Concept

Selection rule — where it appears

A rule forbidding a transition between two quantum states unless their quantum numbers differ in a particular way. It usually expresses a conserved quantity such as angular momentum or parity, and a forbidden transition is not impossible but very slow, which is why some excited states live long.

Named by 2 essays across one field — each of them below, with the objects they name alongside it.

Each unit of angular momentum costs a factor of tens of thousands. Weisskopf's estimates of the half-life of a gamma-ray transition in a nucleus of mass number 100, against the photon's energy, for electric multipoles of order 1 to 5 — the photon carrying away 1 to 5 units of angular momentum. At 1 MeV the estimates are 10⁻¹⁵ s for E1, 10⁻¹¹ s for E2, 2.0 µs for E3, 292.5 ms for E4, 17.3 h for E5. Each extra unit multiplies the half-life at 1 MeV by between 60,000 and 210,000: about a thousand of that is (λ/2πR)², the square of the photon's reduced wavelength over the nucleus's radius, which grows as the energy falls, and the rest is a numerical factor that grows with the order. A transition that must carry away five units at 100 keV has an estimated half-life longer than the age of the universe; the same energy carried off with one unit takes less than a nanosecond.

The spin a photon has to carry away

An excited nucleus sheds its energy as a gamma ray in a millionth of a millionth of a nanosecond — or in minutes, or centuries, or never within the age of the universe. The energy available hardly matters. What matters is how much angular momentum the photon must carry off, because a source much smaller than its wavelength is very bad at launching a wave that twists, and each extra unit of twist costs a factor of tens of thousands in time. Selection rules are usually stated as what cannot happen; they are really a price list, and it spans forty decades.

quantum · Decay $Two lifetimes a thousand times apart. The fraction of positronium atoms surviving in the ground state against time since formation, on a logarithmic time axis, for the spin singlet, para-positronium (red), and the spin triplet, ortho-positronium (blue), in vacuum. Para lives 125.1 ps and ortho 142.1 ns, a ratio of 1135. The lowest-order formulas give 124.5 ps, from α⁵mc²/2ħ, and 138.7 ns, from 2(π² − 9)/9π · α⁶mc²/ħ; the ratio is almost entirely one extra power of the fine-structure constant, the price of a third photon.$

The atom with no nucleus

An electron and a positron can bind into an atom whose structure is hydrogen's with every level halved and every size doubled, because neither partner sits still at the centre. The atom then destroys itself, and how fast depends on one symmetry. With the two spins opposed it vanishes in 125 picoseconds as two photons; with them aligned it must make three, and lives 142 nanoseconds — over a thousand times longer — for no reason but that a rule about charge conjugation forbids the shorter route.

quantum · Atomic structure

Named alongside it

The objects these essays reach for when they reach for this one.

Angular momentum Annihilation Antimatter Charge conjugation Fine structure constant Forbidden transition Gamma-ray Half-life Multipole expansion Nuclear isomer Positronium Radioactive decay

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