Illustrated Physics
physics, drawn
Concept

Phase separation — where it appears

The splitting of a uniform mixture into two coexisting phases of different composition, because mixing would raise the free energy. Below a critical temperature the compositions on either side of a coexistence curve are stable, and the mixture divides between them in proportions fixed by the lever rule.

Named by 2 essays across one field — each of them below, with the objects they name alongside it.

Fifty-nine millivolts for every factor of ten. The voltage that holds a singly charged ion at one concentration on one side of a boundary and another concentration on the other, in equilibrium, against the ratio of the concentrations on a logarithmic axis: (kT/e) ln(c₁/c₂), from requiring the electrochemical potential to be the same on both sides. At 0 °C, 54.20 mV per decade; at 25 °C, 59.16 mV per decade; at 37 °C, 61.54 mV per decade; at 100 °C, 74.04 mV per decade. The voltage depends on the ratio and the temperature and on nothing about the ion, the solvent or the boundary: it is the entropy of dilution, expressed per unit charge.

The voltage that is a chemical potential

A battery, a nerve cell and a pH meter all turn a difference in chemical potential into a voltage, and the conversion is the same in each: fifty-nine millivolts for every factor of ten in concentration, at room temperature, whatever the ion. The voltage a battery holds as it discharges is the chemical potential of the atoms stored in its electrodes — and a battery whose voltage barely changes is one whose electrode is going through a phase transition.

thermodynamics · Chemical potential Why dissolving beats evaporating near absolute zero. Cooling power against temperature on logarithmic axes, for pumping on liquid helium-4, pumping on liquid helium-3 — both with a pump of 100 litres a second at room temperature — and a dilution refrigerator circulating 100 micromoles of helium-3 a second (the T² law, dashed above 0.1 K where it no longer holds). Evaporative cooling is proportional to the vapour pressure, which collapses as e^(−L/T): helium-4 gives 7·10⁻¹¹ W at 0.3 K, helium-3 10⁻⁴ W at 0.3 K and 2·10⁻²⁴ W at 50 mK. The dilution refrigerator's "vapour" is the dilute phase, whose density of helium-3 stays at 6.6% however cold it gets, so its cooling falls only as T²: 2·10⁻⁵ W at 50 mK. Below about 0.3 K nothing that evaporates can compete, and most experiments that must stay continuously below a tenth of a kelvin — superconducting quantum computers, bolometers for the cosmic microwave background, searches for dark matter — run on dilution.

The mixture that stays mixed at absolute zero

The third law says a mixture's entropy must vanish at absolute zero, so every mixture must either separate completely or order into a compound as it is cooled. Liquid helium-3 dissolved in helium-4 does neither. Below 0.87 kelvin it splits into two liquids, but the one that is mostly helium-4 keeps 6.6 per cent helium-3 however cold it gets — and the third law permits it, because the dissolved atoms are a degenerate Fermi gas with a single ground state and no entropy of mixing to lose. Pushing helium-3 across that boundary absorbs heat the way evaporation does, from a 'vapour' that never thins out. That is the dilution refrigerator, the machine that holds every superconducting quantum computer at ten millikelvin.

thermodynamics · Third law

Named alongside it

The objects these essays reach for when they reach for this one.

BatteryChemical potentialCooling powerDilution refrigeratorElectrochemical potentialEntropy of mixingFermi liquidGibbs free energyHelium-3Kapitza resistanceLattice gasMembrane potential

All concepts