Illustrated Physics
physics, drawn
Concept

Battery — where it appears

A device that stores energy as the free energy of a chemical reaction and delivers it as an electric current. Its electrodes are separated by an electrolyte that passes ions but not electrons, and its voltage is the reaction's free energy per unit charge moved, which is why each chemistry has its own.

Named by 2 essays across 2 fields — each of them below, with the objects they name alongside it.

The only part of the field that can pull. A dielectric slab part-way into a parallel-plate capacitor. Everywhere except at the slab's edge the field is perpendicular to the plates and therefore perpendicular to the direction the slab can move, so it exerts no force along that direction at all: inside the parallel-plate model, which is uniform between the plates and zero outside them, nothing pulls the slab anywhere. The force lives in the bowed lines drawn at the edge, where the field leaks past the end of the dielectric and acquires a component along the plates. Those lines are what the model throws away as a small correction near the boundary, and they are the entire mechanism. The energy method sidesteps the drawing altogether: differentiate the total energy with respect to the insertion and the answer is 1.328e-3 newtons, inward, without ever asking where on the slab the force is applied.

The force that lives where the model is not

A slab of glass held at the mouth of a charged capacitor is pulled in. Inside the parallel-plate model there is no force at all — the field is perpendicular to the slab's motion everywhere — and the same model's energy nevertheless gives the pull exactly right. The mechanism is entirely in the part of the field the model throws away.

electromagnetism · Dielectrics Fifty-nine millivolts for every factor of ten. The voltage that holds a singly charged ion at one concentration on one side of a boundary and another concentration on the other, in equilibrium, against the ratio of the concentrations on a logarithmic axis: (kT/e) ln(c₁/c₂), from requiring the electrochemical potential to be the same on both sides. At 0 °C, 54.20 mV per decade; at 25 °C, 59.16 mV per decade; at 37 °C, 61.54 mV per decade; at 100 °C, 74.04 mV per decade. The voltage depends on the ratio and the temperature and on nothing about the ion, the solvent or the boundary: it is the entropy of dilution, expressed per unit charge.

The voltage that is a chemical potential

A battery, a nerve cell and a pH meter all turn a difference in chemical potential into a voltage, and the conversion is the same in each: fifty-nine millivolts for every factor of ten in concentration, at room temperature, whatever the ion. The voltage a battery holds as it discharges is the chemical potential of the atoms stored in its electrodes — and a battery whose voltage barely changes is one whose electrode is going through a phase transition.

thermodynamics · Chemical potential

Named alongside it

The objects these essays reach for when they reach for this one.

Bound chargeCapacitanceChemical potentialDielectricDielectrophoresisElectrochemical potentialElectrostatic forceEnergy methodFree energyFringing fieldGibbs free energyLattice gas

All concepts