Concept

Uncertainty principle — where it appears

The bound on how sharply a position and a momentum can both be defined, which is a property of waves rather than of measurement. It is the same width relation any function has with its Fourier transform, so a short pulse of light is broad in frequency for exactly the reason a localised electron is broad in momentum.

Named by 10 essays across 2 fields — each of them below, with the objects they name alongside it.

A packet, and the wavenumbers it is made of. Above: a wave packet built by adding a continuum of plane waves centred on wavenumber 12 with a spread of 1.6. Below: the weight given to each wavenumber. The packet's width, measured as the standard deviation of its probability, is 0.442; the spread of wavenumbers is 1.131; their product is 0.500, which is a half and cannot be less. Narrowing one bracket widens the other by exactly as much. Nothing quantum has been used to draw either panel.

Sharpness has to be paid for

A wave with one exact wavelength has no beginning and no end. Making it short requires adding wavelengths, and the two widths trade against each other exactly — which is a fact about waves, with Planck's constant added only to convert the units.

quantum · Uncertainty
Two costs, and the width that balances them. The energy of a particle in a harmonic well against how tightly its wavefunction is squeezed, in units of ħω and of the width that minimises the total. Two terms compete. Squeezing the particle into a smaller region raises its kinetic energy, because the uncertainty relation makes a narrow position spread a wide momentum spread and momentum is squared in the energy; that term rises as the inverse square of the width and goes to infinity as the particle is localised. Letting it spread out raises its potential energy, since the well gets steeper away from the bottom; that term rises as the square of the width. The sum has a minimum at a width of 1.0000 in these units, where the total is 0.5000 ħω and the two terms are equal at a quarter each. That number is exactly the true ground-state energy of a quantum harmonic oscillator, obtained here with nothing but the uncertainty relation and a minimisation. What the figure shows and the formula does not is why there is a floor at all: it is not that the particle happens to keep moving, but that every way of stopping it costs more than it saves.

The motion that cannot be stopped

A particle in a well cannot sit at the bottom of it. Squeezing it into a smaller region costs kinetic energy faster than it saves potential energy, so there is a width that minimises the total — and the minimum is not zero. Helium never freezes because of it.

quantum · Uncertainty
Flat, then exponential, then a power law. Survival probability against time in lifetimes, both logarithmic, for a resonance 20 linewidths above the bottom of its band and 400 below the top. The straight dashed line is exp(−Γt), and the computed curve sits on it through the middle — a fitted rate of 0.9998 per lifetime between one and eight — and leaves it at both ends. Below 1.57e-2 lifetimes the curve is flat, falling as (t/τ_z)² with τ_z = 0.1253 lifetimes; beyond 22.6 lifetimes it is an inverse square, which any exponential eventually loses to. Both departures are forced: the head by the state being normalisable and the tail by the band having a bottom.

The exponential that is only true in the middle

A decay law is not an assumption about nuclei; it is the Fourier transform of an energy distribution. Do that transform honestly and the exponential fails at both ends — flat at the start, because the state is normalisable, and an inverse square at the end, because no system has states of arbitrarily negative energy. Neither departure is a correction that could be made small.

quantum · Decay
Which pairs have anything between them. The commutator of every pair of 4 observables of a spin-½, multiplied out in 2×2 complex arithmetic and shown by the size of AB − BA. The diagonal is exactly zero: an observable commutes with itself, which is why measuring the same thing twice gives the same answer. S², the total angular momentum, is a multiple of the identity here and so commutes with everything — its row and its column are zero, and a spin can have a definite total angular momentum and a definite component at the same time. The largest entry is 0.7071 in units of ħ². Sz: 0.000 with Sz, 0.707 with Sx, 0.707 with Sy, 0.000 with S²; Sx: 0.707 with Sz, 0.000 with Sx, 0.707 with Sy, 0.000 with S²; Sy: 0.707 with Sz, 0.707 with Sx, 0.000 with Sy, 0.000 with S²; S²: 0.000 with Sz, 0.000 with Sx, 0.000 with Sy, 0.000 with S². A zero cell is a promise that the two quantities can be sharp together; a non-zero one is an obstruction whose size sets how badly they cannot.

The questions that can be asked together

Two quantities can have definite values at once exactly when their operators commute. That is a piece of arithmetic about matrices, and everything the uncertainty principle forbids follows from it — including the fact that most of the time it forbids nothing at all.

quantum · Uncertainty
A bundle that swings and never spreads. A Gaussian of the ground state's own width, released at rest from x = 3 in a harmonic well and propagated on a grid by split-step Fourier, drawn at 0 of a period, 0.25 of a period, 0.5 of a period. The packet slides from side to side and its shape does not change: over 2.2 full periods the width moves by 6.6e-5 per cent, and its centre tracks x₀cos t to 8.6e-6. Every other initial width breathes. This one is the displaced ground state, and it is the closest a quantum state comes to being a classical oscillator — a definite thing at a definite place, moving on the classical trajectory, staying the size it was.

