.17 times the classical size, and cooling further barely changes them. Mixed together in one trap, as lithium-7 and lithium-6 were in 2001, the two clouds start the same size and end 6.5 times apart in width for ideal atoms of these numbers — further still in volume. The fermions are held up by nothing but the rule that no two of them may share a state.

The cloud that stops shrinking

Two kinds of lithium atom, cooled together in one magnetic trap to a few hundred billionths of a degree, start as clouds of the same size and end very differently. The lithium-7 atoms, which are bosons, shrink with the temperature and then collapse into a condensate. The lithium-6 atoms, which are fermions, stop shrinking at about a quarter of their Fermi temperature and refuse to get any smaller, however much colder they become. Nothing pushes them apart but the rule that no two identical fermions may share a state. The photographs taken in 2001 were the first time Fermi pressure — the pressure that holds up white dwarfs — was seen as a picture.

quantum · Exclusion

Named alongside it

The objects these essays reach for when they reach for this one.

Fermi energyExchange interactionFerromagnetismAngular momentumAntisymmetryBeta equilibriumBose einstein condensateBosonChemical potentialCovalent bondCurie temperatureDegenerate fermi gas

All concepts