Illustrated Physics
physics, drawn
Concept

Thixotropy — where it appears

The property of a material whose viscosity depends on its history, falling while it is sheared and recovering while it rests. It arises from a structure that builds at rest and breaks in flow, as in clays, paints and drilling muds.

Named by 3 essays across one field — each of them below, with the objects they name alongside it.

The thickness a paste can hold on a slope. The greatest thickness a yield-stress fluid can rest at without flowing, against the angle of the surface it is resting on, on a logarithmic vertical axis, for four materials. A layer of thickness h puts a shear stress ρgh sin α on its own base; it stays put while that is below the yield stress and flows when it is not, so the critical thickness is τ_y divided by ρg sin α and it depends on nothing else — not on the viscosity, not on how long it is left, not on how it was put there. On a vertical wall the numbers are 1.4 mm of ketchup, 9.2 mm of mayonnaise, 15.7 mm of toothpaste, 15.1 mm of basaltic lava, which is why toothpaste stays on a brush and ketchup does not stay on a plate held up. Read the other way it is a measurement: a lava flow that came to rest 3 centimetres thick on a 30° slope had a yield stress of about 400 pascals, and that is how the rheology of a flow nobody was standing next to is recovered from its shape a thousand years later. The model stops where the layer is thin enough for surface tension to matter and where the material's yield stress depends on how long it has been left alone, which for most of these it does.

The paste that holds up its own hill

Toothpaste stands on a brush and ketchup does not stand on a plate, and the difference is a single number with the units of a pressure. Below it a material does not flow slowly — it does not flow. That threshold turns a rheological property into a length, and the length is why a lava flow's thickness says what the lava was made of.

fluids · Rheology The same paste stopping or running, according to the push. A thixotropic paste, sheared hard and then held under a constant stress: its viscosity against time, on a logarithmic axis, for stresses of 1.5, 1.8, 2.0, 2.4 Pa. Its structure builds at rest and is broken by flow, and the model's critical stress is 1.89 Pa. Below it the paste's viscosity climbs without limit: it slows, its structure builds faster than the slowing flow can break it, and it creeps to a stop, its viscosity growing in the end as the 1.5 power of time. Above it the viscosity falls: it speeds up, breaks its structure faster, and runs at a steady rate. After a thousand seconds the viscosities stand at 514.1, 238.3, 2.0, 1.5 Pa s: stresses a few per cent apart have gone opposite ways — a bifurcation, not a smooth change — and the paste hesitates longest when the stress is closest to the critical value.

The paste that forgets it was stirred

A jar of clay slurry left on a shelf sets like a jelly; shaken, it pours. That is thixotropy, and the tempting description — its viscosity falls when it is stirred — misses what makes it strange. A thixotropic paste has no viscosity at a given rate of stirring until it has been told how long it has been stirring, and under a steady push it cannot settle on a slow flow at all. Push slightly less than a critical stress and it creeps to a halt; push slightly more and it runs. Between the two there is nothing, and a paste made to flow slowly splits into a layer that flows and a layer that does not.

fluids · Rheology The force to pull a foot out of packed sand. The suction that resists pulling a foot (a sole of 250 cm², 10 cm long) straight up out of sand, as water is drawn through the sand into the space the foot leaves — Darcy's law with a Kozeny–Carman permeability — against the pulling speed, on logarithmic axes, for compacted sand (fraction 0.6) of three grain sizes and for loose sand (0.41) of 0.1 mm; the dotted line is a 70 kg person's weight. The force is proportional to the speed and inversely to the square of the grain size. Pulled at a centimetre a second from compacted 0.1 mm sand, a foot resists with 2.5 kN, 4 times the person's weight; the speed at which the suction equals that weight is 2.71 mm/s. In the loose sand before it compacted, the same pull would need 15 per cent of the force; with clay filling the pores of the compacted sand, as in natural quicksand, a thousand times more, and the speed a body's weight can pull at falls to microns a second.

The sand that lets a body in and will not let it out

Quicksand cannot swallow anyone: liquefied, it is nearly twice as dense as water, and a person in it floats with their chest clear. What makes it dangerous is the opposite asymmetry. Going in is easy, because a step breaks the gel holding the grains apart and the sand turns liquid. Coming out is hard, because the sand settles and packs around whatever sank, and a trapped foot can only rise as fast as water can seep through the packed grains to fill the space it leaves. Pulling harder barely helps; letting water in does.

fluids · Rheology

Named alongside it

The objects these essays reach for when they reach for this one.

Yield stressViscosityApparent viscosityArchimedes principleBifurcationBingham plasticBuoyancyConstitutive lawLiquefactionNon-newtonian fluidPermeabilityPlug flow

All concepts