Illustrated Physics
physics, drawn
Concept

Helium-3 — where it appears

The light stable isotope of helium, with two protons and one neutron, which makes it a fermion. Its liquid stays normal down to about a millikelvin, its mixture with helium-4 is the working fluid of dilution refrigerators, and nearly all of the world's supply comes from the decay of tritium.

Named by 2 essays across one field — each of them below, with the objects they name alongside it.

The melting curve that turns back, then lies flat. The pressure at which liquid and solid helium-3 coexist, against temperature from 0.9 millikelvin to 1 kelvin on a logarithmic axis, from the international provisional low-temperature scale PLTS-2000, which is defined by this curve. Above 315.2 mK the curve behaves like any other: a higher temperature needs a higher pressure to freeze the liquid. Below it the curve turns back — at its minimum, 2.93113 MPa, it takes a higher pressure to freeze colder helium — and it rises to 3.4391 MPa at 1 mK, where it lies almost flat, as the third law requires of every coexistence line. The kinks that mark the liquid becoming superfluid and the solid's spins ordering sit on that flat end, at 2.444, 1.896 and 0.902 mK.

The melting curve that has to arrive flat

The slope of every line on which two phases coexist is their difference in entropy divided by their difference in volume. The third law says that entropy differences vanish at absolute zero, so every such line — melting, boiling, a superconductor's critical field — must reach the bottom of the temperature scale lying flat. Helium-3 reaches it in the strangest way available: below a third of a kelvin its solid is more disordered than its liquid, the melting curve runs backwards, and squeezing the liquid into solid absorbs heat. That backwards curve was the refrigerator in which superfluid helium-3 was found, and it is now the definition of temperature below one kelvin.

thermodynamics · Third law Why dissolving beats evaporating near absolute zero. Cooling power against temperature on logarithmic axes, for pumping on liquid helium-4, pumping on liquid helium-3 — both with a pump of 100 litres a second at room temperature — and a dilution refrigerator circulating 100 micromoles of helium-3 a second (the T² law, dashed above 0.1 K where it no longer holds). Evaporative cooling is proportional to the vapour pressure, which collapses as e^(−L/T): helium-4 gives 7·10⁻¹¹ W at 0.3 K, helium-3 10⁻⁴ W at 0.3 K and 2·10⁻²⁴ W at 50 mK. The dilution refrigerator's "vapour" is the dilute phase, whose density of helium-3 stays at 6.6% however cold it gets, so its cooling falls only as T²: 2·10⁻⁵ W at 50 mK. Below about 0.3 K nothing that evaporates can compete, and most experiments that must stay continuously below a tenth of a kelvin — superconducting quantum computers, bolometers for the cosmic microwave background, searches for dark matter — run on dilution.

The mixture that stays mixed at absolute zero

The third law says a mixture's entropy must vanish at absolute zero, so every mixture must either separate completely or order into a compound as it is cooled. Liquid helium-3 dissolved in helium-4 does neither. Below 0.87 kelvin it splits into two liquids, but the one that is mostly helium-4 keeps 6.6 per cent helium-3 however cold it gets — and the third law permits it, because the dissolved atoms are a degenerate Fermi gas with a single ground state and no entropy of mixing to lose. Pushing helium-3 across that boundary absorbs heat the way evaporation does, from a 'vapour' that never thins out. That is the dilution refrigerator, the machine that holds every superconducting quantum computer at ten millikelvin.

thermodynamics · Third law

Named alongside it

The objects these essays reach for when they reach for this one.

Fermi liquidThird lawClausius clapeyronCooling powerDilution refrigeratorEntropyEntropy of mixingKapitza resistanceMeltingPhase separationPhase transitionSuperfluidity

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