Illustrated Physics
physics, drawn
Concept

Radioactive decay — where it appears

The spontaneous transformation of a nucleus, at a rate that is constant in time and very nearly independent of everything outside it. The exceptions are the processes that sample the electron density at the nucleus, where chemistry moves the rate by a per cent and stripping the atom entirely moves it by a factor of a billion.

Named by 4 essays across one field — each of them below, with the objects they name alongside it.

Decay, and the ensemble it is a property of. 400 nuclei followed for 4 half-lives. The smooth curve is the exponential; the stepped traces are 3 independent runs in which every nucleus was given its own decay time and told nothing about the others. The number surviving halves at each dashed line — 200, 100, 50, 25 — and it halves again over the next interval regardless of how long the sample has already been sitting there, which is the property no ordinary clock has. The traces wander further from the curve as the numbers get small: at the end only about 25 are left and the scatter is a visible fraction of that.

A nucleus with no clock

A half-life is a precise number and no individual nucleus has one. Each has the same chance of decaying in the next second as it had on the day it formed, and the exponential curve is a property of the population rather than of any member of it.

quantum · Decay Everything in the chain decaying at the parent's rate. The activity of each member of ²³⁸U → ²³⁴Th → ²³⁴Pa, relative to the parent's, against time in days. The parent's half-life is far the longest, so its activity is effectively constant over the range drawn while each daughter rises to meet it. Once they have, every member of the chain is decaying at exactly the same rate — secular equilibrium, checked here to one per cent off the integrated solution — because each is being made as fast as it is disappearing. The amounts are not equal at all: the abundance of each member sits in the ratio of its half-life to the parent's, which for radium in uranium is one part in three million and is why radium had to be extracted from tonnes of ore.

The chain that runs at its slowest member's rate

Put decays in series and something happens that no single decay does. The population settles where every member is being made exactly as fast as it disappears, so every activity in the chain is equal — while the amounts differ by twelve orders of magnitude, in the ratio of the half-lives. A gram of uranium contains a third of a microgram of radium and two hundred million million million atoms fewer of radon, and both numbers are read off a list of half-lives.

quantum · Decay The half-life that depends on the electrons. Half-lives of 3 nuclides as neutral atoms and as bare nuclei, measured at a heavy-ion storage ring where fully stripped ions can be kept circulating for months. The changes are not corrections. ¹⁸⁷Re goes from 41.6 billion years to 32.9 — a factor of 1.26 billion — because a beta decay whose available energy is only 2.5 keV cannot put an electron into the continuum but can put one into an empty K orbital, and stripping the atom opens that channel. ¹⁶³Dy is stable as an atom and decays in 47 days as a bare nucleus, for the same reason. The rate is a property of the nucleus and of what surrounds it, not of the nucleus alone.

The half-life that chemistry can change

A nucleus has no clock, the usual account goes, and nothing outside it touches the rate. That is very nearly true and it is not exactly true. Electron capture takes an electron from the nucleus's own position, so its rate is proportional to how many electrons are there — which is chemistry, worth a per cent. And a nucleus stripped of every electron can gain a decay channel it did not have: rhenium-187 goes from forty-two billion years to thirty-three.

quantum · Decay Each unit of angular momentum costs a factor of tens of thousands. Weisskopf's estimates of the half-life of a gamma-ray transition in a nucleus of mass number 100, against the photon's energy, for electric multipoles of order 1 to 5 — the photon carrying away 1 to 5 units of angular momentum. At 1 MeV the estimates are 10⁻¹⁵ s for E1, 10⁻¹¹ s for E2, 2.0 µs for E3, 292.5 ms for E4, 17.3 h for E5. Each extra unit multiplies the half-life at 1 MeV by between 60,000 and 210,000: about a thousand of that is (λ/2πR)², the square of the photon's reduced wavelength over the nucleus's radius, which grows as the energy falls, and the rest is a numerical factor that grows with the order. A transition that must carry away five units at 100 keV has an estimated half-life longer than the age of the universe; the same energy carried off with one unit takes less than a nanosecond.

The spin a photon has to carry away

An excited nucleus sheds its energy as a gamma ray in a millionth of a millionth of a nanosecond — or in minutes, or centuries, or never within the age of the universe. The energy available hardly matters. What matters is how much angular momentum the photon must carry off, because a source much smaller than its wavelength is very bad at launching a wave that twists, and each extra unit of twist costs a factor of tens of thousands in time. Selection rules are usually stated as what cannot happen; they are really a price list, and it spans forty decades.

quantum · Decay

Named alongside it

The objects these essays reach for when they reach for this one.

Half-lifeDecayProbability densityAbundanceActivityAngular momentumAtomic structureBeta decayConservation lawsDecay chainDecay constantElectron capture

All concepts