Illustrated Physics
physics, drawn
Concept

Thermal conductivity — where it appears

The constant relating the heat crossing a material to the temperature gradient driving it. In a solid two things carry the heat — the charge carriers and the lattice vibrations — and only the second can be reduced without ruining the electrical conductivity.

Named by 7 essays across 2 fields — each of them below, with the objects they name alongside it.

The average position of something that is only shaking. The mean displacement of an oscillator against temperature, taken as a Boltzmann average over each well rather than from any expansion of it, with the temperature measured against each well's own depth so that unlike bonds can share an axis. A symmetric well gives exactly zero at every temperature — heating a harmonic solid makes it vibrate harder and does not make it larger. The others drift outward, because the outward side is the shallower one, and the measured slopes are a pendulum 0.000, a chemical bond 0.766, a pair of atoms 0.150. Thermal expansion is not a property a spring has; it is one a spring lacks.

Why heating a perfect spring changes nothing

A harmonic solid vibrates harder when heated and does not get any longer. Thermal expansion lives entirely in the term that the harmonic approximation throws away — and so does the fact that a solid conducts heat at a finite rate, which is the same discarded term doing a second job nobody would have connected to the first.

thermodynamics · Harmonic approximation One dimensionless group between an engine and Carnot. The efficiency of a thermoelectric couple against the temperature of its hot side, with the cold side at 300 kelvin, for 4 values of the figure of merit, and the Carnot ceiling drawn above them. The expression has exactly one material quantity in it — the dimensionless group formed from the Seebeck coefficient squared, the electrical conductivity, the temperature and the thermal conductivity — and everything else is the two temperatures. At 600 kelvin, a figure of merit of one gives 10.8 per cent against a Carnot ceiling of 50.0, and a figure of merit of four gives 22.6. The approach to the ceiling is slow: every doubling of the group buys less than the last, so the difference between a good material and a perfect one is smaller than the difference between a poor material and a good one.

An engine with one number in it

A thermoelectric couple has no moving part and no working fluid, and its efficiency is the Carnot value multiplied by a factor containing exactly one dimensionless group of material properties. Sixty years of effort have moved that group from about one to about two, and the reason it is hard is that its three ingredients are not independent: raising the conductivity ruins the coefficient it is squared against, and the only lever that is really free is the heat the lattice carries.

thermodynamics · Heat engines The temperature through growing lake ice. Temperature against depth below the ice surface in a lake under air 10 K below freezing, after 1, 4 and 16 days, from Stefan's law with the ice's top held at the air's temperature. The ice is 11.1, 22.3, 44.6 cm thick; within it the temperature rises in a straight line from −10 °C at the top to 0 °C at the bottom, and below it the water is at 0 °C throughout. Ice forms only at the bottom, where water meets ice at the freezing point, and the latent heat it releases there has to be carried up through all the ice above by conduction. The straight lines get shallower as the ice thickens: the same temperature difference drives heat across a longer path, so less heat escapes and the ice grows more slowly. Sixteen times as long gives four times the thickness.

The ice that grows more slowly the thicker it gets

A lake under air ten degrees below freezing grows eleven centimetres of ice on the first day and only another eighteen in the following six. The ice forms at its underside, and every gram of it releases latent heat that must be carried up through the ice already there before more can form: the ice is its own insulation. The thickness therefore grows as the square root of time, and the rule, Stefan's, depends on temperature and time only through their product — the freezing degree-days that lake-ice forecasters count. A few centimetres of snow on top slows it more than any amount of cold speeds it up.

thermodynamics · Diffusion How well a diamond-like crystal conducts heat, from 1 K to 1000 K. The thermal conductivity of a model crystal with diamond's sound speed and Debye temperature, from kinetic theory applied to its phonons, against temperature on logarithmic axes: natural carbon in a sample 1 mm across, isotopically enriched carbon, and natural carbon in a sample 0.1 mm across; copper's room-temperature 400 W/m K is marked for comparison. The model is calibrated to natural diamond's 2,200 W/m K at room temperature. At low temperature the conductivity rises as the cube of the temperature, limited by the sample's walls; at high temperature it falls as umklapp collisions shorten the phonons' paths. Between, it peaks: 3.7·10⁴ W/m K at 100 K for the natural crystal; 7.8·10⁴ W/m K at 94 K for the enriched crystal; 1.2·10⁴ W/m K at 126 K for the thin natural crystal. The model gets the shape — the rise as the cube of the temperature, a peak near 100 K, the fall — but overestimates the heights, because it leaves out the phonon collisions that conserve momentum and every defect but isotopes; measured enriched diamond peaks near 4 × 10⁴ W/m K. An insulator with no free electrons still conducts heat five times better than copper at room temperature.