The state that swings like a pendulum

Most quantum states of an oscillator look nothing like a swinging weight. One family does: it follows the classical trajectory exactly, never spreads, and sits at the uncertainty minimum for ever — and it is the state a laser and a driven circuit actually produce.

quantum · Correspondence
Why it stops falling in. The energy of an electron confined to a region of radius r around a nucleus, as the sum of two terms with different powers: a confinement energy ħ²/2mr² that rises without limit as the region shrinks, and a Coulomb attraction −Ze²/4πε₀r that falls. At Z = 1 the sum is least at 52.92 pm, where it is -13.61 eV. Both numbers are found by searching the drawn curve and both agree with the Bohr radius over Z and minus Z² Rydbergs to a part in a million. Nothing was quantised to get them. The only quantum input is that confining an electron to a region costs kinetic energy, which is the uncertainty relation and nothing more.

Why an atom is the size it is

A tenth of a nanometre is not a measured constant of nature but the outcome of a competition: confining an electron costs kinetic energy, and the nucleus pays for confinement with attraction. Minimising the sum gives the number, and changing the masses moves it by four orders of magnitude.

quantum · Atomic structure
Two terms, and the distance neither can beat. The smallest distance a probe of a given momentum can resolve, as the sum of two terms. The falling one is the uncertainty relation: more momentum, shorter wavelength, finer resolution. The rising one is gravity: the probe's own energy curves the region it is probing, and past a point it makes a horizon larger than the thing being looked at. With the gravitational term at 1× the Planck area, the least resolvable distance is 2.286e-35 m — each located by scanning the drawn curve over four hundred thousand momenta rather than by substituting into a formula. There is no momentum at which the resolution is better than that, so the ordinary procedure for measuring a distance has a floor, and the floor is the Planck length up to a factor of order one.

The length no experiment can resolve

Measuring a small distance needs a short wavelength, a short wavelength needs a large energy, and a large energy in a small region makes a horizon. Past a point, pushing harder makes the probe bigger — and the distance where that turns round is the Planck length.

astrophysics · Planck scale
The floor a state's survival cannot go below. The probability that a quantum state is still found in its initial state, against time measured as its energy spread times time over ħ, for four states with the same spread. The shaded region under cos²(ΔE t/ħ) is forbidden by Mandelstam and Tamm's theorem, and every curve — each a sum of phases over the state's energies — stays out of it. Two equally weighted levels run along its edge and reach an orthogonal state at exactly π/2, the fastest any state with this spread can. The same two levels driven off resonance, with the same spread, never get further than a survival of 0.500. Three equally spaced levels become orthogonal only at 1.7101, 1.0887 times the limit, and a coherent state never does, bottoming out at 0.0183. A spread of energy is permission to change, not an obligation.

The fastest a state can stop being itself

Time has no operator, so the energy–time relation cannot be the commutator inequality it resembles. What stands in its place is sharper: a state whose energy is spread by ΔE cannot become a different, orthogonal state in less than πħ/2ΔE, and cannot do it faster than its mean energy above the ground state allows either. Two equally weighted levels reach both limits exactly. Nothing else does.

quantum · Uncertainty
No beam is narrow enough and wide enough at once. Three lengths at the far end of a Stern-Gerlach magnet 10 centimetres long with a gradient of 1000 tesla a metre, against the width of the beam entering it, for an electron at 100 electronvolts. The spin splitting is a horizontal line at 2.9e-6 metres: it does not depend on the beam's width. The Lorentz blurring rises in proportion to the width, because the field a particle sees depends on where in the beam it is, and the divergence-free condition ties a gradient in one component to a gradient in another. It overtakes the splitting at 1.0e-9 metres. Narrower than that and diffraction has already spread the beam by 3.9e-3 metres, which is larger still. There is no width at which the splitting is the largest of the three, and the magnet's length and gradient cancel out of the comparison entirely — so no magnet helps.

The experiment that defines spin and cannot be done on it

A Stern–Gerlach magnet separates magnetic moments and is how spin was discovered. It cannot be made to work on a free electron, and the obstruction is not the apparatus: the field gradient that splits the beam also deflects the charge by an amount that varies across it, and the ratio of the splitting to that blurring comes out as the de Broglie wavelength over the beam width — with the magnet's length and gradient cancelling exactly.

quantum · Spin
Four states of light, each with the same area of noise. The field of a single mode of light drawn as a point in a plane whose two axes are its two quadratures — the parts of the wave in step with a reference and a quarter-cycle out of step. The distance from the centre is the amplitude and the angle is the phase. Each state is a cloud of 400 sampled measurements with its two-standard-deviation outline, in units where the vacuum's noise is one in every direction. The vacuum is a round cloud at the centre. Steady laser light is the same round cloud moved away from the centre. Light squeezed by 4 dB is an ellipse of the same area: narrower than the vacuum by a factor of 0.63 in one direction and wider by 1.58 in the other. Pointed along the direction from the centre it is quiet in amplitude; pointed across it, quiet in phase. The sampled spreads were checked against each state's widths.

The noise pushed below the floor

A perfectly steady laser beam still flickers, by an amount set by the vacuum itself, and for most of the twentieth century that flicker was treated as the floor of any optical measurement. It is a floor only for one shape of noise. Light can be made quieter than the vacuum in one property by being made louder in another — and the price, the fragility and the use of that trade are all visible in how the noise is shaped, which is why the world's gravitational-wave detectors now run on it.

quantum · Photon

Named alongside it

The objects these essays reach for when they reach for this one.

MeasurementSuperpositionZero-point energyQuantum stateWave packetBandwidthDe broglie wavelengthDiffractionFourier transformGround stateHarmonic oscillatorObservable

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