Concept

Relativistic gas — where it appears

A gas whose particles move at nearly the speed of light, so that a particle of energy E carries momentum E/c rather than the square root of 2mE. Its pressure is a third of its energy density rather than two thirds, and its adiabatic index is 4/3, which is what limits the mass of a white dwarf and of a star.

Named by 4 essays across 2 fields — each of them below, with the objects they name alongside it.

What a coordinate is worth, by the shape of its energy. The mean energy stored in one coordinate, in units of kT, against the power with which that coordinate enters the energy. The curve is 1/n and the points are the same average obtained by integrating the Boltzmann weight numerically, agreeing to 3.3e-7 per cent at worst. an energy going as |x|^1 holds 1.0000 kT; an energy going as |x|^1.5 holds 0.6667 kT; an energy going as |x|^2 holds 0.5000 kT; an energy going as |x|^3 holds 0.3333 kT; an energy going as |x|^4 holds 0.2500 kT; an energy going as |x|^6 holds 0.1667 kT. The familiar half a kT is the case n = 2 and nothing more general than that: a coordinate whose energy is linear in it — the momentum of an ultrarelativistic particle, or a field with no restoring force but a constant tension — carries a whole kT, and one confined by a very steep wall carries almost nothing. Equipartition is a theorem about quadratic terms, and calling it a theorem about degrees of freedom is the substitution that makes it fail.

The share that is not half a kT

Equipartition is quoted as half a kT for every degree of freedom, and it is nothing of the kind. It is half a kT for every *quadratic* term. A coordinate whose energy is linear in it carries a whole kT, and a gas hot enough that its particles' energy is pc rather than p²/2m therefore holds twice what the counting says — which drops its ratio of specific heats to four thirds and puts a star on the edge of being able to hold itself up.

thermodynamics · Equipartition
Energy, pressure and entropy of a gas nobody counted. The energy density, pressure and entropy density of blackbody radiation against temperature, on logarithmic axes, together with the pressure a monatomic gas of the same energy density would have. Every curve is a power of the temperature — the fourth for energy and pressure, the third for entropy — because the only length in the problem is the thermal wavelength and the only energy is kT. The pressure is exactly a third of the energy density, where an ordinary gas's is two thirds, a factor of 2: a photon carries momentum E/c and a slow molecule carries √(2mE), and that difference is the whole of it. Some values: at room temperature the radiation pressure is 1.86e-6 pascals, which is a ten thousand millionth of an atmosphere; at 1e+7 kelvin it is 2.52e+12, which is where radiation rather than matter holds a star up.

The gas that nobody counted

A box of gas holds however many molecules were put in it. A box of radiation holds however many photons the temperature says, because the walls make and destroy them until the free energy is least — and one dropped assumption changes every result. The pressure becomes a third of the energy density instead of two thirds, the entropy goes as the cube of the temperature, and the adiabatic index comes out at exactly four thirds.

thermodynamics · Blackbody
The stiffness a two-solar-mass star demands. The heaviest neutron star the model matter can support, in solar masses, against the constant square of the sound speed assumed above 300 MeV/fm³, as a fraction of c². At the conformal value, one-third (dashed), it is 1.92 solar masses; the heaviest star the model can make rises to 2.97 at the causal limit. To hold up the 2.08 solar masses of J0740+6620 (shaded) the square of the sound speed must exceed 0.394 of c² somewhere above that density — above the conformal one-third, by this model's reckoning. The conclusion depends on the model's low-density part, which the next figure varies.

The sound speed a neutron star needs

Heat any gas without limit and the speed of sound in it climbs towards a ceiling: not the speed of light, but light's speed divided by the square root of three, the sound speed of a gas of massless particles. For decades it was a natural guess that no matter could beat that ceiling, since the densest matter ought to behave like a gas of free quarks. Neutron stars say otherwise. A star of twice the Sun's mass, packed into a ball twenty-five kilometres across, can only be held up if its core is stiffer than the ceiling allows — unless nuclear physics fails at densities where it is believed to hold. Somewhere inside the heaviest neutron stars, sound almost certainly travels faster than it can in any free gas.

relativity · Relativistic thermodynamics
What the heat shares out, and what it does not. Two averages per particle in the Maxwell–Jüttner gas, in units of kT, against kT/mc² on a logarithmic scale: the momentum times the velocity, p·v, whose average over the three directions gives the pressure, and the kinetic energy. The first is 3 at every temperature, computed here by averaging over the distribution and equal to 3 to four decimal places across the whole figure — so the pressure is exactly nkT, the ideal gas law, from a gas colder than a star to one hotter than the early universe. The kinetic energy is not shared out the same way. It is 1.506 kT when the gas is cold, Boltzmann's 3/2, and rises to 3.00 kT when it is ultra-relativistic, because for a fast particle the energy is p·c and p·v, which is what equipartition hands out, is the whole of it rather than twice it.

The gas law relativity leaves exact

Heat a gas until its particles move at nearly the speed of light and almost everything Maxwell and Boltzmann said about it changes. The speeds pile up just below c instead of spreading out. The energy per particle climbs from three halves of kT to three. The heat capacity doubles, and the ratio of heat capacities falls from five-thirds to four-thirds. One law survives untouched: the pressure is still exactly nkT, at a thousand degrees or a hundred thousand million. The reason it survives is the reason the others change. What heat hands out equally to every way of moving is not energy but momentum times velocity, and for slow particles those happen to differ only by a factor of two.

relativity · Relativistic thermodynamics

Named alongside it

The objects these essays reach for when they reach for this one.

Adiabatic indexEquation of stateEquipartitionHeat capacityBlackbodyThe Boltzmann factorCausalityChemical potentialConformal symmetryCosmic microwave backgroundDegrees of freedomEnthalpy

All concepts