The gas of sound that carries a diamond's heat

Diamond has no free electrons and conducts heat five times better than copper. What carries the heat is a gas — not of molecules but of quantised sound waves, phonons — and the kinetic theory that gives the conductivity of air gives the conductivity of a crystal with the same formula: a third of heat capacity times speed times mean free path. The gas is strange in two ways. At low temperature its particles cross the whole crystal without meeting anything, so the conductivity depends on how big the sample is. And at room temperature one atom in a hundred being a neutron heavier is enough to scatter its fastest-oscillating members.

thermodynamics · Kinetic theory A pond that is hottest at the bottom and does not turn over. Temperature, salt and density against depth in a salt-gradient solar pond: a fresh upper layer 0.3 m deep at 25 °C, a gradient layer 1.2 m thick in which the salt rises from 2 to 20 per cent and the temperature from 25 to 80 °C, and a storage layer of hot brine 2 m deep (shaded bands are the two mixed layers). The density rises steadily downward, from 1011 to 1122 kg/m³, so the hottest water is also the heaviest and stays at the bottom. The dashed line is the same temperatures with no added salt: the bottom water would then be 25 kg/m³ lighter than the top, and the pond would overturn.

The pond that is hottest at the bottom

Water heated from below rises, which is why a pond in the sun is never much warmer than the air: the heat is carried to the surface and lost there. Put a metre of salt gradient in the way and the hot water at the bottom is also the heaviest, cannot rise, and keeps its heat, behind an insulating layer that sunlight passes straight through. Ponds built this way reach eighty degrees under an ordinary sky. The salt does not collect any extra light. What it buys is temperature.

fluids · Stratification Insulating a thin wire makes it lose more heat. The heat lost per metre from a wire 2 mm across held 40 K above the air, against the outer radius of the PVC insulation round it (k = 0.19 W/m K), with the surface losing 10 W/m²K to still air by convection and radiation, on a logarithmic radius axis; dashed, the bare wire. The first layers of insulation increase the loss, from 2.51 to a maximum of 12.11 W/m at an outer radius of 19 mm — the critical radius k/h — because they add surface faster than they add resistance. Beyond the critical radius the loss falls again, but so slowly — the resistance of the insulation grows only as the logarithm of its radius — that it does not get back down to the bare wire's until the PVC is 178 km thick. Any sheath a cable could carry makes it lose more heat, not less.

The insulation that makes a wire lose more heat

Wrap a hot water pipe in glass wool and it loses less heat. Wrap a thin electrical wire in PVC and it loses more — four times more, at the best thickness — and runs cooler for it. The insulation adds a resistance to heat flowing through it, but it also adds surface for the heat to leave from, and around a thin enough cylinder the surface wins. The crossover is a radius, k/h, set by the insulation and the air; below it, more insulation means more heat lost, and a small enough ball cannot be insulated by anything wrapped round it.

thermodynamics · Diffusion The pipe that out-conducts any solid. The temperature difference needed to carry 30 W along a rod 300 mm long and 6 mm across, on a logarithmic scale: for solid aluminium 1343 K, for copper 796 K, for diamond, the best conductor of heat at room temperature, 159 K; and for a water heat pipe of the same size 0.8 K, almost all of it across the thin wet wicks where the heat goes in and comes out. Solid metal could not do it at all: the hot end of the copper rod would have to be hundreds of degrees above the cold. The heat pipe carries the heat as latent heat in moving vapour, and the vapour needs almost no temperature difference to flow. As an effective conductivity that is 1000 times copper's — which is why every laptop and many satellites move their heat in pipes rather than through metal.

The pipe that carries heat as vapour

A copper rod six millimetres across and thirty centimetres long, asked to carry thirty watts from a laptop's processor to its fan, would need its hot end eight hundred degrees above its cold end. The flattened copper tube that actually does the job manages it with less than a degree. It is a heat pipe: sealed, emptied of air, and holding a few drops of water and their vapour. The water boils at the hot end, the vapour rushes to the cold end and condenses, and a wick of sintered copper powder drags the liquid back by capillarity. The heat goes as latent heat, and vapour needs almost no temperature difference to flow — which makes the pipe a thousand times better than copper, as long as its wick can keep up.

thermodynamics · Phase change

Named alongside it

The objects these essays reach for when they reach for this one.

PhononConvectionDiffusionLatent heatAbsorptionAnharmonicityApproximationThe Boltzmann factorBuoyancyCapillary pressureCarnot efficiencyClausius clapeyron

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