Illustrated Physics
physics, drawn
Concept

Exchange interaction — where it appears

The energy difference between states that differ only in the symmetry of their wavefunction under swapping two identical particles. It is not a force — no term in the Hamiltonian corresponds to it — and it is nevertheless the largest energy in magnetism, at about 1,000 kelvin in iron against 0.1 kelvin for the magnetic interaction.

Named by 4 essays across 2 fields — each of them below, with the objects they name alongside it.

Four product states, and the four combinations that have a total spin. The four ways two spin-halves can be arranged, on the left, and the four combinations of them that are eigenstates of the total spin, on the right. Two of the products — both up and both down — are already eigenstates. The other two are not: one spin up and the other down does not specify a total spin, because it does not say which spin is which, and the states that do are the sum and the difference. The eigenvalues printed beside them are computed by applying S² as a matrix in the product basis and reading the result off, then solving s(s + 1) for s: |↑↑⟩ gives 2ħ², so s = 1; (|↑↓⟩ + |↓↑⟩)/√2 gives 2ħ², so s = 1; |↓↓⟩ gives 2ħ², so s = 1; (|↑↓⟩ − |↓↑⟩)/√2 gives 0ħ², so s = 0. The column on the far right is the eigenvalue of the operator that swaps the two particles: the three states with s = 1 come back unchanged and the one with s = 0 comes back with a minus sign. That sign is the whole of the difference. It is why the three are called a triplet and the one a singlet, why they behave differently in a magnetic field, and — through the requirement that the total state of two electrons be antisymmetric — why the two families occupy space differently before any force between them has been mentioned.

Four states, and one of them is odd

Two spin-halves make four states, and they split three and one rather than into four of a kind. Three come back unchanged when the two particles are swapped and one comes back with a minus sign — and that single sign decides how far apart two electrons sit before any force between them has been mentioned, and why hydrogen gas is two gases that do not interconvert.

quantum · Spin The hole that holds exactly one particle. How likely a second particle is to be found a distance away from a first, relative to a gas with no correlation at all, for three cases that differ in nothing but the symmetry of the state under swapping the two labels. There is no interaction anywhere in this calculation: no Coulomb term, no potential, no force. Distinguishable particles give a flat line, which is what no interaction ought to give. Identical fermions dig a hole that reaches exactly zero at zero separation and fills back in over about a wavelength. Identical bosons do the opposite and pile up to twice the density. Integrating the fermion hole gives 0.9992 particles missing from around each one — exactly one, and the sum rule holds at any density, because raising the density narrows the hole in exact proportion. That is what makes the effect worth a name of its own. It is often called an exchange force and it is not a force: nothing carries momentum between the particles, and no term in the energy is proportional to a distance. It is a statement about which states exist. What follows from it is most of chemistry — the reason two atoms with filled shells repel, the reason a metal's electrons cost so much less Coulomb energy than a random arrangement would, and the reason matter takes up room.

The force with no force in it

Two identical fermions keep apart and two identical bosons crowd together, and neither is being pushed. The Hamiltonian contains no interaction at all: what produces the hole and the pile is which many-particle states exist, and the hole it digs around each electron holds exactly one particle at any density whatever.

quantum · Exclusion The interaction that orders a magnet is not the magnetic one. For six ordered magnets, two temperatures on a logarithmic scale: the energy of the magnetic interaction between two neighbouring moments, expressed as a temperature, and the temperature at which the material actually orders. iron orders at 1043 K against a dipolar scale of 0.201 K, a factor of 5182; cobalt orders at 1394 K against a dipolar scale of 0.117 K, a factor of 11961; nickel orders at 627 K against a dipolar scale of 0.015 K, a factor of 42312; gadolinium orders at 293 K against a dipolar scale of 0.790 K, a factor of 371; europium oxide orders at 69 K against a dipolar scale of 0.615 K, a factor of 112; lithium holmium fluoride orders at 1.53 K against a dipolar scale of 1.230 K, a factor of 1.24. The five ferromagnets order between a hundred and forty thousand times above the only interaction their moments have with each other, so whatever aligns them is not magnetism. The sixth is the control: lithium holmium fluoride is a magnet whose ordering really is dipolar, and its two temperatures agree.

What holds a magnet together is not magnetism

Two neighbouring moments in iron interact magnetically with an energy worth a fifth of a kelvin, and iron keeps its order to 1,043 kelvin. Whatever aligns them is five thousand times stronger than the only force they exert on one another — and it is electrostatic, with the exclusion principle deciding which of two spatial arrangements two electrons may use.

electromagnetism · Magnetisation Two energies with opposite slopes, and the width between them. The energy per unit area of a domain wall in iron, against the width the wall is assumed to have, split into the two terms that decide it. The exchange term falls as one over the width, because a reversal spread over more atoms turns through a smaller angle between each neighbouring pair. The anisotropy term rises in proportion to the width, because every atom inside the wall points away from an easy direction and pays for it. The sum has a least value, found here by scanning four hundred thousand widths: 92.9 nanometres and 4.46 millijoules per square metre. Neither constant is a dimension of the sample, so neither is the width: it is the first length in magnetism that belongs to the material. The assumed profile turns at a uniform rate, which is not the cheapest way to turn, so this width is 41 per cent above the conventional πδ of the exact profile, and this energy 11 per cent above the exact 4√(AK). A trial function can only ever overestimate, and eleven per cent is how much this one costs.

The first length that belongs to the substance

Every length in magnetism so far has been a length of the sample — a demagnetising factor is a shape, an avalanche cutoff is a sample's own restoring field. A domain wall's width is not. It is √(A/K), made of two material constants and nothing else, and across seven ordinary magnets it runs from two and a half nanometres to nine hundred.

electromagnetism · Magnetisation

Named alongside it

The objects these essays reach for when they reach for this one.

FerromagnetismMagnetisationPauli exclusionSingletAntisymmetryBosonCoercivityCovalent bondCurie temperatureDemagnetising fieldDipole dipole interactionDomain wall

All concepts